Patent classifications
B01J37/0225
NICKEL-BASED MOF FILM PHOTOCATALYST GROWN IN-SITU ON FOAMED NICKEL SURFACE, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF
A nickel-based MOF film photocatalyst grown in-situ on a foamed nickel surface, a preparation method therefor, and an application thereof. The nickel-based MOF film photocatalyst grown in-situ on a foamed nickel surface is prepared by first immersing foamed nickel in a diluted acid and performing ultrasonic processing, then cleaning the foamed nickel with deionized water, and drying the foamed nickel to obtain surface-activated foamed nickel; immersing the surface-activated nickel foam in a mixture of an imidazole compound, sodium formate, and a solvent and reacting at 100° C. to 180° C. to obtain an unactivated nickel-based MOFs film on the surface of the foamed nickel, and after cooling to room temperature, removing same and soaking in an organic solvent to activate, and then drying the obtained product. The film photocatalyst synthesized in-situ on the foamed nickel can increase the specific surface area of the material to facilitate the adsorption and diffusion of VOCs, and can expose more catalytic sites, so that the VOCs can be effectively degraded under the action of sunlight.
Catalysts and processes for the direct production of liquid fuels from carbon dioxide and hydrogen
Embodiments of the present invention relates to two improved catalysts and associated processes that directly converts carbon dioxide and hydrogen to liquid fuels. The catalytic converter is comprised of two catalysts in series that are operated at the same pressures to directly produce synthetic liquid fuels or synthetic natural gas. The carbon conversion efficiency for CO.sub.2 to liquid fuels is greater than 45%. The fuel is distilled into a premium diesel fuels (approximately 70 volume %) and naphtha (approximately 30 volume %) which are used directly as “drop-in” fuels without requiring any further processing. Any light hydrocarbons that are present with the carbon dioxide are also converted directly to fuels. This process is directly applicable to the conversion of CO.sub.2 collected from ethanol plants, cement plants, power plants, biogas, carbon dioxide/hydrocarbon mixtures from secondary oil recovery, and other carbon dioxide/hydrocarbon streams. The catalyst system is durable, efficient and maintains a relatively constant level of fuel productivity over long periods of time without requiring re-activation or replacement.
Method for preparing ternary alloy catalyst with polydopamine coating and ternary alloy catalyst prepared thereby
Disclosed is a method for preparing a ternary alloy catalyst with polydopamine coating and a ternary alloy catalyst prepared thereby. The method for preparing a ternary alloy catalyst according to the present disclosure may provide a ternary alloy catalyst with increased resistance to carbon monoxide (CO) poisoning in which polydopamine is utilized as a coating material for a ternary alloy catalyst having a core-shell structure containing platinum to suppress the growth of particles during subsequent high-temperature heat treatment, and nickel (Ni), which is a transition metal, is diffused inside to form a core, thereby effectively preventing elution of nickel under an acidic condition.
Method and apparatus for manufacturing core-shell catalyst
The present disclosure relates to a method and an apparatus for manufacturing a core-shell catalyst, and more particularly, to a method and an apparatus for manufacturing a core-shell catalyst, in which a particle in the form of a core-shell in which the metal nanoparticle is coated with platinum is manufactured by substituting copper and platinum through a method of manufacturing a metal nanoparticle by emitting a laser beam to a metal ingot, and providing a particular electric potential value, and as a result, it is possible to continuously produce nanoscale uniform core-shell catalysts in large quantities.
Electrodeposition system
An electrocoat system for electrodeposition is described. The system includes an inorganic bismuth-containing compound or a mixture of inorganic and organic bismuth-containing compounds. The system demonstrates a high degree of crosslinking and produces a cured coating with optimal crosslinking and corrosion resistance.
Metal powderdous catalyst for hydrogenation processes
The present invention relates to a metal powder catalyst and its use in the selective catalytic hydrogenation of organic starting materials comprising a carbon-carbon triple bond. The powder catalyst comprises a metal alloy carrier, wherein the metal alloy comprises (i) 55 weight-% (wt-%)-80 wt-%, based on the total weight of the metal alloy, of Co, and (ii) 20 wt-%-40 wt-%, based on the total weight of the metal alloy, of Cr, and (iii) 2 wt-%-10 wt-%, based on the total weight of the metal alloy, of Mo, and wherein the said metal alloy is coated by a metal oxide layer and impregnated with Pd, and is characterized in that the metal oxide layer comprises CeO.sub.2.
DENITRATION CATALYST STRUCTURE
Denitration catalyst unit, comprising two or more platy catalyst elements, wherein the platy catalyst element has an edge located on gas-inflow side, an edge located on gas-outflow side and edges located on either side of the platy catalyst element, the platy catalyst elements are piled so as to align the edges located on gas-inflow side and the edges located on either side of the platy catalyst elements respectively, each of the platy catalyst elements alternately has more than one flat part in the shape of a flat plate and more than one concavo-convex part in the shape of platy convex strips on the upper and lower surfaces, the platy convex strips are parallel to one another and are obliquely disposed at an angle θ of not less than 50° and not more than 85° to an extending direction of the edge located on gas-inflow side of the platy catalyst element so that a ridge of the platy convex strip on the upper surface of one of the platy catalyst elements intersects with a ridge of the platy convex strip on the lower surface of another of the platy catalyst elements adjacent, at least one of the intersection points is within a range x of more than 0 mm and less than 25 mm inward from the edge located on gas-inflow side of the platy catalyst element.
COMPOSITIONS, METHODS, AND APPARATUSES FOR CATALYTIC COMBUSTION
There is provided a catalyst composition including a hydrogen oxidation catalyst and an oxygen reduction catalyst. Heat exchange reactors including the catalyst are also provided. The catalyst is adapted for low temperature activation of a hydrogen combustion reaction.
Microscale chemical reactors
A catalytic microscale reactor with spiral reactor geometry may have a high surface area to volume ratio, high catalytic surface area, high heat transfer surface area, long residence time, and high single pass conversion. The catalytic surface may be treated with microsphere spacer particles which serve to maintain the space between them at an engineered distance without the need for precise manufacturing techniques. The design of the reactor may allow for a catalyst surface to be removed, uncoiled, refurbished, and recoiled in an automated continuous process. An automated continuous process may be suitable both for initially preparing a new catalytic surface as well as refurbishing a fouled catalytic surface and may reduce the time and cost to prepare a new surface.
METHOD FOR FORMING CATALYTIC NANOCOATING
Provided is a method forming a catalytic nanocoating on a surface of a metal plate, wherein the method comprises pretreating the surface of the metal plate by means of heat treatment at 500-800° C., forming a metaloxide support by washcoating on the surface of the metal plate, and coating the surface of the metal plate by depositing catalytically active metals and/or metaloxides on the metaloxide support by means of an atomic layer deposition (ALD) method in order to form a thin and conformal catalyst layer on the metal plate. Further, the invention relates to a catalyst and a use.