A synthetic bead for use in mineral separation is described. The synthetic bead has a surface made of a synthetic material such as polymer and the synthetic material is functionalized with molecules having a functional group for attaching mineral particles to the surface in a separation process. The synthetic beads can be placed in flotation cell containing a mixture of water, valuable material and unwanted material or in a pipeline where the mixture is transported from one location to another. The enriched synthetic beads carrying the mineral particles are separated from the unwanted materials in the mixture. The mineral particles are then released from the synthetic beads by means of low pH treatment, ultrasonic agitation, thermal or electromagnetic treatment.

Apparatus uses engineered collection media to recover mineral particles in a mineral extraction process, e.g., for processing a tailings stream at the end of a flotation separation process. The engineered collection media are added to slurry/tailings containing the mineral particles. The engineered collection media have collection surfaces coated with a chemical selected for attracting the mineral particles to the collection surfaces so the engineered collection media becomes mineral laden media in the slurry/tailings in a loading stage. The apparatus include three stages: removing unwanted material from mineral laden media; using a stripping agent to strip the mineral particles from the mineral laden media; and separating the engineered collection media from the mineral particles and the stripping agent. The stripping agent is reused for stripping, and the engineered collection media are returned to the loading stage. The engineered collection media can have a smooth or foam-like surface.

Methods of increasing the rate of separating hydrophobic and hydrophilic particles by flotation have been developed. They are based on using appropriate reagents to enhance the hydrophobicity of the particles to be floated, so that they can be more readily collected by the air bubbles used in flotation. The hydrophobicity-enhancing reagents include low HLB surfactants, naturally occurring lipids, modified lipids, and hydrophobic polymers. These methods can greatly increase the rate of flotation for the particles that are usually difficult to float, such as ultrafine particles, coarse particles, middlings, and the particles that do not readily float in the water containing large amounts of ions derived from the particles. In addition, new collectos for the flotation of phosphate minerals are disclosed.

A selective recirculation circuit has a loading stage, a stripping stage and a filtering stage for use in processing a feed stream or slurry containing mineral particles. The stripping stage forms a first loop with the loading stage, and a second loop with the filtering stage. The loading stage has a loading mixer and a loading washing screen. The stripping stage has a stripping mixer and a stripping washing screen. The loading mixer receives the slurry and causes barren media in the circuit to contact with the slurry so that the mineral particles in the slurry are loaded onto the barren media. The media is directed to the stripping stage where the mineral particles are removed from the media. The barren media is recycled to the loading stage. The stripping solution recovered from the filtering stage is returned to the stripping stage and the mineral particles are discharged as concentrate.

This invention relates to an composition, comprising A) at least one quaternary ammonium compound which is a collector for the reverse flotation of magnesium minerals from calcium carbonate B) at least one antifoam agent C) a solvent
and its use in the reverse flotation of calcium carbonate.

Apparatus for use in, or forming part of, a separation process to be implemented in separation processor technology, the apparatus comprising synthetic bubbles or beads configured with a polymer or polymer-based material functionalized to attach to a valuable material in a mixture so as to form an enriched synthetic bubbles or beads having the valuable material attached thereto, and also configured to be separated from the mixture based at least partly on a difference in a physical property between the enriched synthetic bubbles or beads having the valuable material attached thereto and the mixture.

Improved sparge compositions for froth flotation separation, methods of using them, and uses thereof are described. The compositions are suitably used in the froth flotation of particulate material containing ultrafine particles, and are well suited to the froth flotation separation of finely comminuted poor (low-grade) ores. The sparge compositions comprise functionalized silicone containing functionality that is tailored to the chemical nature of a beneficiary or a gangue in the ore. Sparging of the compositions effects improved recoveries and purities of beneficiaries. Sparge compositions and functionalized silicones suitable for the froth flotation of iron ores containing silica and/or silicate impurities are described. Sparge compositions and functionalized silicones suitable for the froth flotation of ores containing sulfur compounds such as sulfides are also disclosed.

A synthetic bead for use in mineral separation is described. The synthetic bead has a surface made of a synthetic material such as polymer and the synthetic material is functionalized with molecules having a functional group for attaching mineral particles to the surface in a separation process. The synthetic beads can be placed in flotation cell containing a mixture of water, valuable material and unwanted material or in a pipeline where the mixture is transported from one location to another. The enriched synthetic beads carrying the mineral particles are separated from the unwanted materials in the mixture. The mineral particles are then released from the synthetic beads by means of low pH treatment, ultrasonic agitation, thermal or electromagnetic treatment.

Apparatus featuring synthetic bubbles or beads and a flotation stage. The synthetic bubbles or beads are configured with a polymer or polymer-based material functionalized to attach to the valuable material in a mixture to form at least some enriched synthetic bubbles or beads having the valuable material attached thereto, and also configured to be transported through the mixture based at least partly on a characteristic of the synthetic bubbles or beads. The flotation stage has the mixture containing valuable material, and is configured to receive the synthetic bubbles or beads and to provide the at least some enriched synthetic bubbles or beads having the valuable material attached thereto based at least partly the characteristic of the synthetic bubbles or beads.

An apparatus and method for collecting mineral particles in the tailings is disclosed. The apparatus may take the form of a filter, a conveyor belt, a collection plate or an impeller configured to contact with tailings of a flotation process, before and/or after the tailings are discharged into a pond. The filter, conveyor belt, collection plate or impeller has a collection area or surface made of, or coated with, a synthetic material having a functional group, e.g., having an ionizing bond to attract the mineral particles of interest. Alternatively, the synthetic material has hydrophobic molecules to render the collection area hydrophobic. When the mineral particles of interest in the tailings are combined with collector molecules, the mineral particles of interest may also become hydrophobic. The hydrophobic mineral particles of interest are attracted to the hydrophobic collection area or surface. The filter, conveyor belt, collection plate and impeller may have a plurality of passage ways or synthetic beads in order to increase the contacting surfaces.