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The present invention pertains to a composition comprising at least one compound of formula (I) and to the use of said composition for recovering value minerals from ore and other feedstocks by flotation (formula (I)).

A hydrometallurgical method for simultaneously extracting zinc, lead, silver, iron and calcium from electric arc furnace dust (hazardous waste) produced by the steelmaking industry (steelworks), in the form of industrial products: zinc as zinc sulphate or zinc cathodes; lead and silver as a concentrate of lead and silver; iron as reduced elemental iron for return to the electric arc furnace; and, lastly, calcium as gypsum, without solid waste or liquid effluents being generated relates to the chemical nature of the electric arc furnace dust (complex oxides) changes to a sulfide complex, and eliminating the hazards associated with the generation of fugitive heavy-metal salts. In addition, the hydrometallurgical problem of low recovery of zinc and iron is solved. Consequently, hydrometallurgy is made easier and more environmentally friendly, as condensed water is used as a leachate, the condensed water being continuously regenerated by vacuum evaporation systems without generating effluents.

The flotation reagents from acidic olive oil are made by transesterification of acidic olive oil. Acidic olive oil is olive oil having an acid value high enough to render it unsuitable for consumption, typically greater than 3.3% and/or between 3.3-7%. Transesterification of the olive oil with methanol converts fatty acids in the olive oil to an ester fraction and a glycerol fraction. The ester fraction may be sulfonated and used as the collector in a reverse flotation process, selectively removing the carbonate gangue from phosphate-carbonate rock in the froth, leaving phosphates in the sink. The glycerol fraction may be used without modification as the collector in the reverse flotation process. Both fractions are highly selective for carbonates, substantially reducing loss of phosphates in the froth.

The flotation reagents from acidic olive oil are made by transesterification of acidic olive oil. Acidic olive oil is olive oil having an acid value high enough to render it unsuitable for consumption, typically greater than 3.3% and/or between 3.3-7%. Transesterification of the olive oil with methanol converts fatty acids in the olive oil to an ester fraction and a glycerol fraction. The ester fraction may be sulfonated and used as the collector in a reverse flotation process, selectively removing the carbonate gangue from phosphate-carbonate rock in the froth, leaving phosphates in the sink. The glycerol fraction may be used without modification as the collector in the reverse flotation process. Both fractions are highly selective for carbonates, substantially reducing loss of phosphates in the froth.

A flotation method for mineral processing is disclosed. The method for floating includes a first step of using a first carboxymethyl cellulose (CMC) in a first flotation cell, and a subsequent step includes using a second CMC in a subsequent flotation cell, the first and second CMCs having different characteristics. The first flotation cell may be used in at least one rougher stage and/or at least one rougher-scavenger stage of the flotation method, and the subsequent flotation cell may be used in at least one cleaner stage, and/or at least one cleaner scavenger stage, and/or at least one recleaner stage of the flotation method. A product may be obtained, directly or indirectly, by such a method. A mineral processing plant may use at least two CMCs of different characteristics in flotation for mineral processing.

A flotation method for mineral processing is disclosed. The method for floating includes a first step of using a first carboxymethyl cellulose (CMC) in a first flotation cell, and a subsequent step includes using a second CMC in a subsequent flotation cell, the first and second CMCs having different characteristics. The first flotation cell may be used in at least one rougher stage and/or at least one rougher-scavenger stage of the flotation method, and the subsequent flotation cell may be used in at least one cleaner stage, and/or at least one cleaner scavenger stage, and/or at least one recleaner stage of the flotation method. A product may be obtained, directly or indirectly, by such a method. A mineral processing plant may use at least two CMCs of different characteristics in flotation for mineral processing.

The invention relates to a process for selective flotation of kainite from crushed crude potash salts or, for example, from crystallized salt mixtures obtained by evaporation processes, which in addition to kainite may contain further minerals such as halite, sylvine and other salt minerals, for example, in order to produce a kainite concentrate fraction and a residues fraction. The separation process is characterized in that the crushed or crystallized salt mixture is intensively mixed as a crystallizate suspension with a combination of conditioning agents consisting of a sulfated fatty acid or its alkali metal salt as collecting reagent and a frothing agent known for flotation (for example, glycol ether, monohydric aliphatic alcohols, terpene alcohols, polyglycol ethers, etc.) and is then separated by agitator-driven or pneumatic flotation into a kainite concentrate fraction and a residues fraction. The resulting fractions may be further processed in downstream processes. This process permits industrial-scale processing for selective extraction of kainite from mineral mixtures by means of the flotation process.

The present invention relates to a method of preparing N-acyl amino acids selected from N-acyl cysteine compounds, N-acyl serine compounds, N-acyl aspartic acid compounds and N-acyl glutamic acid compounds. The present invention also relates to the use of N-acyl cysteine, N-acyl serine, N-acyl aspartic acid and N-acyl glutamic acid surfactants, in removing per- and poly-fluoroalkyl substances (PFASs) from mixtures containing PFASs, such as soil and groundwater contaminated with PFASs and for use in cleaning compositions, detergent compositions and toothpaste compositions.

Disclosed herein are methods, devices, and systems for effectively separating carbonate gangue from bastnaesite without sacrificing significant REO grade or recovery. In some embodiments, centrifugal concentrators may beneficiate Ultra-Fine (UF) bastnaesite and calcite bearing flotation concentrates. The disclosed methods, devices, and systems can achieve initial gravity REO recoveries exceeding 90% while rejecting on the order of 25% to 35% of the total calcium from an assortment of rougher and cleaner flotation concentrates. Addition of stages of cleaner UF Falcon gravity separation may be operated in an open circuit configuration, from an original fine feed of 35 microns containing 50.5% REO and 5.5% Ca, to upgrade up to approximately 59% REO and 2.0% calcium. The disclosed methods, devices, and systems may comprise UF gravity concentration that may provide for recovery of rare earth oxides at levels of greater than 70%, 80% and 90%, while also rejecting more than 15%, 20%, 25%, 30, or 35% of the total calcium. Also described are benefication of fine feed of 35 microns containing 50.5% REO and 5.5% Ca, to approximately 59% REO and 2.0% calcium. In some embodiments, the disclosed methods, compounds, and systems may be used to complement existing or modified flotation systems.

Presently claimed invention is directed to a collector composition for the beneficiation of a mineral comprising at least one component (A) selected from the group consisting of anionic (A1) surfactants, cationic (A2) surfactants, ampholytic (A3) surfactants and non-ionic surfactants (A4), and at least one component (B) selected from the group consisting of alkoxylated polyalkyleneimine (B1) and alkoxylated hexamethylene diamine (B2).