An electride, which is more stable and can be more easily obtained, is provided or is made available, and as a result, a catalyst particularly useful for chemical synthesis, in which the electride is particularly used, is provided. A transition metal-supporting intermetallic compound having a transition metal supported on an intermetallic compound represented by the following formula (1): A.sub.5X.sub.3 . . . (1) wherein A represents a rare earth element, and X represents Si or Ge.

A reactor system for treating contaminated water is disclosed. The reactor system includes a reactor vessel having first and second end portions and an internal reactor volume defined by interior surfaces of the reactor vessel. A fluoropolymer coating is applied over at least a portion of the interior surfaces of the reactor vessel. The reactor system also includes a water inlet disposed in the first end portion and a water outlet disposed in the second end portion. At least one ultraviolet light-emitting diode (LED) is included and disposed so as to project ultraviolet light into the reactor vessel. A plurality of photo-catalyst substrates are also disposed within the internal reactor volume of the reactor vessel. Each of these substrates includes a coating of titanium dioxide applied to an outer surface of a substrate. A method for remediating contaminated water is also disclosed.

The present invention provides catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article catalyst article comprises: a substrate which is a wall-flow filter having an inlet end and an outlet end and an axial length L therebetween, a plurality of inlet channels extending from the inlet end and a plurality of outlet channels extending from the outlet end, wherein the plurality of inlet channels comprise a first catalyst composition extending from the inlet or outlet end for at least 50% of L and the plurality of outlet channels comprise a second catalyst composition extending from the outlet or inlet end for at least 50% of L, wherein the first and second catalyst compositions overlap by at most 80% of L, and wherein the first and second catalyst compositions each independently comprise a particulate oxygen storage component (OSC) having a first D90 and a particulate inorganic oxide having a second D90 and: i) the first D90 is less than 1 micron and the second D90 is from 1 to 20 microns; or ii) the second D90 is less than 1 micron and the first D90 is from 1 to 20 microns.

Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum impregnated on an oxygen storage component and rhodium impregnated on a zirconia-coated or yttria-coated alumina. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved reductions in NOx in exhaust gases, particularly after lean-rich aging.

A three-way catalyst for purifying exhaust including noble metal components, enables sintering of the noble metal to be suppressed even at high temperature, enables carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx) to be removed and a method for purifying exhaust gas. A carrier having a honeycomb structure is coated with two or more layers of the catalyst compositions, an upper layer including a heat resistant inorganic oxide supporting Pd and a La-containing oxide, a lower layer including a heat resistant inorganic oxide supporting Rh. The content of La in terms of La.sub.2O.sub.3 is 9.6 g/L to 23 g/L, the content of Ce in terms of CeO.sub.2 is 5 g/L to 20 g/L, and the content of Ba in terms of BaO is 1.2 g/L or less per unit volume of the honeycomb structure.

A method can prepare a metal/metal oxide material from a nanostructure. The nanostructure can contain a first metal to form the metal oxide, and a reaction surface with a reducing agent on the reaction surface. A second metal is deposited onto the reaction surface to form a bimetallic product. The bimetallic product is calcined to form the metal/metal oxide material.

An object is to produce a titanium material with a crystalline titanium oxide film formed on the surface thereof. The titanium material with a crystalline titanium oxide film formed on the surface thereof is useful as a photocatalyst material, a photoelectric conversion element material, a wear-resistant member, an edible oil deterioration-preventing member, and the like that have high functionality.

Provided is a method for producing a titanium material with a crystalline titanium oxide film formed on the surface thereof, the method comprising: (1) performing roughening treatment on the surface of a titanium material to form a roughened material, (2) forming a titanium compound on the surface of the roughened material obtained in step (1), (3) performing anodizing treatment on the material with the titanium compound formed on the surface thereof to form an amorphous titanium oxide film, and (4) performing heat treatment on the material with the amorphous titanium oxide film formed on the surface thereof in an air atmosphere at a temperature of 300 C. or more to form a crystalline titanium oxide film.

Catalysts for NH.sub.3 cracking and/or synthesis generally include barium calcium aluminum oxide compounds decorated with ruthenium, cobalt, or both. These catalysts can be bonded to a metal structure, which improves thermal conductivity and gas conductance.

Provided herein is a novel process for producing shaped catalyst bodies in which a mixture having aluminum contents of Al.sup.=.sup.0 in the range from 80 to 99.8% by weight, based on the mixture used, is used to form a specific intermetallic phase, shaped catalyst bodies obtainable by the process of the invention, a process for producing an active catalyst fixed bed including the shaped catalyst bodies provided herein, the active catalyst fixed beds and also the use of these active catalyst fixed beds for the hydrogenation of organic hydrogenatable compounds or for formate degradation.

The present application relates to a process for producing normally gaseous, normally liquid, and optionally normally solid hydrocarbons from synthesis gas in a three-phase reactor, said reactor comprising a top middle and bottom part wherein the bottom and top part are fluidly connected via one or more reactor tubes, wherein one or more reactor tubes comprise randomly stacked catalyst bodies held stationary in the reactor tube and the reactor is at least partially filled with a liquid medium, said process comprising the steps of: (i) introducing the synthesis gas into the reactor via the bottom part; and (ii) contacting the synthesis gas with a stationary catalyst to catalytically convert the synthesis gas at an elevated temperature to obtain the normally gaseous, normally liquid, and optionally normally solid hydrocarbons from synthesis gas; (iii) withdrawing the normally gaseous, normally liquid, and optionally normally solid hydrocarbons; wherein the catalyst bodies have an open celled foam structure.