Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

A molecular sieve having the framework structure of ZSM-5 is produced using one or more of 1,4-bis(N-pentylpyrrolidinium)butane dications, 1,5-bis(N-pentylpyrrolidinium)pentane dications, and 1,6-bis(N-pentylpyrrolidinium)hexane dications as a structure directing agent.

A molecular sieve having the framework structure of ZSM-5 is produced using one or more of 1,4-bis(N-pentylpyrrolidinium)butane dications, 1,5-bis(N-pentylpyrrolidinium)pentane dications, and 1,6-bis(N-pentylpyrrolidinium)hexane dications as a structure directing agent.

The present disclosure provides a modified catalyst, and preparation method and a method for producing aromatic hydrocarbons by aromatization of olefins using the modified catalyst. The modified catalyst comprises an acidic molecular sieve and an olefin aromatization active metal component, the total acid amount of the catalyst as measured by NH3-TPD method is not higher than 0.35mmo1/g, and ratio of the strong acid to weak acid is within a range of 0.8-1.2.

A method of producing olefins by catalytic cracking of hydrocarbons is disclosed. The method may include catalytic cracking hydrocarbons in a feed stream that includes the hydrocarbons and the dry gas diluent. The catalytic cracking may be carried out in a process using a train of fixed bed reactors while one or more other trains of fixed bed reactors are being regenerated or are on standby after being regenerated. When the train of fixed bed reactors being used needs regenerating, it is taken out of service and the one or more other trains of fixed bed reactors put in service to carry out the catalytic cracking process. Dry gas instead of steam may be used to reduce the partial pressure of hydrocarbons.

A method of producing olefins by catalytic cracking of hydrocarbons is disclosed. The method may include catalytic cracking hydrocarbons in a feed stream that includes the hydrocarbons and the dry gas diluent. The catalytic cracking may be carried out in a process using a train of fixed bed reactors while one or more other trains of fixed bed reactors are being regenerated or are on standby after being regenerated. When the train of fixed bed reactors being used needs regenerating, it is taken out of service and the one or more other trains of fixed bed reactors put in service to carry out the catalytic cracking process. Dry gas instead of steam may be used to reduce the partial pressure of hydrocarbons.

A nanostructured porous catalyst for rubber vulcanization, the catalyst comprising a high surface area.

This disclosure relates to a single stage process for the direct conversion of alcohols, e.g. ethanol, to olefinic mixtures (C.sub.2-C.sub.7) with low levels of aromatics carried out in a single reactor with two fixed catalyst beds in series, or two catalytic fixed bed reactors in series wherein the first reactor operates at a lower or higher temperature than the operating temperature of the second reactor. The process transformation of ethanol is comprised of ethanol dehydration to ethylene and water in high yield with the first catalyst in the first reactor, or via the first fixed catalyst bed, followed by directly feeding the ethylene and water to the second reactor, or second fixed catalyst bed, with conversion of said ethylene and water to a C.sub.2-C.sub.7 olefinic mixture with the second catalyst(s) in high yields with minimal aromatic compound formation.

This disclosure relates to a single stage process for the direct conversion of alcohols, e.g. ethanol, to olefinic mixtures (C.sub.2-C.sub.7) with low levels of aromatics carried out in a single reactor with two fixed catalyst beds in series, or two catalytic fixed bed reactors in series wherein the first reactor operates at a lower or higher temperature than the operating temperature of the second reactor. The process transformation of ethanol is comprised of ethanol dehydration to ethylene and water in high yield with the first catalyst in the first reactor, or via the first fixed catalyst bed, followed by directly feeding the ethylene and water to the second reactor, or second fixed catalyst bed, with conversion of said ethylene and water to a C.sub.2-C.sub.7 olefinic mixture with the second catalyst(s) in high yields with minimal aromatic compound formation.

A process for preparing a peptized alumina having increased solids and acid contents and a decreased water content. The process comprising mixing a boehmite or pseudoboehmite alumina and acid with a high intensity, high energy mixer at a ratio of 0.16 to 0.65 moles acid/moles alumina for a time period sufficient to form a substantially free-flowing solid particulate having a solids content of 45 to 65 wt %. When used in catalyst manufacture, peptized alumina produced by the process provides an increased rate in catalyst production and decreased costs due to high solids concentration and the presence of less water to be evaporated.