The present invention relates to a method for the layer-by-layer production of a cured three- dimensional shaped body, wherein the method comprises at least: (i) providing a binder comprising at least the following components: a) monomeric furfuryl alcohol and optionally a resin component comprising at least a furan resin, wherein about 60% by weight to 100% by weight of monomeric furfuryl alcohol, based on the sum of monomeric furfuryl alcohol and resin component are present in the binder, and b) a hardener component selected from methanesulfonic acid, benzenesulfonic acid, and mixtures thereof, (ii) providing a layer of a refractory molding material to provide a molding material layer, (iii) selectively applying a component a) or b) of the binder separately from the refractory molding material to at least a part of the molding material layer, (iv) applying the other component of the binder separately from the component mentioned in step (iii), wherein step (iv) can be carried out before or after step (iii), or step (iv) can be combined with step (ii), and (v) optionally repeating steps (ii), (iii), and (iv) once or several times. Shaped bodies obtainable thereby as well as their use are disclosed as well.

A casting method of using 3D printing to make shell mold, comprising the following steps of: conducting computer-aided graphic design based on the product to be manufactured; importing the graphic design into the 3D printer to print a 3D shell mold; conducting a sintering process of the printed shell mold for solidifying thereof; using the sintered shell mold as a casting cavity, injecting a molten raw material into the shell mold for formation; in the end, taking out the whole shell mold and breaking the shell mold to obtain a cast product; reprocessing the cast product to obtain a finished product; wherein printing materials of the 3D printing are made of a liquid mixture of photosensitive resin and ceramic powder, thereby improving production efficiency and reducing labor intensity as well as pollution.

A casting method of using 3D printing to make shell mold, comprising the following steps of: conducting computer-aided graphic design based on the product to be manufactured; importing the graphic design into the 3D printer to print a 3D shell mold; conducting a sintering process of the printed shell mold for solidifying thereof; using the sintered shell mold as a casting cavity, injecting a molten raw material into the shell mold for formation; in the end, taking out the whole shell mold and breaking the shell mold to obtain a cast product; reprocessing the cast product to obtain a finished product; wherein printing materials of the 3D printing are made of a liquid mixture of photosensitive resin and ceramic powder, thereby improving production efficiency and reducing labor intensity as well as pollution.

The present invention relates to a resin composition that comprises an acetoacetate ester compound with at least two acetoacetate ester functional groups, an acrylate compound with at least two acrylate functional groups, and a tertiary amine curing catalyst. This resin composition acts as an isocyanate-free binder that is less toxic to the environment. The invention further discloses a method for preparation fiber reinforced parts comprising fibers and said resin composition as well as a method for the preparation of foundry molds for the casting industry, which is based on said binder.

In light of increasingly severe and diverse excavation conditions for hydrocarbon resource recovery, such as the drilling of very deep wells, provided is a highly impact-resistant polyglycolic acid resin composition that is resistant to damage even from contact or collision with various members during molding, transport, and well drilling; has excellent mechanical properties and heat resistance; can easily be removed as necessary after the completion of well treatment; and contributes to reducing the cost and shortening the process of well drilling. Also, provided is a molded product for well drilling, such as a downhole tool member.

According to the invention, by setting the linear thermal expansion amount when a mold made of a molding sand is heated from a room temperature to 1000° C. to be not more than 0.9%, and the ratio (D/d) between the diameter of a slump (D) and the diameter of a slump cone (d) in a slump test of the molding sand having a hardening agent kneaded to be not less than 1.65, a molding sand preferable for use in a mold produced using the self-hardening type of three dimensional laminate molding sand mold, having low thermal expansibility preventing occurrence of a veining defect, and capable of forming a large and complicated shape can be obtained.

According to the invention, by setting the linear thermal expansion amount when a mold made of a molding sand is heated from a room temperature to 1000° C. to be not more than 0.9%, and the ratio (D/d) between the diameter of a slump (D) and the diameter of a slump cone (d) in a slump test of the molding sand having a hardening agent kneaded to be not less than 1.65, a molding sand preferable for use in a mold produced using the self-hardening type of three dimensional laminate molding sand mold, having low thermal expansibility preventing occurrence of a veining defect, and capable of forming a large and complicated shape can be obtained.

A method to form a displacement, the method including disposing a powder blend comprising a plurality of ground ceramic particles and a plurality of ground resin particles into a mold, densifying the powder blend while in the mold, heating the mold to form a first displacement, impregnating said first displacement with a polymer precursor compound to form a second displacement, and heating the second displacement to form a third displacement.

A method to form a displacement, the method including disposing a powder blend comprising a plurality of ground ceramic particles and a plurality of ground resin particles into a mold, densifying the powder blend while in the mold, heating the mold to form a first displacement, impregnating said first displacement with a polymer precursor compound to form a second displacement, and heating the second displacement to form a third displacement.

The invention relates to a method for producing three-dimensionally layered shaped bodies by means of layer-by-layer construction using a resin component which contains at least one furane resin, and more than 5% by weight and less than 50% by weight monomer furfuryl alcohol, and an acid. The shaped bodies produced in this manner are suitable inter alia as casting molds and casting cores for metal casting.