Patent classifications
B01J27/236
LAYERED MAGNESIUM MANGANESE COMPOSITE MATERIAL FOR COPPER ION ADSORPTION, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
Disclosed are a layered magnesium manganese composite material for copper ion adsorption, a preparation method therefor and an application thereof. The preparation method comprises: (1) dissolving a soluble magnesium salt and a soluble manganese salt in water to obtain a compound solution of the magnesium salt and the manganese salt; (2) dissolving a soluble carbonate and a soluble hydroxide in water to obtain a compound solution of the carbonate and the hydroxide; (3) dropwise adding the compound solution of the magnesium salt and the manganese salt into the compound solution obtained in step (2), stirring a mixed solution and allowing the mixed solution to age, and subjecting an obtained precipitate to centrifugation, washing, drying, grinding and sieving to obtain the layered magnesium manganese composite material for copper ion adsorption. The composite material provided by the present invention is excellent in ability to fix Cu.sup.2+, and features high absorption efficiency, high adsorption speed and stability. The composite material not only can fix Cu.sup.2+ efficiently, but also has important environmental significance in treating antibiotics in the environment and achieving in-situ remediation of compound pollution of heavy metals and organic matters.
Catalyst system and process utilizing the catalyst system
This invention relates to a catalyst system comprising (a) at least one layer of a first catalyst comprising a dehydrogenation active metal on a solid support; (b) at least one layer of a second catalyst comprising a metal oxide; and (c) at least one layer of a third catalyst comprising a transition metal on an inorganic support; wherein the at least one layer of a second catalyst is sandwiched between the at least one layer of a first catalyst and the at least one layer of a third catalyst; and a process comprising contacting a hydrocarbon feed with the catalyst system.
METHOD AND CATALYST FOR THE PRODUCTION OF 1,3-BUTADIENE FROM ETHANOL
The present invention is concerned with a catalyst for the conversion of ethanol to 1,3-butadiene comprising a component A selected from the list consisting of zeolite, silicon dioxide, aluminium oxide, or any combination thereof; and a component B.sub.cat comprising a mixed metal oxide, a catalyst precursor for the preparation of a catalyst for the conversion of ethanol to 1,3-butadiene comprising a component A selected from the list consisting of zeolite, silicon dioxide, aluminium oxide, or any combination thereof; and a component B.sub.pre comprising a layered double hydroxide (LDH) as well as a process for the conversion of ethanol to 1,3-butadiene, in which said catalyst is used.
METHOD AND CATALYST FOR THE PRODUCTION OF 1,3-BUTADIENE FROM ETHANOL
The present invention is concerned with a catalyst for the conversion of ethanol to 1,3-butadiene comprising a component A selected from the list consisting of zeolite, silicon dioxide, aluminium oxide, or any combination thereof; and a component B.sub.cat comprising a mixed metal oxide, a catalyst precursor for the preparation of a catalyst for the conversion of ethanol to 1,3-butadiene comprising a component A selected from the list consisting of zeolite, silicon dioxide, aluminium oxide, or any combination thereof; and a component B.sub.pre comprising a layered double hydroxide (LDH) as well as a process for the conversion of ethanol to 1,3-butadiene, in which said catalyst is used.
Method for efficiently catalyzing furfural to prepare cyclopentanone, and catalyst and preparation method therefor
A method for efficiently catalyzing furfural to prepare cyclopentanone, and a catalyst and preparation method therefor, are disclosed, in the field of biomass catalytic conversion. The catalyst comprises uniformly dispersed metal active center nanoparticles and oxides obtained by LDHs calcination. The metal active center is single atom Pt/Cu alloy; the LDHs is used as a precursor to prepare a Cu-containing catalyst precursor; after a reduction in H.sub.2 atmosphere, small amount of Pt.sup.2+ is used for reacting with the Cu-containing catalyst precursor to obtain a monoatomic Pt/Cu catalyst; said catalyst is used to catalyze hydrogenation of an aqueous phase of furfural to prepare cyclopentanone, wherein the reaction temperature is 120-250° C., the reaction pressure is 0.1-5 MPa, the reaction time is 0.5-24 hours, and the reaction solvent is ultrapure water. Low-cost and efficient, the catalyst catalyzes the hydrogenation of an aqueous phase of furfural to prepare cyclopentanone. When the reaction is carried out at 160° C. at an initial pressure of 0.1 MPa for 1 hour, the furfural is completely converted, and the yield of the cyclopentanone reaches 99%.
System and method for alcohol oxidation reaction of lignins
The invention herein concerns a catalyst of gold particles on a layered double hydroxide (LDH) that assists in oxidation of alcohols in lignins. In some embodiments, the LDH comprises lithium and aluminum metals. Also considered are methods of using the catalyst to oxidize lignins and methods of preparing the catalyst.
System and method for alcohol oxidation reaction of lignins
The invention herein concerns a catalyst of gold particles on a layered double hydroxide (LDH) that assists in oxidation of alcohols in lignins. In some embodiments, the LDH comprises lithium and aluminum metals. Also considered are methods of using the catalyst to oxidize lignins and methods of preparing the catalyst.
Highly efficient nanosized mesoporous CuMgAl ternary oxide catalyst
Highly efficient nanosized mesoporous CuMgAl ternary oxide catalysts are provided.
COMPOSITION OF CATALYSTS FOR CONVERSION OF ETHANOL TO N-BUTANOL AND HIGHER ALCOHOLS
A method of producing a catalyst comprises forming a decomposed material comprising a decomposed hydrotalcite, a decomposed hydrocalumite, or a combination of both, combining the decomposed material with a mixture to form a catalyst mixture, and heating the catalyst mixture to convert the metal salt to a metal oxide. The mixture comprises a metal salt and a chelating agent, and the resulting metal oxide combined with the decomposed material forms the catalyst.
METHODS FOR PREPARING MIXED-METAL OXIDE DIAMONDOID NANOCOMPOSITES AND CATALYTIC SYSTEMS INCLUDING THE NANOCOMPOSITES
Methods for preparing a layered metal nanocomposite and a layered metal nanocomposite. The method includes mixing a magnesium salt and a aluminum salt to form a Mg.sup.2+/Al.sup.3+ solution. The Mg/Al has a molar ratio of between 0.5:1 to 6:1. Then a diamondoid compound is added to the Mg.sup.2+/Al.sup.3+ solution to form a reactant mixture. The diamondoid compound has at least one carboxylic acid moiety. The reactant mixture is heated at a reaction temperature for a reaction time to form a Mg/Al-diamondoid intercalated layered double hydroxide. The Mg/Al-diamondoid intercalated layered double hydroxide is thermally decomposed under a reducing atmosphere for a decomposition time at a decomposition temperature to form the layered metal nanocomposite.