The present invention relates to catalytically active material, comprising grains of non-graphitizing carbon with cobalt nanoparticles dispersed therein, wherein d.sub.p, the average diameter of cobalt nanoparticles in the non-graphitizing carbon grains, is in the range of 1 nm to 20 nm, D, the average distance between cobalt nanoparticles in the non-graphitizing carbon grains, is in the range of 2 nm to 150 nm, and ω, the combined total mass fraction of metal in the non-graphitizing carbon grains, is in the range of 30 wt % to 70 wt % of the total mass of the non-graphitizing carbon grains, and wherein d.sub.p, D and ω conform to the following relation: 4.5 d.sub.p/ω>D≥0.25 d.sub.p/ω. The present invention, further, relates to a process for the manufacture of material according to the invention, as well as its use as a catalyst.

The present invention belongs to the technical field of functional organic macromolecule composite catalysts and involves the preparation of a nitrogen-doped lattice macromolecule composite loaded with an efficient denitrification and sulfur resistance catalyst, firstly using the method of adding metal salts to make a large amount of Ce.sup.3+, Ce.sup.4+, Sn.sup.3+ and Sn.sup.4+ ions accumulate around the cyanuric acid molecule. Afterwards, 2,4,6-triaminopyrimidine and cytosine were added to graft with the cyanuric acid to produce the N-doped macromolecule in the first stage. After that, potassium permanganate was used as the oxidizing agent, and redox reaction occurred on the surface of N-doped macromolecules, so that the manganese cerium tin catalyst was grown in situ on the surface of N-doped macromolecules, and finally calcined at once to cross-link the N-doped macromolecules to generate catalyst composites. The catalysts described in this invention have higher efficient NOx reduction and sulfur resistance performance.

The present disclosure relates to a dissimilar metal-doped cerium oxide including cerium oxide and a dissimilar metal other than the cerium oxide, in which a relationship of the following formula (1) is satisfied:

0.8≤|(D90)−(D10)|/D50≤2.0  (1) (in the formula (1), D10, D50, and D90 respectively represent the following: D10: particle diameter at which cumulative volume fraction is 10% D50: particle diameter at which cumulative volume fraction is 50% D90: particle diameter at which cumulative volume fraction is 90%).

Provided herein are TiO.sub.2-x nanoparticles and materials that show unusual photophysical and optical properties. These TiO.sub.2-x particles and materials can be used as efficient photocatalysts for the reduction of CO.sub.2 with H.sub.2O to produce CH.sub.4. Also provided herein are methods of making TiO.sub.2-x nanoparticles using a polymer-derived mesoporous carbon (PDMC) as a template.

The invention relates to a process for preparing aluminates of the general formula (I)

A.sub.1B.sub.xAl.sub.12-xO.sub.19-y where A is at least one element from the group consisting of Sr, Ba and La, B is at least one element from the group consisting of Mn, Fe, Co, Ni, Rh, Cu and Zn, x=0.05-1.0, y is a value determined by the oxidation states of the other elements, which comprises the steps (i) provision of one or more solutions or suspensions comprising precursor compounds of the elements A and B and also a precursor compound of aluminum in a solvent, (ii) conversion of the solutions or suspensions or the solutions into an aerosol, (iii) introduction of the aerosol into a directly or indirectly heated pyrolysis zone, (iv) carrying out of the pyrolysis and (v) separation of the resulting particles comprising hexaaluminate of the general formula (I) from the pyrolysis gas.

An ammonia synthesis catalyst having high activity is obtained by having a two-dimensional electride compound having a lamellar crystal structure such as Ca.sub.2N support a transition metal. However, since the two-dimensional electride compound is unstable, the stability of the catalyst is low. In addition, in cases where a two-dimensional electride compound is used as a catalyst support, it is difficult to shape the catalyst depending on reactions since the two-dimensional electride compound has poor processability. A composite which includes a transition metal, a support and a metal amide compound, wherein the support is a metal oxide or a carbonaceous support; and the metal amide compound is a metal amide compound represented by general formula (1). M(NH.sub.2).sub.x . . . (1) (In general formula (1), M represents at least one metal atom selected from the group consisting of Li, Na, K, Be, Mg, Ca, Sr, Ba and Eu; and x represents the valence of M.)

An organic nanofiber includes a fiber body containing multiple inorganic oxide particles selected from polycrystalline titanium dioxide particles and polycrystalline tin(IV) oxide particles, and having a particle size ranging from 15 to 75 nm. A method for manufacturing the inorganic nanofibers, including: mixing a metal precursor, an organic polymer and a solvent to obtain a solution, the metal precursor being a titanium-containing precursor or a tin-containing precursor; electrospinning the solution at a relative humidity ranging from 50 to 60% to form multiple nanofibers; and annealing the nanofibers at a temperature ranging from 600 to 800° C. to obtain multiple inorganic nanofibers.

A method of preparing a catalyst comprising a) contacting a non-aqueous solvent, a carboxylic acid, and a chromium-containing compound to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst. A method of preparing a catalyst comprising a) contacting a non-aqueous solvent and a carboxylic acid to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed chrominated silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst.

The present disclosure relates to a method for producing a porous metal oxide powder, and more particularly, to a method for producing a porous metal oxide powder including obtaining metal oxide precipitate slurry from an aqueous metal salt solution dissolving a water-soluble metal salt in water; solvent exchanging the water by mixing a butanol solvent and the metal oxide precipitate slurry; and drying the solvent exchanged metal oxide under atmospheric pressure conditions.

An exhaust system for an internal combustion engine, the exhaust system comprising, a lean NO.sub.x trap (LNT), a wall flow monolithic substrate having a NO.sub.x storage and reduction zone thereon, the wall flow monolithic substrate having a pre-coated porosity of 40% or greater, the NO.sub.x storage and reduction zone comprising a platinum group metal loaded on a first support, the first support comprising one or more alkaline earth metal compounds, a mixed magnesium/aluminium oxide, cerium oxide, and at least one base metal oxide selected the group consisting of copper oxide, manganese oxide, iron oxide and zinc oxide.