The presently claimed invention relates to a process for the beneficiation of coal and other hydrophobic materials, wherein a collector composition comprising by-products obtained by hydroformylation of octene isomers as a first component and diesel, kerosene and/or C.sub.8-C.sub.20 olefins as a second component is used.

A process for cleaning and dewatering hydrophobic particulate materials is presented. The process is performed in in two steps: 1) agglomeration of the hydrophobic particles in a first hydrophobic liquid/aqueous mixture; followed by 2) dispersion of the agglomerates in a second hydrophobic liquid to release the water trapped within the agglomerates along with the entrained hydrophilic particles.

The coal-derived solid hydrocarbon particles are discrete particles of coal-derived carbonaceous matter having a particle size less than about 10 μm that are substantially free of inherent or entrained mineral matter. The particles of have an average particle size in the range from 1 μm to 8 μm. The particles of coal-derived carbonaceous matter are milled to a size approximately the same as a size of coal-derived mineral matter inherent in the coal source to release inherent coal-derived mineral matter particles such that the particles of carbonaceous matter and the particles of mineral matter are discrete and separable solid particles. Following separation, less than 1.5 wt. % discrete coal-derived mineral matter particles are associated with the discrete particles of coal-derived carbonaceous matter. Particles of coal-derived solid hydrocarbon matter are blended with a gaseous or liquid hydrocarbon fuel to form a two-phase hydrocarbon fuel feedstock.

A flotation process for treating coal slime in which coal slime, a collecting agent and a frothing agent are fed into an ore slurry pretreater, and salt-containing waste water of coal chemical industry discharged from a coal chemical enterprise is fed as dilution water into the ore slurry pretreater and mixed together to complete mineralization; the mineralized ore slurry is subjected to a rough separation operation, the products obtained in the rough separation operation are subjected to a fine separation operation, and the ash content of the fine separation tailings is tested with an ash analyzer; the tailings are returned into the ore slurry pretreater for separation again if the ash content of the fine separation tailings is greater than 20%; otherwise the tailings are discharged as fine separation tailing products if the ash content of the fine separation tailings is smaller than 20%; the fine separation tailing products discharged through a pipeline enter into a pressure filter for dehydration, and filter cakes are discharged as a finally accepted concentrate product after the dehydration in the pressure filter.

A process for upgrading of a coal product is provided. The process comprising the steps of: (i) providing a purified coal composition, wherein the composition is in the form of solid particles, and wherein at least about 90% by volume (% vol) of the solid particles are no greater than about 500 μm in diameter; and (ii) combining the purified coal composition with a solid coal feedstock, in order to create a combined solid-solid blend upgraded coal product. Further a process for preparation of a purified coal product is provided. The process comprising the steps of: obtaining a starting material that comprises coal; subjecting the starting material to at least one fine grinding stage so as to reduce the starting material to a particulate composition in which substantially all of the particles are no more than 500 microns (μm) in diameter; exposing the particulate composition to at least one froth flotation stage so as to separate hydrocarbonaceous material comprised within the particulate composition from mineral matter, wherein during the at least one froth flotation stage the hydrocarbonaceous material is associated with froth produced and separated from the at least one froth flotation stage; washing the froth separated from the at least one froth flotation stage with water to release the hydrocarbonaceous material; and subjecting the hydrocarbonaceous material to at least one dewatering stage so as to obtain a particulate purified coal product that has an ash content of less than 12% m, a water content of less than 25% m and wherein the particles comprised within the particulate purified coal product have a d90 of less than 00 μm. Products, such as pelletized or briquetted coal, comprising purified coal material obtainable via the described processes are also provided.

A process for upgrading of a coal product is provided. The process comprising the steps of: (i) providing a purified coal composition, wherein the composition is in the form of solid particles, and wherein at least about 90% by volume (% vol) of the solid particles are no greater than about 500 μm in diameter; and (ii) combining the purified coal composition with a solid coal feedstock, in order to create a combined solid-solid blend upgraded coal product. Further a process for preparation of a purified coal product is provided. The process comprising the steps of: obtaining a starting material that comprises coal; subjecting the starting material to at least one fine grinding stage so as to reduce the starting material to a particulate composition in which substantially all of the particles are no more than 500 microns (μm) in diameter; exposing the particulate composition to at least one froth flotation stage so as to separate hydrocarbonaceous material comprised within the particulate composition from mineral matter, wherein during the at least one froth flotation stage the hydrocarbonaceous material is associated with froth produced and separated from the at least one froth flotation stage; washing the froth separated from the at least one froth flotation stage with water to release the hydrocarbonaceous material; and subjecting the hydrocarbonaceous material to at least one dewatering stage so as to obtain a particulate purified coal product that has an ash content of less than 12% m, a water content of less than 25% m and wherein the particles comprised within the particulate purified coal product have a d90 of less than 00 μm. Products, such as pelletized or briquetted coal, comprising purified coal material obtainable via the described processes are also provided.

The present invention relates to methods for beneficiating a banded coal of the type wherein a substantial portion of the ash constituents is within the cleats. The method includes subjecting a comminuted coal feed, including coal and ash and having a particle size of about −13.5 mm, to a density separation process to separate the comminuted coal feed, using a separating gravity value of from about 1.35 up to about 1.9, into a beneficiated coal fraction and an ash containing gangue fraction. The method may include the initial steps of subjecting a coarse coal having a size of up to −150 mm to a density separation process to separate the coarse coal into an initial light coal-containing fraction and an initial heavy ash containing gangue fraction; and subjecting at least a portion of the initial light coal-containing fraction to a comminution process to form the comminuted coal feed. The invention extends to a coal product produced by said methods.

A separation system is disclosed for separating selected particles from a mixture of particles in a fluid. The system includes a froth flotation vessel into which in use the mixture of particles and fluid are subjected to an upward flow of an introduced gas to form a froth layer which rises above an interface formed between the froth layer and the mixture of particles and fluid, such that a quantity of the selected particles is conveyed out of the vessel by the froth layer to become a first product of the system. The vessel also has a first outlet arranged in use for receiving a flow of some of the mixture of particles and fluid from the vessel, an entry to the first outlet being located in a region proximate to, but below, the interface. The vessel also has a second outlet arranged in use for receiving a flow of some of the mixture of particles and fluid from a region of the vessel which is located below the first outlet. In use the first outlet receives a quantity of the selected particles which were not conveyed out of the vessel by the froth layer, and the second outlet receives a quantity of the selected particles in a first by-product of the system. The first by-product comprises a relatively higher percentage of solids compared to the flow of particles and fluid in the first outlet. The flow of the mixture of particles and fluid from the vessel via the first outlet passes to a classification device, which separates the flow into two or more fractions on the basis of their size or density or a combination of the two.

Processes for macroscopically separating a maceral concentrate from raw coal are disclosed. In some embodiments, a process includes the following steps: crushing and sieving the raw coal to obtain a first coal sample and a second coal sample; subjecting the first coal sample to a heavy medium cyclone separation process; and subjecting the second coal sample to a froth flotation process. The first coal sample has a particle size within a first particle size range, and the second coal sample has a particle size within a second particle size range. In other embodiments, the froth flotation process uses a froth flotation agent including a foaming agent and a collector. The foaming agent includes at least one item selected from the group consisting of 2-octanol, terpenic oil, and polyethylene glycol (PEG). The collector includes at least one item selected from the group consisting of kerosene, diethyl phthalate (BET), and diesel.

Processes for macroscopically separating a maceral concentrate from raw coal are disclosed. In some embodiments, a process includes the following steps: crushing and sieving the raw coal to obtain a first coal sample and a second coal sample; subjecting the first coal sample to a heavy medium cyclone separation process; and subjecting the second coal sample to a froth flotation process. The first coal sample has a particle size within a first particle size range, and the second coal sample has a particle size within a second particle size range. In other embodiments, the froth flotation process uses a froth flotation agent including a foaming agent and a collector. The foaming agent includes at least one item selected from the group consisting of 2-octanol, terpenic oil, and polyethylene glycol (PEG). The collector includes at least one item selected from the group consisting of kerosene, diethyl phthalate (BET), and diesel.