B01J29/08

CRYSTALLINE BOEHMITE MATERIALS AS PRECURSORS FOR LARGE CRYSTAL GAMMA ALUMINA AND LOW SURFACE AREA ALPHA ALUMINA
20230365424 · 2023-11-16 ·

A process for preparing crystalline boehmite includes combining a stoichiometric amount of flash calcined gibbsite (AI.sub.2O.sub.3) and gibbsite (Al(OH).sub.3) in a pressurizable reaction vessel; heating the flash calcined gibbsite and gibbsite in the reaction vessel to a temperature of about 200° C. to about 280° C. and for a time sufficient to form crystalline boehmite. A crystalline boehmite exhibiting a crystallite from about 600 Å to about 850 Å when measured in the 120 direction of the crystallographic space group Cmcm.

PEPTIZATION AGENT AND SOLID CATALYST MANUFACTURING METHOD
20230364592 · 2023-11-16 ·

Methods of solid catalyst manufacture using a peptization agent, a peptization agent, and formed solid catalyst materials are provided. The peptization agent includes one or more oxidized disulfide oil (“ODSO”) compounds. These ODSO compounds peptization agents are used to replace conventional acids used as peptization agents.

Catalyst for removal of sulphur oxides from flue gases of power plants

The present invention relates to the catalytic processes for rendering harmless the flue gases of the power stations or more precisely to the catalysts for sulfur oxides reduction to elemental sulfur. The novel catalyst presents the binary polycations of copper and zinc or copper and manganese incorporated into the low silica faujasite X (LSX) having transition metals ratio Cu:Zn or Cu:Mn in the range of 2:1 to 4:1.

Catalyst for producing light olefins from C4-C7 hydrocarbons

The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.

Process and nano-ZSM-5 based catalyst formulation for cracking crude oil to produce light olefins and aromatics

A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a fluidized catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, where the nano-ZSM-5 zeolite has an average particle size of from 0.01 μm to 0.2 μm, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.

Reactive silica-alumina matrix component compositions for bottoms cracking catalysts

A bottoms cracking catalyst composition, comprising: about 30 to about 60 wt % alumina; greater than 0 to about 10 wt % of a dopant, measured as the oxide; about 2 to about 20 wt % reactive silica; about 3 to about 20 wt % of a component comprising peptizable boehmite, colloidal silica, aluminum chlorohydrol, or a combination of any two or more thereof; and about 10 to about 50 wt % of kaolin.

Acrylic acid, and methods of producing thereof
11827590 · 2023-11-28 · ·

Provided herein are methods of producing acrylic acid from beta-propiolactone. Such methods may involve the use of a heterogeneous catalyst, such as a zeolite.

Method for selectively chemically reducing CO.SUB.2 .to form CO

A method for selectively chemically reducing CO.sub.2 to form CO includes providing a catalyst, and contacting H.sub.2 and CO.sub.2 with the catalyst to chemically reduce CO.sub.2 to form CO. The catalyst includes a metal oxide having a chemical formula of Fe.sub.xCo.sub.yMn.sub.(1−x−y)O.sub.z, in which 0.7≤x≤0.95, 0.01≤y≤0.25, and z is an oxidation coordination number.

High activity and high distillate yield hydrocracking catalysts with intimate interaction between unsupported metal oxide and zeolite

A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

MOLECULAR SIEVE SSZ-121 WITH HIGH ACIDITY, ITS SYNTHESIS AND USE
20230382746 · 2023-11-30 · ·

A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-121 is provided which exhibits increased acidity. The SSZ-121 can be synthesized using 1,3-bis(1-adamantyl)imidazolium cations as a structure directing agent. The synthesis employs a boron pathway to achieve increased acid sites. The SSZ-121 of increased acidity may be used in organic compound conversion reactions and/or sorptive processes.