A method of making a xylene isomerization catalyst comprises the steps of (i) contacting a ZSM-5 zeolite starting material having a silica to alumina molar ratio of 20 to 50 and having a mesopore surface area in the range of 50 m.sup.2/gram to 200 m.sup.2/gram in a reactor with a base to provide an intermediate zeolite material; (ii) recovering the intermediate ZSM-5 zeolite material of step (i); (iii) contacting the intermediate zeolite material with an acid to provide an acid treated ZSM-5 zeolite product; (iv) recovering the acid treated ZSM-5 zeolite material; and (v) calcining the acid treated ZSM-5 zeolite material to provide a desilicated ZSM-5 zeolite product having a silica to alumina molar ratio of 20 to 150 and having a mesopore surface area in the range of 100 m.sup.2/gram to 400 m.sup.2/gram.

The present disclosure provides a catalyst for SRO reactions. The catalyst includes a solid acid material and a metal. In this case, pores of the catalyst corresponding to at least 20% of the total pore volume of the catalyst have a pore size of 10 nm or more. The present disclosure also provides a method of using the catalyst.

The present invention relates to a process for modifying the physical and chemical properties of Faujasite Y-type zeolites (FAU), mainly used as a base material of catalyst used in the Fluid Catalytic Cracking (FCC) process, for the interest of the oil refining industry, in which the conversion of oil heavy fractions into lighter fractions, with a higher commercial value, is carried out. The process produces a modified Faujasite Y-type zeolite, with lower sodium content, as low as 75%, than that of the starting Faujasite Y-type zeolite. A mesoporous material associated with the modified Faujasite Y-type zeolite has an average pore size ranging from 2 to 100 nm, having a bimodal or multimodal pore size distribution. The proportion of modified Faujasite Y-type zeolite with respect to the meso-porous material associated to the Faujasite Y type Zeolite can be regulated through the process operation conditions.

A catalyst and its use for selectively desulfurizing sulfur compounds present in an olefin-containing hydrocarbon feedstock to very low levels with minimal hydrogenation of olefins. The catalyst comprises an inorganic oxide substrate containing a nickel compound, a molybdenum compound and optionally a phosphorus compound, that is overlaid with a molybdenum compound and a cobalt compound. The catalyst is further characterized as having a bimodal pore size distribution with a large portion of its total pore volume contained in pores having a diameter less than 250 angstroms and in pores having a diameter greater than 1000 angstroms.

The catalyst in this present application includes a support and an active component dispersed on/in the support; wherein the support is at least one selected from inorganic oxides and the support contains macropores and mesopores; and the active component includes an active element, and the active element contains an iron group element. As a high temperature stable catalyst for methane reforming with carbon dioxide, the catalyst can be used to produce syngas, realizing the emission reduction and recycling utilization of carbon dioxide. Under atmospheric pressure and at 800 C., the supported metal catalyst with hierarchical pores shows excellent catalytic performance. In addition to high activity and good selectivity, the catalyst has high stability, high resistance to sintering and carbon deposition.

Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel or specialty chemical products, or for upgrading bio-oils are described. The catalyst system may comprise a non-zeolitic matrix with a hierarchical pore structure ranging from 300 to about 10.sup.4 Angstrom pore size, a zeolite, such as MFI-type or IM-5 zeolite, and a binder.

The present invention relates to a nitrous oxide decomposition catalyst, the preparation and use. The catalyst contains rhodium on a catalyst carrier. The carrier is obtained by mixing zirconium dioxide powder with a silicon compound as binder, to form a kneadable composition, homogenizing the composition, shaping the composition into shaped articles, drying and calcination, wherein the binder is selected from silicon compounds of general formulae (I) to (VI)
(Hal).sub.xSiR.sub.4-x(I)
(Hal).sub.xSi(OR.sup.1).sub.4-x(II)
(Hal).sub.xSi(NR.sup.1R.sup.2).sub.4-x(III)
RxSi(OR.sup.1)4-x(IV)
R.sub.xSi(NR.sup.1R.sup.2).sub.4-x(V)
(R.sup.1O).sub.xSi(NR.sup.1R.sup.2).sub.4-x(VI) where Hal in each occurrence is independently halogen, R in each occurrence is independently H or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, arylalkyl or aryl radical, R.sup.1 and R.sup.2 in each occurrence are each independently H or a substituted or unsubstituted alkyl, acyl, arylalkyl or aryl radical, and x is from 0 to 4.

Molybdenum sulphide containing catalysts are provided which have been produced using a microemulsion approach. The catalysts thereby produced have a unique morphology which directly translates into improved performance in the conversion of syngas to alcohol and in the selectivity of this reaction towards producing ethanol.

The present invention relates to a catalyst for decomposition of nitrous oxide and also to its method of preparation and use.

A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.