B01J38/44

Catalyst regeneration

The present disclosure provides an air-soak containing regeneration process reducing its time. The process includes (i) removing surface carbon species from a gallium-based alkane dehydrogenation catalyst in a combustion process in the presence of a fuel gas; (ii) conditioning the gallium-based alkane dehydrogenation catalyst after (i) in air-soak treatment at a temperature of 660 C. to 850 C. with (iii) a flow of oxygen-containing gas having (iv) 0.1 to 100 parts per million by volume (ppmv) of a chlorine source selected from chlorine, a chlorine compound or a combination thereof; and achieving a predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iv) 10% to 50% sooner in air-soak treatment than that required to achieve the same predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iii), but without (iv).

Catalyst regeneration

The present disclosure provides an air-soak containing regeneration process reducing its time. The process includes (i) removing surface carbon species from a gallium-based alkane dehydrogenation catalyst in a combustion process in the presence of a fuel gas; (ii) conditioning the gallium-based alkane dehydrogenation catalyst after (i) in air-soak treatment at a temperature of 660 C. to 850 C. with (iii) a flow of oxygen-containing gas having (iv) 0.1 to 100 parts per million by volume (ppmv) of a chlorine source selected from chlorine, a chlorine compound or a combination thereof; and achieving a predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iv) 10% to 50% sooner in air-soak treatment than that required to achieve the same predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iii), but without (iv).

Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.

Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.

Methods and reforming systems for re-dispersing platinum on reforming catalyst

Methods and systems for re-dispersing platinum on catalysts used in continuous catalyst regeneration reformer systems are disclosed. Some aspects of the disclosure provide, for example, methods of evaluating the platinum re-dispersion of a reforming catalyst in a small-scale reactor for use in a continuous catalyst regeneration reformer system and methods of improving the activity and selectivity of reforming catalysts for use in a continuous catalyst regeneration reformer system by selection of appropriate reaction parameters in a small-scale reactor for use in a continuous catalyst regeneration reformer system.

Methods and reforming systems for re-dispersing platinum on reforming catalyst

Methods and systems for re-dispersing platinum on catalysts used in continuous catalyst regeneration reformer systems are disclosed. Some aspects of the disclosure provide, for example, methods of evaluating the platinum re-dispersion of a reforming catalyst in a small-scale reactor for use in a continuous catalyst regeneration reformer system and methods of improving the activity and selectivity of reforming catalysts for use in a continuous catalyst regeneration reformer system by selection of appropriate reaction parameters in a small-scale reactor for use in a continuous catalyst regeneration reformer system.

Methods of Regenerating Aromatization Catalysts with A Decoking Step Between Chlorine and Fluorine Addition
20190247833 · 2019-08-15 ·

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.

Methods of Regenerating Aromatization Catalysts with A Decoking Step Between Chlorine and Fluorine Addition
20190247833 · 2019-08-15 ·

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.

Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.

Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition

Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.