Patent classifications
B01J35/397
CORE-SHELL STRUCTURE SUPPORTED TUNGSTEN COMPOSITE CATALYST AND PREPARATION METHOD AND USE THEREOF
The present invention discloses a core-shell structure supported tungsten composite catalyst and a preparation method and use thereof. Most of the existing synthesis methods of the main ring of quinolone drugs have the defects of many synthesis steps, cumbersome operation, large amount of three wastes, higher costs and the like. The present invention prepares a magnetic separable core-shell supported tungsten composite catalyst, WO.sub.3/SiO.sub.2/Fe.sub.3O.sub.4, by preparing Fe.sub.3O.sub.4 colloid and SiO.sub.2/Fe.sub.3O.sub.4 composite nano-particles. This magnetic separable core-shell supported tungsten composite catalyst, WO.sub.3/SiO.sub.2/Fe.sub.3O.sub.4, is used to catalyze and synthesize quinolone compounds. The present invention provides an efficient preparation method of quinolone compounds using a catalyst which can be recovered by magnetic separation and recycled. The catalyst prepared by the present invention can be reused in the preparation of quinolone compounds and still retains the original activity without deactivation, which not only greatly improves the production efficiency, but also reduces the environmental pollution.
Cobalt-based single-atom dehydrogenation catalysts having high selectivity and regenerability and method for producing corresponding olefins from paraffins using the same
Provided is a dehydrogenation catalyst having single-atom cobalt loaded onto a support including a zirconia core surface-modified with silica, a method for producing the dehydrogenation catalyst, and a method for producing corresponding olefin through dehydrogenation of paraffin, particularly light paraffin, in the presence of the dehydrogenation catalyst.
Zirconium oxide-doped catalyst support, method for producing the same and catalyst containing a zirconium oxide-doped catalyst support
The present invention relates to a porous catalyst support, consisting of a material comprising a natural sheet silicate, containing ZrO.sub.2 dispersed throughout the material. The present invention also relates to a method for the production of the catalyst support according to the invention and to a shell catalyst containing the catalyst support according to the invention and also the use of the catalyst according to the invention in particular for the production of vinyl acetate monomer (VAM).
SHAPED POROUS CARBON PRODUCTS
Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.
STEAM REFORMING CATALYST FOR HYDROCARBONS
There is provided a steam reforming catalyst comprising a carrier and a catalyst supported thereon. The carrier contains a composite oxide containing Ce and Zr. The content of the Ce is not less than 1.0 mol and not more than 3.0 mol per 1 mol of the Zr. The catalyst contains Ni and Ti. The content of the Ni is not less than 70% and not more than 97% by mole, and the content of the Ti is not less than 3% and not more than 30% by mole, based on 100% by mole of the total of the Ni and Ti.
MULTICOMPONENT PLASMONIC PHOTOCATALYSTS CONSISTING OF A PLASMONIC ANTENNA AND A REACTIVE CATALYTIC SURFACE: THE ANTENNA-REACTOR EFFECT
A multicomponent photocatalyst includes a reactive component optically, electronically, or thermally coupled to a plasmonic material. A method of performing a catalytic reaction includes loading a multicomponent photocatalyst including a reactive component optically, electronically, or thermally coupled to a plasmonic material into a reaction chamber, introducing molecular reactants into the reaction chamber, and illuminating the reaction chamber with a light source.
GOLD-BASED CATALYST FOR OXIDATIVE ESTERIFICATION OF ALDEHYDES TO CARBOXYLIC ACID ESTERS
The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.
CATIONIC POLYMERS AND POROUS MATERIALS
According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m.sup.2/g and a pore volume of greater than 0.3 cm.sup.3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.
METHOD FOR PREPARING DEHYDROGENATION CATALYST FOR STRAIGHT CHAIN-TYPE LIGHT HYDROCARBON USING STABILIZED ACTIVE MATERIAL COMPLEX
The present invention relates to a catalyst having improved selectivity and reactivity and applied to preparing olefins by dehydrogenating C9 to C13 paraffin, and particularly to a technique for preparing a catalyst, which uses a heat-treated support having controlled pores, and most of metal components contained therein are distributed evenly in a support in the form of an alloy rather than in the form of each separate metal, thereby exhibiting high a conversion rate and selectivity when used in dehydrogenation.
Egg-shell type hybrid structure of highly dispersed nanoparticle-metal oxide support, preparation method thereof, and use thereof
The present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, a preparation method thereof, and a use thereof. Specifically, the present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, providing an excellent platform in a size of nanometers or micrometers which can support nanoparticles selectively in the porous shell portion by employing a metal oxide support with an average diameter of nanometers or micrometers including a core of nonporous metal oxide and a shell of porous metal oxides, a preparation method thereof, and a use thereof.