A preparation method for covalent organic framework 5 (COF-5) includes: adding 2,3,6,7,10,11-hexahydroxytriphenylene and 1,4-phenylenebisboronic acid to a mixed solution of 1,3,5-trimethylbenzene and 1,4-dioxane to form a mixture in the anhydrous and oxygen-free environment; and the addition ratio of 2,3,6,7,10,11-hexahydroxytriphenylene: 1,4-phenylenebisboronic acid: 1,3,5-trimethylbenzene: 1,4-dioxane is 0.02-0.8 mmol: 0.08-1.4 mmol: 10-15 mL: 10-15 mL; sealing the mixture in an airtight container; and obtaining a uniform dispersion solution after shaking the container for wholly mixing the components; heating the dispersion solution to a temperature ranging from 80-100° C.; reacting for a period of time ranging from 72-120 h; and obtaining a precipitate after the reaction; and washing the precipitate, drying the precipitate in vacuum, and heating the precipitate at a temperature ranging from 200-300° C. for a period of time ranging from 1-3 h with a protective atmosphere to obtain COF-5 crystal.

A method for forming a zeolite membrane by performing an ALD cycle, the ALD cycle including a silicon oxide film forming step and an aluminum oxide film forming step. In the silicon oxide film forming step, an organic Si compound is used as a first raw material gas and OH radicals are used as a reaction gas; in the aluminum oxide film forming step, an organic Al compound is used as a second raw material gas and OH radicals are used as a reaction gas; and the silicon oxide films and the aluminum oxide films are alternately formed in forward or reverse order to form the zeolite membrane.

The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.

The present invention relates to an average-density-adjustable structure and more specifically provides a structure the average density of which is adjusted by changing the material of the structure and the size of a void formed therein and which can thereby float on the surface of or in a liquid and can easily bond with or change a material present in a gas or liquid by being equipped with a first material, which is one among an organic catalyst, an inorganic catalyst, a microorganism, and a biomolecule.

An amine-functionalized, crosslinked porous copolymer can be synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of concentrated hydrochloric acid catalyst. The polymer is permanently microporous, with a BET surface area of 250 to 350 m.sup.2/g. Due to the high concentration of polar amines within its backbone, the polymer exhibits a CO.sub.2 uptake of 17.5 to 30 cm3/g at 298 K and 1 bar, but demonstrated a remarkably high selectivity for CO.sub.2 over N.sub.2 at 298 K. Dynamic breakthrough experiments indicate that this material is an effective adsorbent for selectively separating CO.sub.2 from a dry and wet gas mixture containing N.sub.2 for over 45 cycles without significant loss of performance. Furthermore, the polymer can be regenerated at room temperature after each cycle by a simple N.sub.2 flow.

The method includes mixing an aldehyde and a first solvent to form a mixture. The method further includes mixing an organosulfur phenol and an aromatic compound to the mixture to form a phenol mixture and heating the phenol mixture in the presence of an acid to form a solid. The solid is dried to obtain the cross-linked porous polymer. The obtained cross-linked porous polymer has repeat pyrrole units bonded to one another, and the cross-linked porous polymer has a thiol group which separates non-adjacent pyrrole units. The cross-linked porous polymer obtained after drying is in a form of solid particles having a spherical particle structure.

Embodiments of templated polymeric materials capable of binding lysophosphatidic acids (LPAs) are disclosed. Methods of making and using the templated polymeric materials also are disclosed. The disclosed templated polymeric materials are molecularly imprinted polymers that bind LPAs and facilitate the production of lysophosphatidic acid-enriched samples, for instance through extraction of lysophosphatidic acids from biological samples, such as plasma or serum samples.

An amine-functionalized, crosslinked porous copolymer can be synthesized by linking 1,4-benzenediamine and pyrrole with p-formaldehyde in the presence of concentrated hydrochloric acid catalyst. The polymer is permanently microporous, with a BET surface area of 250 to 350 m.sup.2/g. Due to the high concentration of polar amines within its backbone, the polymer exhibits a CO.sub.2 uptake of 17.5 to 30 cm3/g at 298 K and 1 bar, but demonstrated a remarkably high selectivity for CO.sub.2 over N.sub.2 at 298 K. Dynamic breakthrough experiments indicate that this material is an effective adsorbent for selectively separating CO.sub.2 from a dry and wet gas mixture containing N.sub.2 for over 45 cycles without significant loss of performance. Furthermore, the polymer can be regenerated at room temperature after each cycle by a simple N.sub.2 flow.

A method of forming one or more composite structures is provided wherein one or more carbon structures is formed from a carbon source via a hydrothermal process. Said carbon source is a biomass material including glucose and glucosamine hydrochloride. In particular, the method further comprises introducing a seeding additive of potassium or phosphate salt, preferably monopotassium phosphate to the carbon source. The method includes introducing iron onto the carbon structures to form the one or more composite structures including carbon and iron.

A method for separating N.sub.2 from a hydrocarbon gas mixture containing N.sub.2 comprising the steps of: i) providing a bed of adsorbent selective for N.sub.2; (ii) passing the hydrocarbon gas mixture through the bed of adsorbent to at least partially remove N.sub.2 from the gas mixture to produce: (a) N.sub.2-loaded adsorbent and (b) N.sub.2-depleted hydrocarbon gas mixture; iii) recovering the N.sub.2-depleted hydrocarbon gas mixture; iv) regenerating the N.sub.2-loaded adsorbent by at least partially removing N.sub.2 from the adsorbent; and v) sequentially repeating steps (ii) and (iii) using regenerated adsorbent from step (iv); wherein the adsorbent comprises a pyrolized sulfonated macroporous ion exchange resin.