A method is provided for the synthesis of a zeolite of the offretite structure using cyclopropyltrimethylammonium cations as a structure directing agent.

There is disclosed a microporous crystalline material comprising a crystal structure having building units of double-6-rings (d6r) and pore opening of 8-rings, wherein the material comprises a first metal chosen from alkali-earth group, rare-earth group, alkali group or mixtures thereof, and a second metal chosen from copper, iron or mixtures thereof, wherein the material has molar silica to alumina ratio (SAR) from 3 to 12, and is further steamed to enhance stability. Methods of making the crystalline material are also disclosed. There is also disclosed a method of selective catalytic reduction of nitrogen oxides in exhaust gas, comprising at least partially contacting the exhaust gases with an article comprising the disclosed microporous crystalline material.

There is disclosed a microporous crystalline material comprising a crystal structure having building units of double-6-rings (d6r) and pore opening of 8-rings, wherein the material comprises a first metal chosen from alkali-earth group, rare-earth group, alkali group or mixtures thereof, and a second metal chosen from copper, iron or mixtures thereof, wherein the material has molar silica to alumina ratio (SAR) from 3 to 12, and is further steamed to enhance stability. Methods of making the crystalline material are also disclosed. There is also disclosed a method of selective catalytic reduction of nitrogen oxides in exhaust gas, comprising at least partially contacting the exhaust gases with an article comprising the disclosed microporous crystalline material.

An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.

Disclosed herein are compositions comprising an aluminosilicate zeolite crystals with an 8 ring pore size having a depth dependent silica to alumina molar ratio and processes of making aluminosilicate zeolite crystals with an 8 ring pore size having a depth dependent silica to alumina molar ratio.

The present invention relates to a catalytic wall-flow monolith for use in an emission treatment system, the monolith comprising a porous substrate and having a first face and a second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction, the first plurality of channels provides a first plurality of inner surfaces and is open at the first face and closed at the second face, and the second plurality of channels is open at the second face and closed at the first face, a first catalytic material is distributed within the porous substrate, a microporous membrane is provided in the first plurality of channels on a first portion, extending in the longitudinal direction, of the first plurality of inner surfaces, and the first portion extends from the first face for 75 to 95% of a length of the first plurality of channels.

The present invention relates to a catalytic wall-flow monolith for use in an emission treatment system, the monolith comprising a porous substrate and having a first face and a second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction, the first plurality of channels provides a first plurality of inner surfaces and is open at the first face and closed at the second face, and the second plurality of channels is open at the second face and closed at the first face, a first catalytic material is distributed within the porous substrate, a microporous membrane is provided in the first plurality of channels on a first portion, extending in the longitudinal direction, of the first plurality of inner surfaces, and the first portion extends from the first face for 75 to 95% of a length of the first plurality of channels.

Carbonylation process for producing methyl acetate, by contacting dimethyl ether and carbon monoxide under carbonylation conditions in the presence of a catalyst having a zeolite of micropore volume of 0.01 ml/g. The zeolite is an as-synthesized organic structure directing agent-containing zeolite and contains at least one channel which is defined by an 8-member ring.

A carbonylation process in the presence of a pretreated zeolite catalyst which comprises the sequential steps (i) pretreating the catalyst and (ii) carbonylating dimethyl ether with a carbon monoxide-containing gas to produce methyl acetate in which the catalyst pretreatment step (i) comprises a step (a) contacting the catalyst with a first treatment mixture comprising water vapour; and a step (b) contacting the treated catalyst of step (a) with a second treatment mixture comprising an inert gas and at least one of dimethyl ether and methanol.

A carbonylation process in the presence of a pretreated zeolite catalyst which comprises the sequential steps (i) pretreating the catalyst and (ii) carbonylating dimethyl ether with a carbon monoxide-containing gas to produce methyl acetate in which the catalyst pretreatment step (i) comprises a step (a) contacting the catalyst with a first treatment mixture comprising water vapour; and a step (b) contacting the treated catalyst of step (a) with a second treatment mixture comprising an inert gas and at least one of dimethyl ether and methanol.