Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

An anti-coking surface having a thickness up to 15 microns comprising from 15 to 50 wt. % of MnCr.sub.2O.sub.4 (for example manganochromite); from 15 to 25 wt. % of Cr.sub.0.23Mn.sub.0.08Ni.sub.0.69 (for example chromium manganese nickel); from 10 to 30 wt. % of Cr.sub.1.3Fe.sub.0.7O.sub.3 (for example chromium iron oxide); from 12 to 20 wt. % of Cr.sub.2O.sub.3 (for example eskolaite); from 4 to 20 wt. % of CuFe.sub.5O.sub.8 (for example copper iron oxide); and less than 5 wt. % of one or more compounds chosen from FeO(OH), CrO(OH), CrMn, Si and SiO.sub.2 (either as silicon oxide or quartz) and less than 0.5 wt. % of aluminum in any form provided that the sum of the components is 100 wt. % is provided on steel.

The disclosed technology relates to methods of inhibiting corrosion in reaction chambers configured for hydrothermal reaction of feeds containing a heteroatom. An embodiment of such a method comprises providing a feed stream comprising a phosphorus-containing material, an alkali metal compound, water, and a corrosion-inhibitor. The embodiment additionally includes introducing the feed stream and oxidant into a reactor chamber and oxidizing the phosphorus-containing material at an oxidation temperature greater than about 374 C. and an oxidation pressure exceeding about 25 bar, wherein the reactor chamber has inner surfaces comprising a material that corrodes when in contact with a phosphorus compound within the reactor. The embodiment additionally includes selectively reacting the corrosion-inhibitor with phosphorus within the reactor, thereby precipitating in the reactor chamber a phosphorus-containing solid inorganic compound. The embodiment further includes forming in the reactor chamber an alkali salt melt and carrying away from the reactor chamber a mixture comprising the solid phosphorus-containing inorganic compound and the alkali salt melt.

The invention relates to a metal element (12) for anchoring an anti-erosion coating that is intended to be fastened alone in an isolated manner to a metal wall or assembled with other identical anchoring elements. The anchoring element (12) has an edge (12a) for fastening to said metal wall and an anchoring body firmly attached to the fastening edge (12a) and having an upper edge (12b) that is away from the fastening edge and intended to be covered by a composite material of concrete type. A section of this upper edge (12b), which is not intended to be juxtaposed and assembled with an upper edge of an identical anchoring element, is provided with a delimiting tab (16) in order to delimit a height of composite material that must cover the upper edge (12b) of said anchoring element, said delimiting tab (16) having a delimiting edge (18) that is a predetermined distance away from a plane defined by the upper edge (12b) of the anchoring element.

The invention relates to a metal element (12) for anchoring an anti-erosion coating that is intended to be fastened alone in an isolated manner to a metal wall or assembled with other identical anchoring elements. The anchoring element (12) has an edge (12a) for fastening to said metal wall and an anchoring body firmly attached to the fastening edge (12a) and having an upper edge (12b) that is away from the fastening edge and intended to be covered by a composite material of concrete type. A section of this upper edge (12b), which is not intended to be juxtaposed and assembled with an upper edge of an identical anchoring element, is provided with a delimiting tab (16) in order to delimit a height of composite material that must cover the upper edge (12b) of said anchoring element, said delimiting tab (16) having a delimiting edge (18) that is a predetermined distance away from a plane defined by the upper edge (12b) of the anchoring element.

A thermal barrier coating and a cold-wall reactor including the coating are provided. A second ceramic layer is sandwiched between the conventional two-layer structures of the thermal barrier coating. The second ceramic layer is made of aluminum oxide stabilized zirconium oxide and the content of aluminum oxide does not exceed 30 wt %. The zirconium oxide in the first and second ceramic layer has a tetragonal crystal structure. A cold-wall reactor formed by applying the thermal barrier coating provides advantageous steel hydrogen corrosion resistance in ultra-high temperature. The effective volume of the hydrogenation reactor is fully used, overcoming the problem that the thermal insulation liner is easily damaged and causes local overheating of the reactor wall, as well as eliminating potential safety hazards of reactor wall local stress concentration caused by expansion and contraction of the liner cylinder attachment member.

In various embodiments, a microreactor features a corrosion-resistant microchannel network encased within a thermally conductive matrix material that may define therewithin one or more hollow heat-exchange conduits.

An anti-coking surface having a thickness up to 15 microns comprising from 15 to 50 wt. % of MnCr.sub.2O.sub.4; from 15 to 25 wt. % of Cr.sub.0.23Mn.sub.0.08Ni.sub.0.69, from 10 to 30 wt. % of Cr.sub.1.3Fe.sub.0.7O.sub.3, from 12 to 20 wt. % of Cr.sub.2O.sub.3, from 4 to 20 wt. % of CuFe.sub.5O.sub.8, and less than 5 wt. % of one or more compounds chosen from FeO(OH), Cr+3O(OH), CrMn, Si and SO.sub.2 (either as silicon oxide or quartz) and less than 0.5 wt. % of aluminum in any form provided that the sum of the components is 100 wt. % is provided on steel.

Process for depositing a corrosion-protection coating on at least one portion of the surfaces of a metallic substrate having at least one cavity with an equivalent diameter e.sub.mm<2 mm and a length/width ratio of greater than 150, using an aqueous suspension comprising powder of the metal to be deposited on the substrate combined with an agent for protecting the surface of the metal powder, a diluent, and at least one additive, the particles of the suspension each having an equivalent diameter d such that de.sub.mm/10.