A hydrocarbon reforming catalyst for producing a synthesis gas containing hydrogen and carbon monoxide from a hydrocarbon-based gas, the hydrocarbon reforming catalyst containing a complex oxide having a perovskite structure including at least Ba, Zr, and Ru; and a hydrocarbon reforming apparatus that includes the hydrocarbon-reforming catalyst.

A synthesis process for forming nanodendrites. The nanodendrites are utilized in a process to form a heterojunction catalyst. Nanodendrites may include PtRu.sub.8 nanodendrites that can be oxidized through annealing to form PtRuO.sub.2. One heterojunction catalyst comprises PtRuO.sub.2 on a carbon support.

The present invention relates to a monolith catalyst for carbon-dioxide/methane reforming and a method of manufacturing the same, and more particularly to a novel monolith catalyst for a reforming reaction having improved thermal durability, configured such that a sintering inhibiting layer is formed by coating the surface of a monolith support with at least one element selected from the group consisting of Group 2, 3, 6, 13, 15 and 16 elements among elements in Period 3 or higher and an active catalyst layer is formed on the sintering inhibiting layer, thereby preventing carbon deposition and catalyst deactivation due to deterioration even upon reaction at high temperatures.

The present invention relates to a monolith catalyst for carbon-dioxide/methane reforming and a method of manufacturing the same, and more particularly to a novel monolith catalyst for a reforming reaction having improved thermal durability, configured such that a sintering inhibiting layer is formed by coating the surface of a monolith support with at least one element selected from the group consisting of Group 2, 3, 6, 13, 15 and 16 elements among elements in Period 3 or higher and an active catalyst layer is formed on the sintering inhibiting layer, thereby preventing carbon deposition and catalyst deactivation due to deterioration even upon reaction at high temperatures.

Methods for preparing a catalyst system, include providing a catalytic substrate comprising a catalyst support having a surface with a plurality of metal catalytic nanoparticles bound thereto and physically mixing and/or electrostatically combining the catalytic substrate with a plurality of oxide coating nanoparticles to provide a coating of oxide coating nanoparticles on the surface of the catalytic nanoparticles. The metal catalytic nanoparticles can be one or more of ruthenium, rhodium, palladium, osmium, iridium, and platinum, rhenium, copper, silver, and gold. Physically combining can include combining via ball milling, blending, acoustic mixing, or theta composition, and the oxide coating nanoparticles can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, lanthanum, iron, strontium, and calcium. The catalyst support can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, iron, strontium, and calcium.

A method for producing a methane-rich gas from a heavy hydrocarbon feed, the method comprising the steps of introducing the heavy hydrocarbon stream to a catalytic reactor, the catalytic reactor comprising an activated catalyst, the activated catalyst comprising 20 wt % of nickel, 70 wt % of a cerium oxide component, and 10 wt % of a gadolinium oxide component; applying the heavy hydrocarbon stream to the activated catalyst; and producing the methane-rich gas over the activated catalyst, wherein the methane-rich gas is selected from the group consisting of methane, carbon dioxide, carbon monoxide, hydrogen, and combinations of the same.

A method for producing a methane-rich gas from a heavy hydrocarbon feed, the method comprising the steps of introducing the heavy hydrocarbon stream to a catalytic reactor, the catalytic reactor comprising an activated catalyst, the activated catalyst comprising 20 wt % of nickel, 70 wt % of a cerium oxide component, and 10 wt % of a gadolinium oxide component; applying the heavy hydrocarbon stream to the activated catalyst; and producing the methane-rich gas over the activated catalyst, wherein the methane-rich gas is selected from the group consisting of methane, carbon dioxide, carbon monoxide, hydrogen, and combinations of the same.

A method is described of producing a catalyst-containing composite oxygen ion membrane and a catalyst-containing composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1xA.sub.x).sub.wCr.sub.1yB.sub.yO.sub.3 and a doped zirconia. Adding certain catalyst metals into the fuel oxidation layer not only enhances the initial oxygen flux, but also reduces the degradation rate of the oxygen flux over long-term operation. One of the possible reasons for the improved flux and stability is that the addition of the catalyst metal reduces the chemical reaction between the (Ln.sub.1xA.sub.x).sub.wCr.sub.1yB.sub.yO.sub.3 and the zirconia phases during membrane fabrication and operation, as indicated by the X-ray diffraction results.

Disclosed are methods, compositions, reagents, systems, and kits to prepare and utilize branched multi-functional macromonomers, which contain a ring-opening metathesis polymerizable norbornene group, one or more reactive sites capable of undergoing click chemistry, and a terminal acyl group capable of undergoing a coupling reaction; branched multi-cargo macromonomers; and the corresponding polymers are disclosed herein. Various embodiments show that the macromonomers and polymers disclosed herein display unprecedented control of cargo loading of agents. These materials have the potential to be utilized for the treatment of diseases and conditions such as cancer and hypertension.

A multicomponent photocatalyst includes a reactive component optically, electronically, or thermally coupled to a plasmonic material. A method of performing a catalytic reaction includes loading a multicomponent photocatalyst including a reactive component optically, electronically, or thermally coupled to a plasmonic material into a reaction chamber; introducing molecular reactants into the reaction chamber; and illuminating the reaction chamber with a light source.