A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material. Any two or more metals are loaded in the porous support structure, the two or more metals selected from the group consisting of Ga, Ag, Mo, Zn, Co and Ce, where each metal loaded in the porous support structure is present in an amount from about 0.1 wt % to about 20 wt %. In example embodiments, the catalyst structure includes three or more of the metals loaded in the porous support structure. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.

Provided is a catalyst washcoat comprising (i) a molecular sieve loaded with about 1 to about 10 weight percent of at least non-aluminum promoter metal (wherein the promoter metal weight percent is based on the weight of the molecular sieve); and (ii) about 1 to about 30 weight percent of a binder having a d90 particle size of less than 10 microns (wherein the binder weight percent is based on the total weight of the washcoat). In another aspect of the invention, the catalyst washcoat is applied to a wall-flow filter to form a catalyst article. In another aspect of the invention the catalyst article is part of an exhaust gas treatment system. And in yet another aspect of the invention, provided is a method for treating exhaust gas using the catalyst article.

A reactor system may comprise a housing; and a condensation catalyst layer within the housing comprising a condensation catalyst comprised of at least one of a base-substituted zeolite, a stannous salt, or a phosphonitrile chloride. The condensation catalyst layer may be configured to catalyze a condensation reaction of a plurality of silane diols in water flowing through the housing into a plurality of siloxanes.

It is intended to provide a novel zeolite with a rare earth element-substituted framework which has a higher amount of NOx adsorbed and a method for producing the same, and a NOx adsorption member and a catalyst for automobile exhaust gas, etc. comprising the same. The present invention provides a zeolite with a rare earth element-substituted framework, comprising at least a zeolite and at least one rare earth element selected from the group consisting of Ce, La, Nd and Pr, wherein a content ratio of the rare earth element is 1 to 15% by mass in total based on the total amount, and one or some of Al and/or Si atoms constituting the framework of the zeolite are replaced with the rare earth element.

The subject invention is a novel UZM-63 material which comprises globular aggregates of crystallites having a DDR framework type with a mesopore volume of at least 0.025 cc/g, the nanocrystals having an average diameter of less than 60 nm. The novel UZM-63 material is useful for hydrocarbon conversion processes as well as separation applications, particularly the separation of olefins from paraffins.

A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

The present disclosure recognizes a correlation between zeolitic surface area (ZSA) of a catalyst composition and its catalytic activity. Particularly, the disclosure provides catalyst articles for diesel NO.sub.x abatement, including a substrate and a washcoat layer containing metal-promoted molecular sieves, wherein the zeolitic surface area (ZSA) of the catalyst article is about 100 m.sup.2/g or greater, the volumetric surface area is about 900 m.sup.2/in.sup.3 or greater, and/or the total zeolitic surface area (tZSA) is about 1200 m.sup.2 or greater. The disclosure further relates to methods for evaluating ZSA, volumetric ZSA, and tZSA, e.g., including the steps of coating a catalyst composition comprising metal-promoted molecular sieves onto a substrate; calcining and aging the catalyst composition; determining the ZSA (or volumetric ZSA or tZSA) thereof; and correlating the ZSA (or volumetric ZSA or tZSA) with catalyst composition NO.sub.x abatement activity to determine whether the catalyst composition is suitable for an intended use.

A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.

A method of manufacturing a modified zeolite catalyst may include reacting a zeolite with a metal salt to form a zeolite/metal salt complex. The zeolite may be a ZSM-5 or ZSM-11. The method may include heating the zeolite/metal salt complex to form an intermediate modified zeolite, and reacting the intermediate modified zeolite with an acid. The method may include ion exchanging the intermediate modified zeolite following the reaction with the acid to form a modified zeolite catalyst.

According to one or more embodiments described, a zeolite supported catalyst may be synthesized by a process that includes combining a colloidal mixture with a metal oxide support material to form a support precursor material, processing the support precursor material to form a support material, and impregnating the support material with one or more metals to form the zeolite supported catalyst. The colloidal mixture may include nano-sized zeolite crystals, and the nano-sized zeolite crystals may have an average size of less than 100 nm.