Patent classifications
B01J31/0204
Catalyst made from an organic compound and use thereof in a hydroprocessing and/or hydrocracking method
The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and an organic compound of formula (I) ##STR00001##
in which R1, R2, R3, R4 and R5 are selected from among a hydrogen atom, or a hydroxyl radical, or a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, and R6 is selected from a hydrogen atom, a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, a methacryloyl radical, an acryloyl radical or an acetyl radical. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.
Normal alpha olefin synthesis using dehydroformylation or dehydroxymethylation
The present invention discloses processes for producing normal alpha olefins, such as 1-hexene, 1-octene, 1-decene, and 1-dodecene in a multistep synthesis scheme from another normal alpha olefin. Also disclosed are reactions for converting aldehydes, primary alcohols, and terminal vicinal diols into normal alpha olefins.
Cobalt catalyst comprising a support comprising a mixed oxide phase including cobalt and/or nickel produced from an ether compound
The present invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support containing a mixed oxide phase containing cobalt and/or nickel, said catalyst has been prepared by introducing at least one ether organic compound comprising not more than two ether functions and not comprising a hydroxyl group. The invention also relates to the process for the preparation thereof, and to the use thereof in the field of Fischer-Tropsch synthesis processes.
APPLICATION OF LITHIUM 4-METHOXYANILINE IN CATALYSIS OF HYDROBORATION REACTION OF IMINE AND BORANE
The present invention relates to the application of lithium 4-methoxyaniline in catalysis of the hydroboration reaction of an imine and a borane. A catalyst, a borane and an imine are successively stirred and mixed until uniform, reacted for 1 to 2 hours, and then exposed to air so as to stop the reaction, and the reaction liquid is subjected to decompression to remove a solvent therein, so as to obtain a borate with different substituents. The lithium 4-methoxyaniline disclosed in the present invention can catalyze the hydroboration reaction of an imine and a borane in a high activity manner at room temperature, wherein the amount of the catalyst is merely 4-5 mol % of the molar amount of the imine, and the yield of the reaction can reach 90% or more. The yield of a borate with different substituents can reach 99% with mild reaction conditions under an optimized condition.
HYDROGENATION CATALYST COMPOSITIONS AND THEIR USE FOR HYDROGENATION OF NITRILE RUBBER
This invention relates to novel hydrogenation catalyst compositions obtainable from reacting metal-based complex hydrogenation catalysts with specific co-catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such novel hydrogenation catalyst compositions.
Catalyst containing a furan compound and use thereof in a hydroprocessing and/or hydrocracking method
The invention relates to a catalyst comprising an alumina-, silica- or silica-alumina-based support, at least one group VIII element, at least one group VIB element, and a furan compound. The invention also relates to the method for producing said catalyst and to the use thereof in a hydrotreating and/or hydrocracking method.
HYDROPROCESSING CATALYST HAVING AN ORGANIC ADDITIVE WITH OVERLAID METALS AND METHOD OF MAKING AND USING SUCH CATALYST
A highly active hydroprocessing catalyst that comprises a doped support impregnated with at lease one hydrogenation metal component and filled with an organic additive blend. The catalyst is made by providing a doped support particle followed by impregnating the doped support particle with a metal impregnation solution to provide a metal-impregnated doped support particle. The metal-impregnated doped support particle is dried but not calcined and impregnated with an organic additive blend component.
Selective hydrogenation method using a nickel-based catalyst produced using an additive comprising a carboxylic acid function
A process for the selective hydrogenation of polyunsaturated compounds containing at least 2 carbon atoms per molecule, contained in a hydrocarbon feedstock having a final boiling point below or equal to 300 C. in the presence of a catalyst comprising an alumina support and an active phase comprising nickel, said active phase not comprising a metal from Group VIB, said catalyst being prepared by a process comprising at least: i) a step of bringing said support into contact with at least one solution containing at least one nickel precursor; ii) a step of bringing said support into contact with at least one solution containing at least one organic compound comprising at least one carboxylic acid function; iii) a step of drying said impregnated support at a temperature below 250 C.;
steps i) and ii) being carried out separately, in any order.
METHOD FOR MANUFACTURING ELECTROLESS PLATING SUBSTRATE AND METHOD FOR FORMING METAL LAYER ON SURFACE OF SUBSTRATE
The instant disclosure provides a method for manufacturing an electroless plating substrate and a method for forming a metal layer on a surface of a substrate. The method for preparing the electroless plating substrate includes: providing a substrate; attaching a self-adsorbed catalyst composition to a surface of the substrate; and performing an electroless metal deposition for forming an electroless metal layer on the surface of the substrate. The self-adsorbed catalyst composition includes a colloidal nanoparticle and a silane compound. The colloidal nanoparticle includes a palladium nanoparticle and a capping agent enclosing the palladium nanoparticle. The silane compound has at least one amino group to interact with the colloidal nanoparticle. A covalent bond between the silane compound and the surface of the substrate is formed through the at least one silane group of the silane compound. The colloid nanoparticle has a particle size ranging from 5 to 10 nanometers.
RADICAL GENERATING CATALYST, METHOD FOR PRODUCING RADICAL, METHOD FOR PRODUCING OXIDATION REACTION PRODUCT, DRUG, AND DRUG FOR AGRICULTURE AND LIVESTOCK
An object of a first aspect of the present invention is to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, a first radical generating catalyst according to the first aspect of the present invention is characterized in that it includes ammonium and/or a salt thereof. A second radical generating catalyst according to the first aspect of the present invention is characterized in that it includes an organic compound having Lewis acidic properties and/or Brnsted acidic properties.