Patent classifications
B01J2523/845
METHOD FOR PRODUCING A MULTIMETAL OXIDE CATALYST
A method for producing a multimetal oxide catalyst comprises preparation of a precursor composition, exposing said precursor composition to elevated temperatures to activate the composition, and grinding the activated composition. The preparation of the precursor composition comprises: a) forming a plasticized precursor composition from the constituents of the composition; b) discharging the plasticized precursor composition from an extruder having at least one die to form extrudates; c) allowing the extrudates to drop onto a transfer surface disposed beneath the at least one die whereby the extrudates break into pieces which come to rest on the transfer surface; d) transferring the pieces to at least one drying chamber; and e) moving the pieces, through the at least one drying chamber on an air permeable drying conveyor belt; wherein steps b) through d) are carried out under reduced pressure. The method allows the production of a multimetal oxide catalyst with uniform characteristics. Fine particles of the multimetal oxide precursor that may be generated during extrusion of the plasticized precursor composition and handling of the extrudates are removed.
A MOLDING COMPRISING A MIXED OXIDE COMPRISING OXYGEN, LANTHANUM, ALUMINUM, AND COBALT
A molding comprising a mixed oxide, wherein the mixed oxide comprises oxygen, lanthanum, aluminum, and cobalt, wherein in the mixed oxide, the weight ratio of cobalt relative to aluminum, calculated as elements, is at least 0.17:1. A preparation method by a dry route. Use of the molding as a catalyst for the reforming of hydrocarbons into a synthesis gas.
A MOLDING COMPRISING A MIXED OXIDE COMPRISING OXYGEN, LANTHANUM, ALUMINUM, AND COBALT
A molding comprising a mixed oxide, wherein the mixed oxide comprises oxygen, lanthanum, aluminum, and cobalt, wherein in the mixed oxide, the weight ratio of cobalt relative to aluminum, calculated as elements, is at least 0.17:1. A preparation method by a dry route. Use of the molding as a catalyst for the reforming of hydrocarbons into a synthesis gas.
Catalyst for low temperature ethanol steam reforming and related process
A catalyst composition suitable for the ethanol reforming process at low temperature with enhanced stability on long term, comprises a noble metal, such as platinum or rhodium, and a transition non-noble metal, such as nickel or cobalt, supported by a carrier comprising, cerium, zirconium, optionally aluminium, supplemented with potassium. It is provided also a method for the stable production of hydrogen from an ethanol containing gas stream, comprising subjecting the gas stream to catalytic ethanol reforming as to form a rich H2 stream, using the catalyst as defined above.
Catalyst for low temperature ethanol steam reforming and related process
A catalyst composition suitable for the ethanol reforming process at low temperature with enhanced stability on long term, comprises a noble metal, such as platinum or rhodium, and a transition non-noble metal, such as nickel or cobalt, supported by a carrier comprising, cerium, zirconium, optionally aluminium, supplemented with potassium. It is provided also a method for the stable production of hydrogen from an ethanol containing gas stream, comprising subjecting the gas stream to catalytic ethanol reforming as to form a rich H2 stream, using the catalyst as defined above.
Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds
A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.
Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds
A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.
Method for preparing high-efficiency denitrification activity catalyst
A method for preparing an active catalyst for high-efficiency denitration is disclosed. The method includes: a catalyst raw material is charged into a denitration reactor, NH.sub.3 and an inert gas are introduced and then heating is performed, and the temperature is held and then natural cooling is performed, thereby obtaining the catalyst. The active catalyst can greatly improve the denitration activity in low temperature range, and can not only improve the denitration efficiency under the condition without SO.sub.2 and H.sub.2O, but also can improve the denitration efficiency under the condition with both SO.sub.2 and H.sub.2O. The service life of the catalyst is prolonged under the premise of not changing the existing catalyst preparation process, and the economic benefit is significant. The denitration efficiency of a powder catalyst can be increased by 25%, and the denitration efficiency of a honeycombed catalyst or a corrugated catalyst can be increased by 20%.
Method for preparing high-efficiency denitrification activity catalyst
A method for preparing an active catalyst for high-efficiency denitration is disclosed. The method includes: a catalyst raw material is charged into a denitration reactor, NH.sub.3 and an inert gas are introduced and then heating is performed, and the temperature is held and then natural cooling is performed, thereby obtaining the catalyst. The active catalyst can greatly improve the denitration activity in low temperature range, and can not only improve the denitration efficiency under the condition without SO.sub.2 and H.sub.2O, but also can improve the denitration efficiency under the condition with both SO.sub.2 and H.sub.2O. The service life of the catalyst is prolonged under the premise of not changing the existing catalyst preparation process, and the economic benefit is significant. The denitration efficiency of a powder catalyst can be increased by 25%, and the denitration efficiency of a honeycombed catalyst or a corrugated catalyst can be increased by 20%.
Catalyst for water splitting reactions
A perovskite-type oxide catalyst for water-splitting reactions is provided. The catalyst, Ca.sub.2-ySr.sub.yFe.sub.1-xCo.sub.1-xMn.sub.2xO.sub.6-δ where y=0.10-1.90 and x=0.05-0.95, has catalytic activity for both hydrogen- and oxygen-evolution reactions. An exemplary catalyst is CaSrFe.sub.0.75Co.sub.0.75Mn.sub.0.5O.sub.6-δ.