Provided is an electrically heated catalyst device that enables improving an exhaust gas purification performance. The electrically heated catalyst device of the present disclosure includes a substrate, an inflow side catalyst layer, and an outflow side catalyst layer. The substrate contains SiC. The inflow side catalyst layer contains Pd as a catalyst component. The outflow side catalyst layer contains Rh as a catalyst component. The substrate includes a partition wall defining a plurality of cells extending from an inflow side end surface to an outflow side end surface. The inflow side catalyst layer is disposed on a surface of the partition wall in an inflow side catalyst region. The inflow side catalyst region extends from an inflow side end of the partition wall along an extending direction to an outflow side by a distance of 60% to 90% of a total length in the extending direction of the partition wall. The outflow side catalyst layer is disposed on a surface of the partition wall and a surface of the inflow side catalyst layer in an outflow side catalyst region. The surface of the partition wall is in a portion not overlapping with the inflow side catalyst region. The surface of the inflow side catalyst layer is in a portion overlapping with the inflow side catalyst region. The outflow side catalyst region extends from an outflow side end of the partition wall along the extending direction to an inflow side by a distance of 60% to 90% of the total length in the extending direction of the partition wall.

Provided is a method for the preparation of a metal lattice-doping catalyst in an amorphous molten state, and the process of catalyzing methane to make olefins, aromatics, and hydrogen using the catalyst under oxygen-free, continuous flowing conditions. Such a process has little coke deposition and realizes atom-economic conversion. Under the conditions encountered in a fixed bed reactor (i.e. reaction temperature: 7501200 C.; reaction pressure: atmospheric pressure; the weight hourly space velocity of feed gas: 100030000 ml/g/h; and fixed bed), conversion of methane is 8-50%. The selectivity of olefins is 3090%. And selectivity of aromatics is 1070%. There is no coking. The reaction process has many advantages, including a long catalyst life (>100 hrs), high stability of redox and hydrothermal properties under high temperature, high selectivity towards target products, zero coke deposition, easy separation of products, good reproducibility, safe and reliable operation, etc., all of which are very desirable for industrial application.

A novel method for catalytic dehydration of glycerol to acrolein is provided. A fixed bed reactor is used, which is placed in a microwave unit. The feedstock is introduced into the fixed bed reactor after being preheated and gasified. Continuous glycerol dehydration occurs in the presence of a microwave-absorbing catalyst in the fixed bed reactor to form acrolein. The microwave-absorbing catalyst is composed of an active component loaded on a core-shell structure which consists of microwave absorbent coated by an oxide. The uniformity of microwave heating can reduce the formation of hot spot during the reaction and hence improve the catalyst stability. The process and operation is simple, and the unit can steadily run for a long time.

The present disclosure provides an integrated process for producing trifluoroiodomethane (CF.sub.3I), in three steps: a) reacting a first reactant stream comprising hydrogen (H.sub.2) and iodine (I.sub.2) in the presence of a first catalyst to produce a first product stream comprising hydrogen iodide (HI); (b) reacting the first product stream with a second reactant stream comprising trifluoroacetyl chloride (TFAC) in the presence of a second catalyst to produce an intermediate product stream comprising trifluoroacetyl iodide (TFAI); and (c) reacting the intermediate product stream to produce a final product stream comprising trifluoroiodomethane. (CF.sub.3I).

The present disclosure provides an integrated process for producing trifluoroiodomethane (CF.sub.3I), in three steps: a) reacting a first reactant stream comprising hydrogen (H.sub.2) and iodine (I.sub.2) in the presence of a first catalyst to produce a first product stream comprising hydrogen iodide (HI); (b) reacting the first product stream with a second reactant stream comprising trifluoroacetyl chloride (TFAC) in the presence of a second catalyst to produce an intermediate product stream comprising trifluoroacetyl iodide (TFAI); and (c) reacting the intermediate product stream to produce a final product stream comprising trifluoroiodomethane. (CF.sub.3I).

A method for making a metal carbide based catalyst for crude oil cracking includes mixing a clay with a phosphorous based stabilizer material to obtain a liquid slurry; adding an aluminosilicate zeolite and an ultrastable Y zeolite to the liquid slurry; adding Al.sub.2Cl(OH).sub.5 to the liquid slurry; adding metal carbide particles, having a given diameter, to the liquid slurry to obtain a mixture; and spray drying the mixture to obtain the metal carbide based catalyst. The metal carbide particles are coated with the aluminosilicate zeolite and the ultrastable Y zeolite.

A method for making a metal carbide based catalyst for crude oil cracking includes mixing a clay with a phosphorous based stabilizer material to obtain a liquid slurry; adding an aluminosilicate zeolite and an ultrastable Y zeolite to the liquid slurry; adding Al.sub.2Cl(OH).sub.5 to the liquid slurry; adding metal carbide particles, having a given diameter, to the liquid slurry to obtain a mixture; and spray drying the mixture to obtain the metal carbide based catalyst. The metal carbide particles are coated with the aluminosilicate zeolite and the ultrastable Y zeolite.

An exhaust gas purification catalyst or the like may inhibit poisoning of a noble metal component by a Si-containing compound generated or detached from silicon carbide, may inhibit degradation of exhaust gas purification performances over a long period, and may have excellent long-term durability. An exhaust gas purification catalyst may have a stacked structure including at least a substrate and a first and second coat layer, in that order. The substrate may be selected from a silicon carbide carrier including silicon carbide and a silicon carbide-covering carrier on which a coating layer including silicon carbide is provided. The first coat layer may include a compound including one or more alkaline-earth metals selected from Mg, Ca, Sr, and Ba. The second coat layer may includes one or more platinum group elements selected from Rh, Pt, and Pd.

An exhaust gas purification catalyst or the like may inhibit poisoning of a noble metal component by a Si-containing compound generated or detached from silicon carbide, may inhibit degradation of exhaust gas purification performances over a long period, and may have excellent long-term durability. An exhaust gas purification catalyst may have a stacked structure including at least a substrate and a first and second coat layer, in that order. The substrate may be selected from a silicon carbide carrier including silicon carbide and a silicon carbide-covering carrier on which a coating layer including silicon carbide is provided. The first coat layer may include a compound including one or more alkaline-earth metals selected from Mg, Ca, Sr, and Ba. The second coat layer may includes one or more platinum group elements selected from Rh, Pt, and Pd.

The present invention relates to a porous alpha-SiC-containing shaped body with a gas-permeable, open-pored pore structure comprising platelet-shaped crystallites which are connected to form an interconnected, continuous skeletal structure, wherein the skeletal structure consists of more than 80 wt.-% alpha-SiC, relative to the total weight of SiC, a process for producing same and its use as a filter component.