The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C.sub.2+ compounds and non-C.sub.2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C.sub.2+ impurities from the C.sub.2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H.sub.2 with CO and/or CO.sub.2 in the non-C.sub.2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.

A system and method for producing a high-purity and high-activity vanadium electrolyte, comprising converting high-purity vanadium oxytrichloride into an ammonium salt in a fluidized bed by gas phase ammoniation, then in another fluidized bed, reducing the ammonium salt into a low-valence vanadium oxide having an average vanadium valence of 3.5, adding clean water and sulfuric acid for dissolution, and further performing activation by ultrasound to obtain a 3.5-valence vanadium electrolyte which can be directly used in a new all-vanadium redox flow battery stack. The method of producing an ammonium salt containing vanadium in the fluidized bed by gas phase ammoniation is of short process and high efficiency. Precise regulation of the valence state of the reduction product is implemented by arranging an internal member in the reduction fluidized bed, and ultrasonication is used to activate the vanadium ion, thereby greatly improving the activity of the electrolyte.

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

Disclosed is a process for producing C.sub.2+ hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700 C. contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C.sub.2+ hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C.sub.2+ hydrocarbons in the second product stream is greater than the amount of C.sub.2+ hydrocarbons in the first product stream.

A reformer includes at least one reformer reactor unit (300) having a space-confining wall with external (307) and internal surfaces (306), at least a section of the wall and space confined thereby defining a reforming reaction zone (311), an inlet end (301) and associated inlet (302) for admission of flow of gaseous reforming reactant to the reforming reaction zone (311), an outlet end (303) and associated outlet (304) for outflow of hydrogen-rich reformate produced in the reforming reaction zone (311), at least that section of the wall (305) corresponding to the reforming reaction zone comprising perovskite as a structural component thereof such wall section being gas-permeable to allow gaseous reforming reactant to diffuse therein and hydrogen-rich reformate to diffuse therefrom.

A heating system for a vehicle includes a reaction space (16) containing a first reactant (22) and a reactant storage space (20) containing or/and receiving a second reactant (24), wherein the first reactant and the second reactant form such a reaction system. A reaction of the first reactant with the second reactant produces a reaction product that releases heat. The second reactant can be separated from the first reactant by introducing heat into the reaction product. A reactant-releasing device (26) releases second reactant from the reactant storage space into the reaction space (16). A first heat removal device (58) removes heat from the first reactant or/and reaction product contained in the reaction space (16). A heating unit (52) heats the first reactant or/and heats the reaction product contained in the reaction space. A reactant-recirculating device (36) recirculates second reactant from the reaction space into the reactant storage space.

A liquid fuel reformer includes a fuel vaporizer which utilizes heat from an upstream source of heat, specifically, an electric heater, operable in the start-up mode of the reformer, and therefore independent of the reforming reaction zone of the reformer, to vaporize fuel in a downstream vaporization zone.

A system and method for a polyolefin reactor temperature control system having a first reactor temperature control path, a second reactor temperature control path, and a shared temperature control path. The shared temperature control path is configured to combine and process coolant return streams, and to provide coolant supply for the first reactor temperature control path and the second reactor temperature control path.

A heat exchanger pipe system is provided for transporting viscous fluids, including a plurality of individual heat exchangers designed as pipe elements and having a predefined control temperature and/or pressure distribution along the pipe system and in the cross-section of the pipes. The heat exchangers, which are in the form of pipe elements, are arranged at regular distances in the pipe system. The regular distances are selected in such a manner that a predetermined temperature and/or pressure distribution is maintained along the pipe system, tempering apparatus of a viscous fluid transported in the heat exchanger pipe are arranged in the heat exchangers and optional mixing elements which are used to maintain, in accordance with the pipe cross-section, a predetermined temperature and pressure distribution in the cross section of the pipes, and at least 30% of the length of the heat exchanger pipe system is equipped with heat exchangers.

A method for producing methanol allows the temperature of the catalyst layer to fall within an appropriate temperature range, reduces energy used, and achieves higher carbon yield. In a synthesis loop including at least two synthesis steps and two separation steps, a first mixed gas is obtained by mixing the final unreacted gas with a fraction of the make-up gas, methanol is synthesized from the first mixed gas after preheating, a first unreacted gas is separated from the obtained first reaction mixture, a final mixed gas is obtained by finally mixing the unreacted gas and a fraction of the make-up gas, the final mixed gas after preheating is further increased in pressure and then methanol is synthesized, a final unreacted gas is separated from the obtained final reaction mixture, and the reaction temperature of the catalyst layer is controlled by the indirect heat exchange with pressurized boiling water.