Patent classifications
B01J29/0341
Method for obtaining metal oxides supported on mesoporous silica particles
A method for obtaining metal oxides supported on mesoporous silica particles includes a) providing a solution of at least one metal salt, b) providing a solution of at least one template forming agent of the general formula (I) Y.sub.3Si(CH.sub.2).sub.nX (I), wherein X is a complexing functional group; Y is OH or a hydrolysable moiety selected from the group containing halogen, alkoxy, aryloxy, acyloxy, c) mixing the metal salt solution and the complex forming agent solution to obtain a metal precursor; d) adding at least one solution containing at least one pore structure directing agent to the metal precursor to obtain a metal precursor template mixture; e) adding at least one alkali silicate solution to the metal precursor template mixture at room temperature to obtain a silica-supported metal complex; and f) calcination of the silica-supported metal complex under air to obtain the supported metal oxide mesoporous silica particles.
Catalyst granules used in olefin disproportionation reaction and preparation method therefor
An integrated catalyst can be used in an olefin disproportionation reaction. The integrated catalyst contains a plurality of different integrated active phases. The relative positions among different active phases remain substantially unchanged during the olefin disproportionation reaction. The effective distance between respective bisecting planes of two adjacent different active phases is 0.5-5 mm, preferably 1-3 mm.