B01J29/80

Molecular sieve intergrowths of cha and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
11766668 · 2023-09-26 ·

Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

Molecular sieve intergrowths of cha and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
11766668 · 2023-09-26 ·

Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

Catalyst for synthesizing dimethylether or methylacetate from synthetic gas, method for preparing the same, and method for preparing dimethylether or methylacetate using the same

The present disclosure provides a method of preparing a catalyst for synthesizing dimethyl ether or methylacetate from synthetic gas that includes preparing a nanosheet ferrierite zeolite (FER), and co-precipitating the nanosheet ferrierite zeolite and a precursor of a Cu—Zn—Al-based oxide (CZA) to obtain a hybrid CZA/FER catalyst.

Catalyst for synthesizing dimethylether or methylacetate from synthetic gas, method for preparing the same, and method for preparing dimethylether or methylacetate using the same

The present disclosure provides a method of preparing a catalyst for synthesizing dimethyl ether or methylacetate from synthetic gas that includes preparing a nanosheet ferrierite zeolite (FER), and co-precipitating the nanosheet ferrierite zeolite and a precursor of a Cu—Zn—Al-based oxide (CZA) to obtain a hybrid CZA/FER catalyst.

PROCESS FOR DEPARAFFINNING A MIDDLE DISTILLATE FEEDSTOCK USING A CATALYST BASED ON IZM-2 ZEOLITE AND AN MFI-TYPE ZEOLITE

The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point.

Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.

PROCESS FOR DEPARAFFINNING A MIDDLE DISTILLATE FEEDSTOCK USING A CATALYST BASED ON IZM-2 ZEOLITE AND AN MFI-TYPE ZEOLITE

The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point.

Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.

PROCESS FOR INTERCONVERSION OF OLEFINS WITH MODIFIED BETA ZEOLITE

Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.

PROCESS FOR INTERCONVERSION OF OLEFINS WITH MODIFIED BETA ZEOLITE

Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.

HIGH ACTIVITY AND HIGH DISTILLATE YIELD HYDROCRACKING CATALYSTS WITH INTIMATE INTERACTION BETWEEN UNSUPPORTED METAL OXIDE AND ZEOLITE

A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

A CATALYST AND METHOD OF USE THEREOF
20210362140 · 2021-11-25 ·

A catalyst for the conversion of NO.sub.X comprising iron chabazite and iron beta zeolite and a method of reducing the NOX concentration in a process gas stream comprising contacting the process gas stream with the catalyst. The catalyst is especially useful for high temperature deNO.sub.X conversion.