Patent classifications
B01J29/18
CATALYST CONTAINING LF-TYPE B ACID AND METHOD FOR PREPARING ETHYLENE USING DIRECT CONVERSION OF SYNGAS
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
CATALYST CONTAINING LF-TYPE B ACID AND METHOD FOR PREPARING ETHYLENE USING DIRECT CONVERSION OF SYNGAS
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
ORGANIC BASE MODIFIED COMPOSITE CATALYST AND METHOD FOR PRODUCING ETHYLENE BY HYDROGENATION OF CARBON MONOXIDE
An organic base modified composite catalyst for producing ethylene by hydrogenation of carbon monoxide is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide; the component II is an organic base modified zeolite of MOR topology; and a weight ratio of the active ingredients in the component I to the component II is 0.1-20, and preferably 0.3-8. The reaction process has an extremely high product yield and selectivity. The selectivity of C.sub.2-C.sub.3 olefins is as high as 78-87%; the selectivity of hydrocarbon products with more than 4 C atoms is less than 10%; the selectivity of a methane side product is extremely low (<9%); and meanwhile, the selectivity of the ethylene is 75-82%.
DIESEL OXIDATION CATALYST
An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, described is an oxidation catalyst composite including a first oxidation component comprising a first refractory metal oxide support, palladium (Pd) and platinum (Pt); a NO.sub.x storage component comprising one or more of alumina, silica, titania, ceria, or manganese; and a second oxidation component comprising a second refractory metal oxide, a zeolite, and Pt. The oxidation catalyst composite is sulfur tolerant, adsorbs NO.sub.x and thermally releases the stored NO.sub.x at temperature less than 350 C.
Treatment of aromatic alkylation catalysts
The present disclosure relates to a process for producing a mono-alkylated aromatic compound using a treated catalyst made by a method of this invention is disclosed. The method comprises the steps of heating an untreated catalyst in the presence of a gaseous stream having a dew point temperature less than about 5 C. to form a treated catalyst. The treatment is effective to improve the activity and selectivity of the catalyst.
Treatment of aromatic alkylation catalysts
The present disclosure relates to a process for producing a mono-alkylated aromatic compound using a treated catalyst made by a method of this invention is disclosed. The method comprises the steps of heating an untreated catalyst in the presence of a gaseous stream having a dew point temperature less than about 5 C. to form a treated catalyst. The treatment is effective to improve the activity and selectivity of the catalyst.
CATALYST AND PROCESS FOR PREPARING DIMETHYL ETHER
The invention relates to a catalyst and catalyst layer and process for preparing dimethyl ether from synthesis gas or methanol as well as the use of the catalyst or catalyst layer in this process.
Mordenite zeolite and production method therefor
Provided is a mordenite zeolite which can be produced without using an organic structure-directing agent, and has superior multivalent metal cation exchange capability. The mordenite zeolite according to the present invention containing silicon, a divalent metal M and aluminum in a skeletal structure, wherein the mordenite zeolite has the following atomic ratios in the state of Na-form. The mordenite zeolite preferably has a BET specific surface area of 250 m.sup.2/g or more and 500 m.sup.2/g or less and a micropore volume of 0.07 cc/g or more and 0.25 cc/g or less in the state of Na-form or H-form. Si/(M+Al)=5 or more and 10 or less, M/(M+Al)=0.1 or more and less than 1, and Na/(M+Al)=1 or more and less than 2.
Mordenite zeolite and production method therefor
Provided is a mordenite zeolite which can be produced without using an organic structure-directing agent, and has superior multivalent metal cation exchange capability. The mordenite zeolite according to the present invention containing silicon, a divalent metal M and aluminum in a skeletal structure, wherein the mordenite zeolite has the following atomic ratios in the state of Na-form. The mordenite zeolite preferably has a BET specific surface area of 250 m.sup.2/g or more and 500 m.sup.2/g or less and a micropore volume of 0.07 cc/g or more and 0.25 cc/g or less in the state of Na-form or H-form. Si/(M+Al)=5 or more and 10 or less, M/(M+Al)=0.1 or more and less than 1, and Na/(M+Al)=1 or more and less than 2.
Disproportionation and transalkylation of heavy aromatic hydrocarbons
Disclosed herein is a process for producing para-xylene comprising the steps of: (a) contacting a feedstock comprising toluene with a first catalyst under effective vapor phase toluene disproportionation conditions to disproportionate said toluene and produce a first product comprising benzene, unreacted toluene and greater than equilibrium amounts of para-xylene; and (b) contacting a feedstock comprising C.sub.9+ aromatic hydrocarbons and benzene with a second catalyst in the presence of 0 wt. % or more of hydrogen having a 0 to 10 hydrogen/hydrocarbon molar ratio under effective C.sub.9+ transalkylation conditions to transalkylate said C.sub.9+ aromatic hydrocarbons and produce a second product comprising xylenes.