Patent classifications
B01J2523/824
EXHAUST GAS PURIFICATION CATALYST, METHOD OF PURIFYING EXHAUST GAS, AND METHOD OF MANUFACTURING EXHAUST GAS PURIFICATION CATALYST
In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.
EXHAUST GAS PURIFICATION CATALYST, METHOD OF PURIFYING EXHAUST GAS, AND METHOD OF MANUFACTURING EXHAUST GAS PURIFICATION CATALYST
In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.
CATALYST FOR SYNTHESIS OF HYDROGEN PEROXIDE AND RECOVERY, AND METHOD OF PREPARING SAME
Described is a catalyst for preparing hydrogen peroxide by an anthraquinone process and for regenerating a working solution and a method of preparing the catalyst. The catalyst contains palladium, magnesium, and cerium components uniformly distributed in alumina. Alternatively, the catalyst contains a palladium component distributed in a ring shape in an alumina sphere and magnesium and cerium components uniformly distributed in the alumina.
EXHAUST GAS PURIFICATION CATALYST DEVICE
An exhaust gas purification catalyst device including a substrate and an SCR catalyst layer on the substrate, the substrate containing catalyst precious metal particles directly supported on the substrate, the catalyst precious metal particles containing Pt, and the catalyst precious metal particles having an average particle diameter of 30 to 120 nm inclusive.
Process of Selectively Hydrogenating Gas Mixture Having High Acetylene Content
Disclosed is a process for converting methane into value-added compounds. In this process, a gas mixture containing hydrogen as well as high-concentration acetylene formed through methane pyrolysis (e.g. non-oxidative coupling of methane) is selectively hydrogenated in the presence of a bimetallic supported catalyst. This process obtains ethylene from acetylene in the gas mixture while unreacted methane and hydrogen are recovered as byproducts and/or additionally recycled.
CATALYTIC HYDROGENATION METHOD FOR CARBON NINE RESIN
The present invention discloses a catalytic hydrogenation method for carbon nine resin, comprising the following steps: 1) adding a Pt—W—Y/γ-Al.sub.2O.sub.3 catalyst in the first half of a fixed bed, adding a Pd—Zr—Nd/γ-Al.sub.2O.sub.3 catalyst in the second half of the fixed bed, and feeding hydrogen for reduction; and 2) catalytic hydrogenating the pretreated carbon nine resin in the fixed bed. In the present invention, different catalysts capable of reacting under the same catalytic conditions are added in the first and second halves of the fixed bed, and the two different catalysts play different roles, and can be active and complementary to each other under the same conditions. The synergistic effect of the two catalysts plays a good catalytic role. Moreover, the production process is simplified, and the production cost is saved.
CATALYTIC HYDROGENATION METHOD FOR CARBON NINE RESIN
The present invention discloses a catalytic hydrogenation method for carbon nine resin, comprising the following steps: 1) adding a Pt—W—Y/γ-Al.sub.2O.sub.3 catalyst in the first half of a fixed bed, adding a Pd—Zr—Nd/γ-Al.sub.2O.sub.3 catalyst in the second half of the fixed bed, and feeding hydrogen for reduction; and 2) catalytic hydrogenating the pretreated carbon nine resin in the fixed bed. In the present invention, different catalysts capable of reacting under the same catalytic conditions are added in the first and second halves of the fixed bed, and the two different catalysts play different roles, and can be active and complementary to each other under the same conditions. The synergistic effect of the two catalysts plays a good catalytic role. Moreover, the production process is simplified, and the production cost is saved.
CATALYST CONSISTING OF GRAPHENE-SUPPORTED NANOPARTICLES FOR SELECTIVE OIL HYDROGENATION AIMED AT THE PRODUCTION OF CIS-OLEIC ACID AND THE REDUCTION OF TRANS-OLEIC ACID
A nano-catalyst which is usable in processes of vegetable oil hydrogenation for producing bio-lubricants or biodegradable plastics for producing copolymers, characterized in that it consists of an active phase composed of nickel, palladium and ruthenium, dispersed on a support including graphene layers less than 1 micron, the outer surface of which is covered with surfactant chains, and having a high activity and a very high selectivity for the cis-configuration of the 9-octadecenoic acid (cis-oleic acid).
CATALYST CONSISTING OF GRAPHENE-SUPPORTED NANOPARTICLES FOR SELECTIVE OIL HYDROGENATION AIMED AT THE PRODUCTION OF CIS-OLEIC ACID AND THE REDUCTION OF TRANS-OLEIC ACID
A nano-catalyst which is usable in processes of vegetable oil hydrogenation for producing bio-lubricants or biodegradable plastics for producing copolymers, characterized in that it consists of an active phase composed of nickel, palladium and ruthenium, dispersed on a support including graphene layers less than 1 micron, the outer surface of which is covered with surfactant chains, and having a high activity and a very high selectivity for the cis-configuration of the 9-octadecenoic acid (cis-oleic acid).
Oxidation catalyst for lean compressed natural gas engine
The present invention provides an oxidation catalyst composition suitable for at least partial conversion of gaseous hydrocarbon emissions, e.g., methane. The oxidation catalyst composition includes at least one platinum group metal (PGM) component supported onto a porous zirconia-containing material that provides an effect on hydrocarbon conversion activity. The porous zirconia-containing material is at least 90% by weight in the monoclinic phase. Furthermore, the PGM component can comprise at least one platinum group metal in the form of colloidally deposited nanoparticles. The oxidation catalyst composition can be used in the treatment of emissions from lean compressed natural gas engines.