Patent classifications
B01J35/393
Preparation method of carbon-supported metal oxide and/or alloy nanoparticles catalyst using physical vapour deposition
Disclosed is a method for preparing a carbon-supported metal oxide and/or alloy nanoparticle catalyst. According to the method, a carbon-supported metal oxide and/or alloy nanoparticle catalyst is prepared by depositing metal oxide and/or alloy nanoparticles on a water-soluble support and dissolving the metal oxide and/or alloy nanoparticles deposited on the water-soluble support in an anhydrous polar solvent containing carbon dispersed therein to support the metal oxide and/or alloy nanoparticles on the carbon. The anhydrous polar solvent has much lower solubility for the water-soluble support than water and is used to dissolve the water-soluble support. The use of the anhydrous polar solvent instead of water can prevent the water-soluble support present at a low concentration in the solution from impeding the support of the nanoparticles on the carbon, thus providing a solution to the problems of environmental pollution, high cost, and complexity encountered in conventional chemical and physical synthetic methods.
Use of a bifunctional catalyst based on IZM-2 with a specific Si/Al ratio for the isomerization of long paraffinic feedstocks to middle distillates
The present invention describes a process for the isomerization of paraffinic feedstocks operating at a temperature of between 200 C. and 500 C., at a total pressure of between 0.45 MPa and 7 MPa, at a hydrogen partial pressure of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kilograms of feedstock introduced per kilogram of catalyst and per hour and using a catalyst comprising at least one metal of group VIII of the periodic table of elements, at least one matrix and at least one zeolite IZM-2, in which the ratio between the number of moles of silicon and the number of moles of aluminium of the zeolite IZM-2 network is between 25 and 55, preferably between 25 and 50, and preferably between 30 and 50.
NANOPARTICLES AS CATALYTIC SUBSTRATES FOR REAL-TIME BIOSENSING OF HUMAN PERFORMANCE AND DIAGNOSTIC AND THERAPEUTIC METHODS
Nanostructures having an inorganic core and a lipid layer capable of binding a lecithin:cholesterol acyltransferase (LCAT) activator such as an apolipoprotein are provided herein. Methods of using the nanostructures and related devices and compositions for assessing the risk of developing a disease or condition or treating the disease or condition are also provided.
BIODERIVED FUELS AND METHODS OF MAKING THE SAME
The present disclosure relates to a composition that includes a first oxide having a phosphate, a ratio of Brnsted acid sites to Lewis acid sites between 0.05 and 1.00, and a total acidity between 50 mol/g and 300 mol/g, where the phosphate is at least one of a functional group covalently bonded to the first oxide and/or an anion ionically bonded to the first oxide.
Carbon Foam-Based Catalyst Support
A catalysis substrate, which includes an open cell carbon foam substrate having a geometric surface area of at least about 5000 m.sup.2/m.sup.3, wherein the substrate includes a catalytic metal.
NOVEL PGM NANOPARTICLES TWC CATALYSTS FOR GASOLINE EXHAUST GAS APPLICATIONS
A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first platinum group metal (PGM) component and a first inorganic oxide, wherein the first PGM component comprises PGM nanoparticles, wherein the PGM nanoparticles have no more than 100 PGM atoms, and wherein the PGM nanoparticles have a mean particle size of 1 nm to 10 nm with a standard deviation (SD) no more than 1 nm.
NANOPARTICLES OF CO COMPLEXES OF ZERO-VALENT METALS THAT CAN BE USED AS HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION CATALYSTS
Nanoparticles that can be used as hydrosilylation and dehydrogenative silylation catalysts. The nanoparticles have at least one transition metal with an oxidation state of 0, chosen from the metals of columns 8, 9 and 10 of the periodic table, and at least one carbonyl ligand, preferably a silicide.
Nanocatalysts for hydrocracking and methods of their use
Novel catalysts comprising nickel oxide nanoparticles supported on alumina nanoparticles, methods of their manufacture, heavy oil compositions contacted by these nanocatalysts and methods of their use are disclosed. The novel nanocatalysts are useful, inter alia, in the upgrading of heavy oil fractions or as aids in oil recovery from well reservoirs or downstream processing.
Self-adsorbed catalyst composition, method for preparing the same and method for manufacturing electroless plating substrate
The instant disclosure provides a self-adsorbed catalyst composition, a method for preparing the self-adsorbed catalyst composition and a method for manufacturing an electroless plating substrate. The self-adsorbed catalyst composition includes colloidal nanoparticles and a silane compound. The colloidal nanoparticles include palladium nanoparticles and capping agents enclosing the palladium nanoparticles. The silane compound has at least an amino group, and an interaction is established between the amino group of the silane compound and the colloidal nanoparticle.
Noble metal-promoted IN2O3 catalyst for the hydrogenation of CO2 to methanol
Method to prepare a catalyst for use in a process for the synthesis of methanol, comprising indium oxide in the form of In.sub.2O.sub.3, and at least one additional metal selected from a noble metal; and in that the average particle size of said noble metal phase is, preferably at least 0.05 nm, and less than 5 nm as determined by STEM-EDX, characterized in that the catalyst is prepared by co-precipitation of a saline solution at a pH above 8.5 comprising an indium salt and a salt of the at least one additional metal selected from a noble metal and optionally further comprising a salt of the at least one alkaline earth metal.