Patent classifications
B01J29/061
PROCESS FOR INTERCONVERSION OF OLEFINS WITH MODIFIED BETA ZEOLITE
Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.
Dual functional composite catalyst for olefin metathesis and cracking
Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.
Lithium-modified zeolite catalyst for alkane cracking
Methods for cracking a hydrocarbon feed stream include contacting a hydrocarbon feed stream with a catalyst system in a catalytic cracking unit having a flowing gas stream to obtain a cracking product containing light olefins. The catalyst system includes at least a base catalyst. The base catalyst includes a pentasil zeolite. The pentasil zeolite includes from 0.01% to 5% by mass lithium atoms, as calculated on an oxide basis, based on the total mass of the pentasil zeolite. The flowing gas stream comprises hydrogen and, optionally, at least one additional carrier gas.
Method for conversion of diols to olefin products
A method for converting a diol in solution to an olefin fraction, the method comprising: (i) reacting a diol of the formula HO—R—OH in solution with a carbonyl-containing molecule of the formula: ##STR00001##
in the presence of an acid catalyst to result in a dioxolane molecule of the formula: ##STR00002##
wherein R is a hydrocarbon linker containing 1-12 carbon atoms, and R.sup.1 and R.sup.2 are independently selected from hydrogen atom and hydrocarbon groups containing 1-12 carbon atoms, wherein R.sup.1 and R.sup.2 optionally interconnect; (ii) removing the dioxolane molecule from the solution by phase separation; and (iii) contacting the dioxolane molecule with a metal-loaded zeolite at a temperature of 100-500° C. to convert the dioxolane molecule to an olefin fraction.
Zeolitic catalytic conversion of alcohols to hydrocarbons
A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.
Platinum encapsulated zeolite hydrocracking catalyst and methods of making same
Embodiments of the present disclosure are directed to hydrocracking catalysts and methods of making same. The hydrocracking catalyst comprises a platinum encapsulated zeolite having a crystallinity greater than 20% determined by X-ray powder diffraction analysis.
CATALYST FOR NON-OXIDATIVE CONVERSION OF HYDROCARBONS TO HYDROGEN
The present disclosure refers to systems, methods, and catalysts for conversion of a hydrocarbon to hydrogen. The catalyst typically comprises a matrix comprising fused silica, quartz, glass, a zeolite, Si.sub.3N.sub.4, SiC, SiC.sub.xO.sub.y wherein 4x+2y =4, SiO.sub.aN.sub.b wherein 2a+3b =4, BN, TiO.sub.2, ZrO.sub.2, Al.sub.2O.sub.3, CeO.sub.2, Nb.sub.2O.sub.5, La.sub.2O.sub.3, a perovskite, or any mixture thereof. A metal dopant is embedded in the matrix. The metal dopant comprises Fe, Ni, Co, Cu, Zn, Mn, or any mixture thereof.
MOLECULAR SIEVE COMPLEX, COMPOSITE MATERIAL AND APPLICATION THEREOF
A molecular sieve complex contains an oxide of aluminum, an oxide of an alkaline earth metal and a rare earth-modified molecular sieve. The rare earth-modified molecular sieve is a molecular sieve doped by a rare earth element. The percentage of the pore volume occupied by pores of 3 nm or less to the total pore volume in the molecular sieve complex is greater than or equal to 63.5%. The content of the rare earth element and the contents of the oxide of aluminum, the oxide of the alkaline earth metal and the molecular sieve satisfy a certain relationship. The composite material contains a molecular sieve complex and an auxiliary agent loaded on the molecular sieve complex, and the composite material may be applied to flue gas adsorption and desulfurization.
Modified catalyst, method for preparing the same, and method for producing aromatic hydrocarbons by aromatization of olefins
The present disclosure provides a modified catalyst, and preparation method and a method for producing aromatic hydrocarbons by aromatization of olefins using the modified catalyst. The modified catalyst comprises an acidic molecular sieve and an olefin aromatization active metal component, the total acid amount of the catalyst as measured by NH.sub.3-TPD method is not higher than 0.35 mmol/g, and ratio of the strong acid to weak acid is within a range of 0.8-1.2.
AIR PURIFIERS
In certain exemplary embodiments, an air purifier comprises a housing defining an enclosure and having an air entrance and an air exit; a particulate filter; a NCCO filter material configured to adsorb and decompose at least one gaseous pollutant; an AOG configured to generate at least one oxidant; an oxidant remover configured to remove at least one oxidant; a fan unit configured to generate airflow from the air entrance to the air exit; wherein the particulate filter, the NCCO filter material, the AOG, the oxidant remover and the fan unit are positioned within the enclosure such that during operation, a flow of air passes from the air entrance to the air exit through the particulate filter and the NCCO filter material along a direction of the flow of air. In certain embodiments, the air purifier may ensure safety to users while efficiency in removing contaminants can be greatly improved.