B01J35/69

Catalyst and process for the selective conversion of hydrocarbons

A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

CATALYST IN WHICH METAL IS CARRIED ON INORGANIC POROUS BODY HAVING HIERARCHICAL POROUS STRUCTURE, AND METHOD FOR MANUFACTURING SAID CATALYST

A catalyst includes a carrier, and a metal obtained by reducing a metal ion supported on the carrier 1) in a supercritical state or 2) in a polar organic solvent, wherein the carrier is an inorganic porous body having a hierarchical porous structure. By employing the catalyst, it is possible to exhibit better catalytic activity than a conventional catalyst. Heat generation and spontaneous ignition are prevented because no organic porous body is used.

IRON-LOADED SMALL PORE ALUMINOSILICATE ZEOLITES AND METHOD OF MAKING METAL LOADED SMALL PORE ALUMINOSILICATE ZEOLITES

The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2. The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.

Catalyst for decomposition of nitrous oxide

The present invention relates to a catalyst for decomposition of nitrous oxide and also to its method of preparation and use.

Selective hydrogenation catalyst for a C3 hydrocarbon cut

A catalyst comprises an active phase constituted by palladium, and a porous support comprising at least one refractory oxide selected from the group constituted by silica, alumina and silica-alumina, in which: the palladium content in the catalyst is in the range 0.0025% to 1% by weight with respect to the total weight of catalyst; at least 80% by weight of the palladium is distributed in a crust at the periphery of the porous support, the thickness of said crust being in the range 25 to 450 m; the specific surface area of the porous support is in the range 70 to 160 m.sup.2/g; the metallic dispersion D of the palladium is less than 20%.

Extruded titania-based material comprising mesopores and macropores

Porous, extruded titania-based materials further comprising mesopores and macropores and/or prepared using one or more porogens, Fischer-tropsch catalysts comprising them, uses of the foregoing, processes for making and using the same and products obtained from such processes.

Extruded titania-based material comprising zirconium oxide

Porous, extruded titania-based materials further comprising zirconium oxide and/or prepared using ammonium zirconium carbonate, Fischer-tropsch catalysts comprising them, uses of the foregoing, processes for making and using the same and products obtained from such processes.

Process for regenerating a catalyst for the selective conversion of hydrocarbons

A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

Processes for regenerating a catalyst for the selective conversion of hydrocarbons

A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

Extruded titania-based materials comprising one or more acids or prepared using one or more acids

Porous, extruded titania-based materials further comprising one or more acids and/or prepared using one or more acids, Fischer-tropsch catalysts comprising them, uses of the foregoing, processes for making and using the same and products obtained from such processes.