B01J37/0209

Aromatization catalyst and methods of making and using same

A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.

CATALYST AND METHOD RELATED THERETO FOR THE SYNTHESIS OF HYDROCARBONS FROM SYNGAS
20220118436 · 2022-04-21 ·

The present disclosures and inventions relate to a catalyst and methods for making same, which are useful in Fischer-Tropsch reactions.

A CATALYST COMPOSITION AND METHOD OF MAKING THEREOF FOR PURE HYDROGEN PRODUCTION

The present invention provides an impregnated catalyst composition for production of pure hydrogen comprising: 10 wt %-50 wt % metal oxide; 1 wt %-15 wt % promoter; and 60 wt %-90 wt % support material. Another aspect of the present invention is to provide a method of preparation of an impregnated catalyst for pure hydrogen production (10) and a method for producing pure hydrogen (20) according to the impregnated catalyst of the present invention. The present invention is able to reduce the reaction temperature by 1 to 2 folds and also able to reduce the usage of energy but maintain its good production quality. Besides, selectivity of the present invention is high, hence able to produce high purity of hydrogen.

Cobalt-based single-atom dehydrogenation catalysts having improved thermal stability and method for producing olefins from corresponding paraffins by using the same

Disclosed herein are a dehydrogenation catalyst having single-atom cobalt loaded onto a silica support that has undergone pretreatment including a thermal treatment and a high-temperature aqueous treatment (reaction), a preparation method therefor, and a method for producing olefins by dehydrogenating corresponding paraffins, particularly light paraffins in the presence of the dehydrogenation catalyst.

AMMOXIDATION CATALYST FOR PROPYLENE, MANUFACTURING METHOD OF THE SAME CATALYST, AMMOXIDATION METHOD USING THE SAME CATALYST
20220023837 · 2022-01-27 ·

There are provided an ammoxidation catalyst for propylene, a manufacturing method of the same, and an ammoxidation method of propylene using the same. Specifically, according to one embodiment of the invention, a catalyst is realized with a structure in which metal oxide is supported on a silica carrier, and thus, using mesopores useful for adsorption and desorption of gas, a high reaction surface area can be provided, and ultimately, ammoxidation of propylene can be increased.

PHOSPHATE-PROMOTED NICKEL CATALYST FOR HIGH TEMPERATURE OLIGOMERIZATION

An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500° C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170° C. to 360° C.

Metal single-atom catalyst and method for preparing the same

Disclosed are a metal single-atom catalyst and a method for preparing the same. The method uses a minimal amount of chemicals and is thus environmentally friendly compared to conventional chemical and/or physical methods. In addition, the method enables the preparation of a single-atom catalyst in a simple and economical manner without the need for further treatment such as acid treatment or heat treatment. Furthermore, the method is universally applicable to the preparation of single-atom catalysts irrespective of the kinds of metals and supports, unlike conventional methods that suffer from very limited choices of metal materials and supports. Therefore, the method can be widely utilized to prepare various types of metal single-atom catalysts. All metal atoms in the metal single-atom catalyst can participate in catalytic reactions. This optimal atom utilization achieves maximum reactivity per unit mass and can minimize the amount of the metal used, which is very economical.

Method for manufacturing catalysis reactant having high efficiency catalysis for thermal reaction
11219890 · 2022-01-11 · ·

A method for manufacturing a catalysis reactant having high efficiency catalysis for thermal reaction primarily includes: preparing a three-dimensional catalysis carrier; preparing at least one aqueous-phase nanometer metallic particle solution; soaking the catalysis carrier in a methanol solution containing a silane group compound and removing and subjecting the catalysis carrier to drying and freezing for surface modification; soaking the catalysis carrier in the aqueous-phase nanometer metallic particle solution and removing and subjecting the catalysis carrier to blow-drying to have the surface of the catalysis carrier combined with a first layer of nanometer metallic particles; soaking the catalysis carrier in a methanol solution containing 1,12-diaminododecane to carry out surface modification and removing and subjecting the catalysis carrier to drying, followed by soaking in the aqueous-phase nanometer metallic particle solution and then blow-drying to have the surface of the catalysis carrier further combined with a second layer of nanometer metallic particles.

Preparation method for olefin epoxidation catalyst and applications thereof

Disclosed in the present invention are a preparation method for an olefin epoxidation catalyst and applications thereof. The method comprises: loading an auxiliary metal salt onto a silica gel carrier, and carrying out a drying treatment to the silica gel carrier; loading a titanium salt (preferably TiCl.sub.4) onto the silica gel carrier by a chemical vapor deposition method; calcining to obtain a silica gel on which the auxiliary metal oxide and Ti species are loaded; obtaining an catalyst precursor (Ti-MeO—SiO.sub.2 composite oxide) by water vapor washing; loading alkyl silicate (preferably tetraethyl orthosilicate) onto the surface of the catalyst precursor by a chemical vapor deposition method and calcining the catalyst precursor to obtain a Ti-MeO—SiO.sub.2 composite oxide with the surface coated with a SiO.sub.2 layer; and carrying out a silylanization treatment to obtain the catalyst. The catalyst can be applied to a chemical process of propylene epoxidation to prepare propylene oxide, and has an average selectivity to PO up to 96.7%, the method of the present invention and the applications thereof have industrial application prospects.

PROCESS AND CATALYST FOR OXIDATIVE ESTERICATION WITH MECHANICALLY STRONG AND CHEMICALLY RESISTANT CATALYST

A catalyst comprising a noble metal disposed on a support. The noble metal is present in an amount ranging from 0.1 wt % to 10 wt % relative to the total weight of the catalyst. The support comprises at least 50 wt % silicon carbide relative to the total weight of the support. The silicon carbide has a surface area of at least 5 m.sup.2/g. A method for preparing methyl methacrylate from methacrolein and methanol using the catalyst is also disclosed.