This disclosure relates to weldments useful as heat transfer tubes in refinery processes dealing with gas phase hydrocarbon process streams at high temperatures. This disclosure also relates to tubes that are useful in refinery processes dealing with gas phase hydrocarbon process streams at high temperatures. The weldments include a tubular member and at least one mixing element. The tubular member comprises an aluminum-containing alloy. The mixing element comprises an aluminum-containing alloy. The mixing element's aluminum-containing alloy can be the same as or different from the tubular member's aluminum-containing alloy. Other aspects of the disclosure relate to refinery processes dealing with gas phase hydrocarbon process streams at high temperatures which include such weldments.

The invention relates to a tubular reactor for gas phase phosgenation of at least one organic amine comprising at least one inlet device for starting materials, an outer shell with inner diameters D.sub.ri, a tubular inner sleeve disposed within a segment of the outer shell, having a length Ls along its longitudinal axis and outer diameters D.sub.so, wherein along at least 50% of length L.sub.s, having an inner diameter D.sub.ri and an outer diameter D.sub.so, ratio R.sub.d is from 0.600 to 0.990, calculated by the following equation R.sub.d=D.sub.so/D.sub.ri, wherein there is a gap between the inner sleeve and the outer shell, and wherein the inlet device is disposed within the outer shell.

Disclosed herein are systems and processes which prevent fouling of a reactor inlet of an oligomerization reactor. The systems and processes involve placement of an inlet sleeve around at least a portion of a reactor inlet such that a curtain of inert material flows through an annular space coaxially with respect to an outer surface of the end of the reactor inlet and into the reactor.

The present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids and controlling method thereof. And, more specifically, the present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids comprising a fluidized bed reactor to store a solid layer with a certain height and to fluidize the solid layer by using fluidization gases; a sparger having a pipe shape submerged in the solid layer and having a plurality of gas-discharging holes to spray fluidization gases onto the solid layer; and a gas-supplying line having its one end contacting a gas-supplying source and the other end connected to the sparger, wherein fluidization gases are introduced through the gas-supplying line into the sparger by driving the gas-supplying source, the fluidization gases are sprayed through the gas-discharging holes onto the solid layer, the gas-supplying source is placed higher than the sparger and the height difference (H.sub.g) between the gas-supplying source and the sparger is greater than the height of the solid layer.

The present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids and controlling method thereof. And, more specifically, the present invention relates to a fluidized bed system having a sparger capable of minimizing a blockage by solids comprising a fluidized bed reactor to store a solid layer with a certain height and to fluidize the solid layer by using fluidization gases; a sparger having a pipe shape submerged in the solid layer and having a plurality of gas-discharging holes to spray fluidization gases onto the solid layer; and a gas-supplying line having its one end contacting a gas-supplying source and the other end connected to the sparger, wherein fluidization gases are introduced through the gas-supplying line into the sparger by driving the gas-supplying source, the fluidization gases are sprayed through the gas-discharging holes onto the solid layer, the gas-supplying source is placed higher than the sparger and the height difference (H.sub.g) between the gas-supplying source and the sparger is greater than the height of the solid layer.

The invention concerns a process for the oligomerization of ethylene into alpha-olefins, comprising a step for the oligomerization of ethylene, a step for deactivation of the catalyst, a and step for separation of the products, the reactor being provided with a cooling loop (100, 101, 102) by means of which at least a portion of the reaction effluent is moved through at least two switchable heat exchangers, said heat exchangers being cleaned alternately by means of an integrated cleaning device.

In an outlet flow control arrangement (1) arrangeable to control a flow of material through an outlet (2) with a predetermined diameter arranged at an end of a pressurized processing container (3), the outlet flow control arrangement (1) comprises an adaptor unit (4) configured so that a cross-section of a flow into the adaptor unit (4) is reduced as compared to a cross-section of the outlet (2), to enable the adaptor unit (4) to control and center a flow of processed material out of the processing container (3) and through the outlet (2) into a discharge pipe (5).

The disclosure provides a flushing process for removing polymer fouling from a reactor including a gas distributor proximal to the bottom thereof and an internal condenser proximal to the top thereof, the method including, for a first flushing time period, injecting a flushing solvent into the reactor and withdrawing the flushing solvent from a reactor outlet proximal to the internal condenser to induce an upward movement of flushing solvent, the withdrawn flushing solvent containing a first polymer content. After the first flushing time period is complete, for a second flushing time period, the process includes injecting a flushing solvent into the reactor and withdrawing the flushing solvent from a reactor outlet proximal to the gas distributor to induce a downward movement of flushing solvent, the withdrawn flushing solvent containing a second polymer content.

The present invention relates to a plant for oligomerizing ethylene to produce oligomerized alpha-olefins, with production of a fouling by-product in the form of a deposit, said plant comprising a reaction section comprising: a reactor (c) for two-phase gas/liquid or single-phase all-liquid oligomerization proceeding from an optional solvent, an oligomerization catalyst and ethylene, and cooling means associated with said reactor in the form of at least one cooling circuit external to the reactor and/or in the form of a jacket of the walls of the reactor. Packings are disposed in the reaction section in order to increase the contact surface area per unit volume that is accessible to the deposition of the byproduct.

A system and method is provided for upgrading a continuously flowing process stream including heavy crude oil (HCO). A reactor receives the process stream in combination with water, at an inlet temperature within a range of about 60 C. to about 200 C. The reactor includes one or more process flow tubes having a combined length of about 30 times their aggregated transverse cross-sectional dimension, and progressively heats the process stream to an outlet temperature T(max)1 within a range of between about 260 C. to about 400 C. The reactor maintains the process stream at a pressure sufficient to ensure that it remains a single phase at T(max)1. A controller selectively adjusts the rate of flow of the process stream through the reactor to maintain a total residence time of greater than about 1 minute and less than about 25 minutes.