Patent classifications
B01J37/0246
AMMONIA ADSORPTION CATALYST AND PREPARATION METHOD AND USE THEREOF
An ammonia adsorption catalyst and a preparation method and a use thereof, where the ammonia adsorption catalyst includes a substrate and an adsorption layer located on the surface of the substrate, and the adsorption layer includes a noble metal-containing zeolite adsorption material. The catalyst has the advantages of high ammonia adsorption/conversion efficiency, low cost, and flexible application, etc.
NITROUS OXIDE REMOVAL CATALYSTS FOR EXHAUST SYSTEMS
A nitrous oxide (N.sub.2O) removal catalyst composite is provided, comprising a N.sub.2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H.sub.2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H.sub.2-TPR). Methods of making and using the same are also provided.
Honeycomb catalyst body
The honeycomb catalyst body is equipped with a honeycomb structure body having partition walls that define a plurality of cells extending from a first end face as one of the end faces to a second end face as the other end face and serving as through channels of a fluid. The partition walls each have a base layer containing from 50 to 90 mass % of zeolite and a coat layer with which the surface of the base layer 11 is coated with a thickness of from 1 to 50 μm. The coat layer is either a coat layer (A) containing from 1 to 5 mass % vanadia and titania or a coat layer (B) containing from 1 to 5 mass % vanadia and a composite oxide of titania and tungsten oxide.
COMPRESSED NATURAL GAS COMBUSTION AND EXHAUST SYSTEM
The present invention relates to a compressed natural gas combustion and exhaust system comprising: (i) a natural gas combustion engine; and (ii) an exhaust treatment system, the exhaust treatment system comprising a intake for receiving an exhaust gas from the combustion engine and a catalyst article arranged to receive and treat the exhaust gas, wherein the catalyst article comprises: a substrate having at least first and second coatings, the first coating being free from platinum-group-metals and comprising a copper-containing zeolite having the CHA framework-type and the second coating comprising a palladium-containing zeolite, wherein the first coating is arranged to contact the exhaust gas before the second coating. The present invention further relates to a method and a use.
RAPID SYNTHESIS OF A CATALYST COMPRISING A ZEOLITE HAVING AN AFX STRUCTURE AND AT LEAST ONE TRANSITION METAL FOR SELECTIVE NOX REDUCTION
A catalyst based on a zeolite of AFX structural type and on at least one transition metal, can be prepared by a process comprising at least the following steps: i) mixing, in an aqueous medium, of at least one source of silicon in oxide form SiO2, of at least one source of aluminium in oxide form Al2O3, of an organic nitrogen-comprising compound R, of at least one source of at least one alkali metal and/or alkaline-earth metal M until a homogeneous precursor gel is obtained; ii) hydrothermal treatment of said precursor gel to obtain a crystallized solid phase, iii) at least one ion exchange with a transition metal; iv) heat treatment. The catalyst can be used for the selective reduction of NOx employing the catalyst, and can achieve an NOx conversion (conversion=(NOx inletNOx outlet)/NOx inlet) of 100% at a temperature of 430 C. or lower.
CATALYTIC MATERIAL FOR TREATING AN EXHAUST GAS PRODUCED BY A NATURAL GAS ENGINE
The present invention relates to a catalytic material for treating an exhaust gas produced by a natural gas engine, which catalytic material comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen and germanium, and has a content of heteroatom T-atoms of ≤about 0.20 mol %, wherein the germanium is present in an amount of from 15 to 20 mol %. The present invention further relates to a catalyst article and a compressed natural gas combustion and exhaust system.
CATALYTIC MATERIAL FOR TREATING AN EXHAUST GAS PRODUCED BY A NATURAL GAS ENGINE
The present invention relates to a catalytic material for treating an exhaust gas produced by a natural gas engine, which catalytic material comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen, titanium and optionally germanium, and has a content of non-titanium heteroatom T-atoms of ≤ about 0.20 mol %, wherein the titanium is present in an amount of from 1 to 3 mol %. The present invention further relates to a catalyst article and to a compressed natural gas combustion and exhaust system.
CATALYST MANUFACTURING METHOD
A method for producing a catalyst or catalyst precursor is described including: applying a slurry of a particulate catalyst compound in a carrier fluid to an additive layer manufactured support structure to form a slurry-impregnated support, and drying and optionally calcining the slurry-impregnated support to form a catalyst or catalyst precursor. The mean particle size (D50) of the particulate catalyst compound in the slurry is in the range 1-50 μm and the support structure has a porosity ≧0.02 ml/g.
HIGH-SILICA AFX FRAMEWORK TYPE ZEOLITES
An AFX framework type zeolite having a SiO.sub.2/Al.sub.2O.sub.3 molar ratio of greater than 50 is disclosed. The high-silica AFX framework type zeolite is synthesized from a reaction mixture having high silica and low hydroxide concentrations in the presence of an organic structure directing agent comprising 1,3-bis(1-adamantyl)imidazolium cations.
Enhanced soot oxidation on particulate filter using ceria-based catalyst and zone coating strategy
An improved SCRoF (selective catalytic reduction on filter) device for treating exhaust from an internal combustion engine. The filter has numerous entry and exit channels. Exhaust enters the entry channels and flows through side walls into the exit channels. Relative to the exhaust flow path, these side walls are coated on the downstream side with a ceria-based catalyst and on the upstream side with a Cu-zeolite catalyst. This allows the filter to optimally achieve both particulate matter oxidation and NOx reduction, respectively.