B01J38/14

Integrated C3—C4 hydrocarbon dehydrogenation process
10590048 · 2020-03-17 · ·

An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.

Integrated C3—C4 hydrocarbon dehydrogenation process
10590048 · 2020-03-17 · ·

An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.

Processes for controlling the partial regeneration of spent catalyst from an MTO reaction
10589264 · 2020-03-17 ·

A method of controlling the regeneration of spent catalyst from an oxygenate-to-olefin reaction zone in order to provide a partially regenerated catalyst. The partially regenerated catalyst has between 1 to 4, or 1 to 3, or, 2 to 3 wt % coke. The regeneration is controlled by adjusting a ratio of air to recycled flue gas in the combustion gas passed to the regeneration zone. CO in the flue gas is removed in a CO oxidation zone which receives oxygen to oxidize CO to CO.sub.2.

Processes for controlling the partial regeneration of spent catalyst from an MTO reaction
10589264 · 2020-03-17 ·

A method of controlling the regeneration of spent catalyst from an oxygenate-to-olefin reaction zone in order to provide a partially regenerated catalyst. The partially regenerated catalyst has between 1 to 4, or 1 to 3, or, 2 to 3 wt % coke. The regeneration is controlled by adjusting a ratio of air to recycled flue gas in the combustion gas passed to the regeneration zone. CO in the flue gas is removed in a CO oxidation zone which receives oxygen to oxidize CO to CO.sub.2.

A CATALYTIC PROCESS FOR CO-PRODUCTION OF BENZENE, ETHYLENE, AND HYDROGEN
20200078778 · 2020-03-12 ·

A process for the production of benzene and ethylene from an alkane-containing gas stream. The alkane-containing gas stream may be contacted, in a reaction zone of a reactor under alkane aromatization conditions, with an aromatization catalyst including any combination of fresh, spent, and regenerated catalyst to produce an outlet stream including (i) spent catalyst and (ii) a product mixture including benzene and ethylene. The spent catalyst may be regenerated in a regeneration zone under regeneration conditions to produce the regenerated catalyst. A selected amount of fresh catalyst may be added to the regeneration zone to produce the mixture of fresh catalyst and regenerated catalyst, which may be recycled to the reaction zone. A ratio of benzene to ethylene in the product mixture may be controlled by modifying the alkane aromatization conditions, the regeneration conditions, and/or the selected amount of fresh catalyst added to the regeneration zone.

FLUID CATALYTIC CRACKING (FCC) PROCESS AND APPARATUS FOR PRODUCTION OF LIGHT OLEFINS

The instant disclosure provides a composition for fluid catalytic cracking of petroleum based feedstock into useful short chain olefins. The composition comprising: 76-86% of a non-zeolitic material; and 2-30% of at least one zeolite material, the percentage being based on weight of the catalyst composition, wherein one of the zeolites has been modified with 0.1-2.5 wt % metal. The said catalyst was found to be selective in enhancing the usable propylene gas content, while reducing the undesirable dry gas content of the cracked olefinic products. The present disclosure also provides a process for the preparation of the composition. The present disclosure also provides an apparatus (100) and process (200) for fluid catalytic cracking to obtain light olefins. The apparatus comprises a second riser (33) that includes a lower dense riser (2) and upper dilute riser (3). Further, the lower dense riser (2) has a diameter that is 1.1 to 2 times that of the upper dilute riser (3).

PROCESSES FOR CONTROLLING THE PARTIAL REGENERATION OF SPENT CATALYST FROM AN MTO REACTION
20200047174 · 2020-02-13 ·

A method of controlling the regeneration of spent catalyst from an oxygenate-to-olefin reaction zone in order to provide a partially regenerated catalyst. The partially regenerated catalyst has between 1 to 4, or 1 to 3, or, 2 to 3 wt % coke. The regeneration is controlled by adjusting a ratio of air to recycled flue gas in the combustion gas passed to the regeneration zone. CO in the flue gas is removed in a CO oxidation zone which receives oxygen to oxidize CO to CO.sub.2.

PROCESSES FOR CONTROLLING THE PARTIAL REGENERATION OF SPENT CATALYST FROM AN MTO REACTION
20200047174 · 2020-02-13 ·

A method of controlling the regeneration of spent catalyst from an oxygenate-to-olefin reaction zone in order to provide a partially regenerated catalyst. The partially regenerated catalyst has between 1 to 4, or 1 to 3, or, 2 to 3 wt % coke. The regeneration is controlled by adjusting a ratio of air to recycled flue gas in the combustion gas passed to the regeneration zone. CO in the flue gas is removed in a CO oxidation zone which receives oxygen to oxidize CO to CO.sub.2.

Composite catalyst, method for producing composite catalyst, method for producing lower olefin and method for regenerating composite catalyst

A lower olefin by using a zeolite catalyst, a composite catalyst capable of further extending the lifetime of catalytic activity, a method for producing the composite catalyst, a method for producing a lower olefin by using the composite catalyst, and a method for regenerating a composite catalyst in the method for producing a lower olefin are provided. The composite catalyst is a catalyst for producing a lower olefin from a hydrocarbon feedstock. This composite catalyst is constituted of a zeolite being a crystalline aluminosilicate containing gallium and iron or iron and further having a framework with 8- to 12-membered ring, and of silicon dioxide. By using the composite catalyst, a lower olefin can be continuously produced over a long period of time.

Method and device for the desulphurisation of a gas flow

A method and device for the desulphurisation of a hydrogen sulphide-containing gas flow, in particular for combustion in a gas turbine, wherein the gas flow is brought into contact with a washing agent containing a catalytically active component for the absorption of the hydrogen sulphide and forming elementary sulphur, wherein the catalytically active component is reduced in the formation of the elementary sulphur, wherein the washing medium containing the reduced catalytically active component is supplied to a regeneration stage, in which the reduced catalytically active component is converted back via oxidation with an oxygen-containing gas supplied to the regeneration stage, and wherein the oxygen-containing gas is supplied to the regeneration stage from a compressor of a gas turbine. Air from the compressor of a gas turbine is used for purifying a washing medium used for the desulphurisation of a gas flow.