Patent classifications
B01J2229/186
Method for preparing molecular sieve SCR catalyst, and catalyst prepared therethrough
A method for preparing a molecular sieve SCR (selective catalytic reduction) catalyst and a prepared catalyst therethrough. In the method, several molecular sieves are mixed and modified by transition metal or rare-earth metal via ion exchange, then loaded Fe by equivalent-volume impregnation, and loaded Cu by one or more liquid ion exchange. This present invention, combined with several techniques, such as modification of stable molecular sieve by transition and rare-earth metal, Fe loading by equivalent-volume impregnation and Cu loading by one or more liquid ion exchange, and after through stable and effective modification and loading control, the obtained catalyst material is coated on a carrier substrate via size mixing and coating process to be prepared into an integral catalyst.
Isomerisation process
The invention relates to a process for combined ethylbenzene reforming and xylene isomerisation comprising contacting a hydrocarbon feedstock containing ethylbenzene and xylene with a catalyst comprising a catalyst carrier and one or more metal(s) supported on the catalyst carrier, wherein the catalyst carrier is an extrudate comprising (i) a ZSM-48 and/or EU-2 type zeolite and (ii) an alumina binder, the extrudate having a shape with a C/A value of at least 3, where C is the circumference of the extrudate and A is the cross-sectional area of the extrudate. The metal may be platinum and the alumina may be a wide-pore alumina. The process displays high conversion rates whilst maintaining low levels of side-product formation.
Catalyst for production of hydrocarbons and method of producing hydrocarbons
A catalyst is provided for production of hydrocarbons including monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 and aliphatic hydrocarbons having a carbon number of 3 to 4 from feedstock in which a 10 vol % distillation temperature is 140° C. or higher and a 90 vol % distillation temperature is 380° C. or lower. The catalyst includes crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure.
Small crystal ferrierite and method of making the same
There is disclosed a highly crystalline, small crystal, ferrierite zeolite prepared from a gel containing a source of silica, alumina, alkali metal and a combination of two templating agents. The resulting material includes ferrierite crystals having a particle size of about or less than about 200 nm. The desired crystal size can be achieved by using a specific composition of the gel. The purity of the material and the crystal size was determined by using X-ray powder diffraction and scanning electron microscopy. The material has excellent surface area and micropore volume as determined by nitrogen adsorption.
A SELECTIVE CATALYTIC REDUCTION CATALYST FOR THE TREATMENT OF AN EXHAUST GAS
The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a combustion engine, the catalyst comprising a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough; a coating disposed on the substrate (i), the coating comprising a first non-zeolitic oxidic material comprising aluminum, an 8-membered ring pore zeolitic material comprising one or more of copper and iron, and a second non-zeolitic oxidic material comprising cerium and one or more of zirconium, aluminum, silicon, lanthanum, niobium, iron, manganese, titanium, tungsten, copper, molybdenum, neodymium, cobalt, chromium, tin and praseodymium; wherein at least 65 weight-% of the coating consist of the 8-membered ring pore zeolitic material comprising one or more of copper and iron.
MIXED METAL LARGE CRYSTAL MOLECULAR SIEVE CATALYST COMPOSITIONS, CATALYTIC ARTICLES, SYSTEMS AND METHODS
Described are compositions and catalytic articles comprising both a first molecular sieve promoted with copper and a second molecular sieve promoted with iron, the first and second molecular sieves having a d6r unit and the first molecular sieves having cubic shaped crystals with an average crystal size of about 0.5 to about 2 microns. The weight ratio of the copper-promoted molecular sieve to the iron-promoted molecular sieve can be about 1:1 to about 4:1. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.
CATALYST AND MANUFACTURING METHOD OF CATALYST
A catalyst manufacturing method includes: preparing UZM-35 zeolite; manufacturing ion-containing UZM-35 zeolite by substituting ions in a structure of the UZM-35 zeolite; and manufacturing metal-containing UZM-35 zeolite by exchanging copper (Cu) ions or iron (Fe) ions in a structure of the ion-containing UZM-35 zeolite.
PROCESS FOR PREPARING A MOLECULAR SIEVE
The present invention relates to the synthesis of molecular sieves of the STT and ITE framework types using, as structure directing agent Q, [L(DETA)2].sup.2+ cation or [L(TEPA)].sup.2+ cation, or a mixture thereof, where L is a divalent metal cation comprising at least one of Ni, Co and Mn and DETA is diethylene triamine and TEPA is tetraethylene pentamine.
HEAT GENERATING CATALYST FOR HYDROCARBONS CRACKING
A method of making a heat generating catalyst for hydrocarbon cracking. The method includes providing at least one mordenite framework-inverted (MFI) zeolite having a Si/Al molar ratio of 15 or greater and providing at least one metal oxide precursor. Further, the at least one metal oxide precursor is dispersed within a microstructure of the MFI zeolite catalyst. The method additionally includes calcining the heat generating material with the at least one metal oxide precursor dispersed within the microstructure of the MFI zeolite catalyst to form at least one metal oxide in situ. The heat generating catalyst includes at least one MFI zeolite and at least one metal oxide in a ratio between 50:50 and 95:5. Additionally, an associated method of using the heat generating catalyst in a hydrocarbon cracking process is provided.
Modified Beta Zeolite, Catalytic Cracking Catalyst and Their Preparation Method and Application
A modified β zeolite has 0.5-15 wt % of an IVB group metal element in terms of oxide on the dry basis weight of the modified β zeolite. The number of medium strong acid centers of the modified β zeolite accounts for 30-60% of the total acid amount, the number of strong acid centers accounts for 5-25% of the total acid amount, and the ratio of B acid to L acid is 0.8 or more. The ratio of the weight content of the IVB group metal element in the modified β zeolite body phase to the weight content of the IVB group metal element on the surface is 0.1-0.8. The catalytic cracking catalyst containing the modified β zeolite has good selectivity and yield of C4 olefin.