Embodiments of processes for producing propylene utilize a dual catalyst system comprising a mesoporous silica catalyst impregnated with metal oxide and a mordenite framework inverted (MFI) structured silica catalyst downstream of the mesoporous silica catalyst, where the mesoporous silica catalyst includes a pore size distribution of at least 2.5 nm to 40 nm and a total pore volume of at least 0.600 cm.sup.3/g, and the MFI structured silica catalyst has a total acidity of 0.001 mmol/g to 0.1 mmol/g. The propylene is produced from the butene stream via metathesis by contacting the mesoporous silica catalyst and subsequent cracking by contacting the MFI structured silica catalyst.

Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of titanium hydride moieties each bonded to at least two bridging oxygen atoms, wherein a titanium atom of the titanium hydride is bonded to the bridging oxygen atom, and wherein the bridging oxygen atom bridges the titanium atom of the titanium hydride moiety and a silicon atom of the microporous framework.

A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 , wherein the volume of the pores having a diameter of 30 to 40 is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 is 0.07 to 0.4 cc/g.

Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 , wherein the volume of the pores having a diameter of 30 to 40 is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 is 0.07 to 0.4 cc/g.

The present invention relates to a catalyst for the epoxidation of alkenes, comprising silver, rhenium, cesium, lithium, tungsten and sulfur on a support. The present invention further relates to a process for producing the catalyst and the use of the catalyst for the oxidation of alkylenes to alkylene oxides. In addition, the present invention relates to a process for preparing ethylene oxide from ethylene, which comprises the oxidation of ethylene with oxygen in the presence of said catalyst.

A composition comprising an extruded inorganic support comprising an oxide of a metal or metalloid, and at least one catalytically active metal, wherein the extruded inorganic support has pores, a total pore volume, and a pore size distribution, wherein the pore size distribution displays at least two peaks of pore diameters, each peak having a maximum, wherein a first peak has a first maximum of pore diameters of equal to or greater than about 120 nm and a second peak has a second maximum of pore diameters of less than about 120 nm, and wherein greater than or equal to about 5% of a total pore volume of the extruded inorganic support is contained within the first peak of pore diameters.

A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

To provide a heterogeneous catalyst that exhibits high activity and high selectivity, specifically a catalyst suitable for oxychlorination to produce 1,2-dichloroethane from ethylene, and a catalyst system. Provided are: a heterogeneous catalyst supported on a porous carrier, characterized in that the integral value of the hysteresis occurring between an adsorption isotherm and a desorption isotherm by a gas adsorption method, is at most 19% to the total integral value of the adsorption isotherm; and a catalyst system for producing 1,2-dichloroethane, which comprises this catalyst and a diluent having a spherical shape, circular cylindrical shape or hollow cylindrical shape.

Disclosed herein is an activated EU-2 zeolite, including: pores having a diameter of 30 to 40 while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 , wherein the volume of the pores having a diameter of 30 to 40 is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 is 0.07 to 0.4 cc/g.