B01J29/65

ZEOLITE PROMOTED V/TiW CATALYSTS

Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, ceria, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.

ZEOLITE PROMOTED V/TiW CATALYSTS

Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, ceria, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.

Methods for synthesizing hierarchical zeolites for catalytic cracking

Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.

Methods for synthesizing hierarchical zeolites for catalytic cracking

Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.

Composition and process for preparation of cracking catalyst suitable for enhancing yields of light olefins

The present invention relates to a fluid catalytic cracking additive composition for cracking of heavy hydrocarbon feed stocks and process for preparing the additive. The additive is suitable for enhancing yields of light olefins such as propylene, isobutylene, LPG and reduces the bottom yields. The invention specifically relates to a fluid catalytic cracking additive composition comprising a pentasil zeolite, zeolites having pore size in a range of 5.4-7.7 , alumina, colloidal silica, kaolin clay, and phosphate, wherein the zeolites having pore size in the range of 5.4-7.7 is present in an amount of 1 to 10 wt % with respect to the total amount of the pentasil zeolite and zeolite having the pore size in the range of 5.4-7.7 .

Composition and process for preparation of cracking catalyst suitable for enhancing yields of light olefins

The present invention relates to a fluid catalytic cracking additive composition for cracking of heavy hydrocarbon feed stocks and process for preparing the additive. The additive is suitable for enhancing yields of light olefins such as propylene, isobutylene, LPG and reduces the bottom yields. The invention specifically relates to a fluid catalytic cracking additive composition comprising a pentasil zeolite, zeolites having pore size in a range of 5.4-7.7 , alumina, colloidal silica, kaolin clay, and phosphate, wherein the zeolites having pore size in the range of 5.4-7.7 is present in an amount of 1 to 10 wt % with respect to the total amount of the pentasil zeolite and zeolite having the pore size in the range of 5.4-7.7 .

Hybrid extruded mixed zeolite catalysts for synthesis of light olefins

A catalyst for converting dimethyl ether into light olefins, including ethylene and propylene. The catalyst comprises a mixture of two zeolites, ZSM-5 and ZSM-35, intimately mixed and kept in close proximity in a porous extruded binder system. The resulting combination of zeolites demonstrates a synergistic effect with respect to the conversion of the dimethyl ether and has improved resistance to deactivation due to carbon and coke formation than the individual zeolites alone when operating in this reaction. The catalyst is used to produce ethylene and propylene from a feed mixture containing methanol, dimethyl ether and water.

METHOD FOR THE ISOMERIZING DEHYDRATION OF A NON-LINEAR PRIMARY ALCOHOL FEEDSTOCK IN THE PRESENCE OF WATER INJECTION AND A CATALYST COMPRISING A FER OR MFS ZEOLITE

A process for the isomerizing dehydration of a feedstock including a primary monoalcohol, alone or as a mixture, of formula RCH.sub.2OH, wherein R is a nonlinear alkyl radical of general formula C.sub.nH.sub.2n+1 where n is an integer between 3 and 20, the process taking place in the gas phase at a weighted average temperature between 275 C. and 400 C., at a pressure between 0.3 MPa and 1 MPa and at a WWH (weight per weight per hour) between 5 and 10 h.sup.1, in the presence of a catalyst containing at least one silicic binder and at least one zeolite having at least one series of channels, the opening of which is defined by a ring of 8 oxygen atoms (8MR), process wherein vaporized feedstock entering the reactor has a weight content of water of from 4% to 35%.

METHOD FOR THE ISOMERIZING DEHYDRATION OF A NON-LINEAR PRIMARY ALCOHOL FEEDSTOCK IN THE PRESENCE OF WATER INJECTION AND A CATALYST COMPRISING A FER OR MFS ZEOLITE

A process for the isomerizing dehydration of a feedstock including a primary monoalcohol, alone or as a mixture, of formula RCH.sub.2OH, wherein R is a nonlinear alkyl radical of general formula C.sub.nH.sub.2n+1 where n is an integer between 3 and 20, the process taking place in the gas phase at a weighted average temperature between 275 C. and 400 C., at a pressure between 0.3 MPa and 1 MPa and at a WWH (weight per weight per hour) between 5 and 10 h.sup.1, in the presence of a catalyst containing at least one silicic binder and at least one zeolite having at least one series of channels, the opening of which is defined by a ring of 8 oxygen atoms (8MR), process wherein vaporized feedstock entering the reactor has a weight content of water of from 4% to 35%.

METHOD FOR SYNTHESIZING A FER/MOR COMPOSITE MOLECULAR SIEVE

This application consists of a method for the synthesis of a type of FER/MOR composite molecular sieve. That method consisting of mixing FER seed crystals, MOR seed crystals, a silicon source, water and an acid or alkali, thus yielding a reaction mixture; by adjusting the proportions of the seed crystals added, the silicon-aluminium proportion, acidity/alkalinity and other reaction conditions, it is possible to obtain a dual phase composite molecular sieve within which the proportions of the crystal phases may be adjusted. In the synthesis process to which the method of this application relates, there is no need to add any organic template, thus reducing the cost of the reaction, in addition to reducing likely environmental pollution, thus having major potential applications.