Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

A process for increasing alcohol yield from biomass (the form or agro- or forest residue, grains, hops, etc.), involving multiple hydrodynamic cavitation treatments of biomass filtrateboth before and after fermentation. Carbohydrates extracted from biomass are subjected to a first cavitation treatment to promote additional conversion into carbohydrates. The carbohydrates are then combined with bacterial species and nutrients, and allowed to ferment. The fermentation product is subjected to a second hydrodynamic cavitation treatment to promote further conversion of carbohydrates into bioalcohol. After distillation, the bioalcohol is subjected to a second hydrodynamic cavitation treatment to increase its purity.

Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

The invention provides a Potassium Fluotitanate (K.sub.2TIF6) manufacture process. The Potassium Fluotitanate (K.sub.2TIF6) manufacture process includes steps: A. providing titanium ferrum powder to a reaction furnace and adding HF and peroxide solution to react with the titanium ferrum powder sufficiently to manufacture H.sub.2TiF.sub.6, B. filtrating the sufficiently mixed solution of step A and adding it to another reaction furnace, and then after the H.sub.2TiF.sub.6 cools off, adding Potassium Chloride (KCl) solution to react with the mixed solution to manufacture Potassium Fluotitanate (K.sub.2TiF.sub.6); C. adding K.sub.2CO.sub.3 solution to the remaining solution of step B and react with the remaining solution and controlling the pH value, the element Fe is recycled by a form of Fe(OH).sub.3 flocculent precipitate and the Potassium Chloride (KCl) and KF solution are recycled. This invention has these advantages: adding peroxide to the titanium ferrum powder can oxidize Fe.sup.2+ into Fe.sup.3+ and adding K.sub.2CO.sub.3 solution to clean element Fe out by a form of Fe(OH).sub.3 flocculent precipitate, and the hydrofluoric acid (HF) can be recycled which can realize the HF zero polluting discharge.

An apparatus for producing a mixed solution, comprising a mixing vessel for preparing an aqueous mixed solution containing a dicarboxylic acid and an Nb compound and a filter for the aqueous mixed solution connected to the mixing vessel via a pipe, the mixing vessel being anticorrosive and equipped with a stirring unit, a heating unit and a cooling unit for the aqueous mixed solution, wherein the aqueous mixed solution prepared in the mixing vessel is fed to the filter via the pipe and filtered in the filter under increased pressure.

Both a system and method for cleaning a low pressure separation vessel of a high pressure polyethylene polymerization plant are provided. The system includes a polytetrafluoroethylene lining that covers the interior surfaces of the vessel, and a cover mounting assembly including an annular clamp for detachably mounting a cover over the vessel. The mounting assembly includes a clamp actuator for quickly securing and releasing the cover with respect to a top rim of the vessel. The vessel is drained of liquid polyethylene and allowed to cool to ambient temperature, thus creating a frozen skin of polyethylene around the interior surfaces of the vessel. The clamp actuator releases the cover. The polyethylene skin is peeled off the interior sides the vessel and gathered up at the top to form a neck, thus peeling the polyethylene skin away from the polytetrafluoroethylene lining along with any degraded polymers or other impurities that have accumulated on the interior surfaces of the vessel.

A process for increasing alcohol yield from biomass (the form or agro- or forest residue, grains, hops, etc.), involving multiple hydrodynamic cavitation treatments of biomass filtrateboth before and after fermentation. Carbohydrates extracted from biomass are subjected to a first cavitation treatment to promote additional conversion into carbohydrates. The carbohydrates are then combined with bacterial species and nutrients, and allowed to ferment. The fermentation product is subjected to a second hydrodynamic cavitation treatment to promote further conversion of carbohydrates into bioalcohol. After distillation, the bioalcohol is subjected to a second hydrodynamic cavitation treatment to increase its purity.

Apparatus for undertaking a chemical reaction includes an elongate housing and a receptacle. The elongate housing may include a cooling means, and end fittings, which may include ports where fluids may be introduced and/or removed. In use of the apparatus, a chemical reaction product is formed within the receptacle. Subsequently the receptacle containing the chemical reaction product is withdrawn from the elongate housing.

An industrial microwave ultrasonic reactor has an inner wall liner. A microwave generation device is formed by microwave units distributed on an outer sidewall, or by a microwave pipe disposed outside the reactor and microwave units distributed on the microwave pipe. One end of the microwave pipe communicates with the bottom of the reactor via a connection pipe I, and the other end communicates with the top via a return pipe. A shield is disposed outside the microwave generation device to separate the microwave units from the outside, and a heat removal device is disposed outside the shield. An ultrasonic wave generation device is formed by 10 to 30 sets of ultrasonic pulse units disposed at intervals along the outer sidewall. Each set has 10 to 50 members distributed along the circumferential direction of the reactor. A stirring shaft is fixed below a stirring motor and extends into the reactor.

A continuous solid-state polymerization device according to the present invention comprises: a feeder for injecting a prepolymer continuously; a transverse reactor connected to the feeder via a first connector to receive the prepolymer from the feeder and to perform solid-state polymerization, the reactor itself rotating; and a chamber connected to the transverse reactor via a second connector to receive a polymer, which has been discharged from the transverse reactor, and solid-state polymerization of which has been completed, and to discharge the polymer, wherein the transverse reactor has a demolding coating film formed on the inner wall thereof, and the feeder, the transverse reactor and the chamber are in a vacuum state. The continuous solid-state polymerization device can prevent formation of an interval, in which the prepolymer stagnates, and can perform solid-state polymerization continuously in a vacuum state without using inert gas.