The present disclosure provides a preparation method of a metal powder material. An alloy sheet composed of a matrix phase and a dispersive phase with different chemical reactivities is prepared by the rapid solidification technique of alloy melt. Metal powder is prepared by the reaction of the alloy sheet and an acid solution. Please refer to the description for the detailed preparation method. This method is simple in operation, can be used to prepare many kinds of metal powder materials of different shapes and at the nanometer scale, the submicron scale and the micron scale, and has a good application prospect in the fields of catalysis, powder metallurgy and 3D printing.

This invention concerns a versatile and simple one-pot method to prepare nanomaterials, and in particular nanoparticles, grafted with an ultra-thin layer of calixarenes by placing at 5 least one oxidized metal with at least one calix[n]arene diazonium salt in the presence of a reducing agent in a solvent, and heating the traction mixture to obtain a metal-based nanomaterial coated with calix[n]arenes. The invention further concerns the coupling of organic molecules or biomolecules to the calixarene-grafted nanomaterials in order to further functionalize the surface of the particles. The metal-based nanomaterial coated with 10 calix[n]arenes can for example be used in immunoassays.

The present invention relates to a process for purifying metal nanowires, comprising at least the following steps: (i) providing a suspension of metal nano-objects in a hydroalcoholic solvent medium having a viscosity at 25° C. strictly less than 10 mPa.Math.s, the metal nano-objects including fine nanowires and additional nanoparticles different from the fine nanowires; (ii) adding, to the metal nano-object suspension, metalloid or metal oxide nanoparticles having a diameter less than or equal to 50% of the average diameter of the nanowires; (iii) allowing the suspension of metal nano-objects with the added metalloid or metal oxide nanoparticles to settle under conditions conducive to the precipitation of the fine metal nanowires; and (iv) recovering the settled solids made from the fine metal nanowires.

Atomic-to-Nanoscale Matter Emission/Flow Regulation Devices, Systems and methods are set forth. An exemplary device can include a through-hole that has a top, and a nozzle configured to facilitate atomic-to-nanoscale matter emission/flow regulation formed in an etchable nozzle substrate. The nozzle can be configured at the smallest cross-section of the through-hole. A bottom can be formed in the nozzle substrate or selectively connected to the nozzle. Systems can include matter transportation/flow regulation columns, printing systems, etching systems and the like through which self-aligned nanodroplets or single-to-finite numbered ionic species/gas phase matter can flow under spontaneous or external excitation conditions (such as voltages) at atmospheric as well as regulated pressures.

Atomic-to-Nanoscale Matter Emission/Flow Regulation Devices, Systems and methods are set forth. An exemplary device can include a through-hole that has a top, and a nozzle configured to facilitate atomic-to-nanoscale matter emission/flow regulation formed in an etchable nozzle substrate. The nozzle can be configured at the smallest cross-section of the through-hole. A bottom can be formed in the nozzle substrate or selectively connected to the nozzle. Systems can include matter transportation/flow regulation columns, printing systems, etching systems and the like through which self-aligned nanodroplets or single-to-finite numbered ionic species/gas phase matter can flow under spontaneous or external excitation conditions (such as voltages) at atmospheric as well as regulated pressures.

The devices and systems described herein generally relate to magnetic field chambers and reversibly hardenable ferrofluids. The reversibly hardenable ferrofluid can include a magnetically responsive fluid and a reversible hardening agent. The reversibly hardenable ferrofluid can achieve a first shape using one or more magnetic fields, such as delivered from a magnetic field chamber. Once the first shape is achieved, the reversibly hardenable ferrofluid can be cured or otherwise hardened. The hardened reversibly hardenable ferrofluid can be used for the intended purpose and then returned to a liquid state once the task is completed, allowing for reuse. The steps of hardening and liquifying can be mediated by the magnetic field chamber, as described in embodiments herein.

The present invention provides a process for making nanoparticle based bulk materials. Also provided is a single component metal nanoparticle based bulk glass material comprising less than about 1% by weight of ligand capped nanocrystals; and wherein the metal is palladium.

Provided are a dispersion medium for metal particle sintering that gives an electroconductive paste whereby metal particles are satisfactorily sintered at a low temperature even when not in a reducing atmosphere, and an electroconductive paste in which the dispersion medium is used. The dispersion medium for metal particle sintering according to an embodiment of the present disclosure contains formic acid and a basic compound, the basic compound being a nitrogen-containing compound represented by Formula (1), and a molar ratio (basic group/formic acid) of basic groups included in the basic compound to formic acid being from 0.50 to 1.20. [Formula 1] In Formula (1): R.sup.a to R.sup.c are the same or different and each represent a hydrogen atom or a hydrocarbon group that may have a substituent; the double line including a dashed line represents a single bond or a double bond, with R.sup.c being absent in the case of a double bond; and any two of R.sup.a to R.sup.c may bond with each other and form a ring together with the adjacent nitrogen atom.

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Various embodiments provide a method of additively manufacturing a part including depositing a layer of a powder on a working surface, depositing a binder solution on the layer of the powder at first locations, and depositing a sintering aid solution on the layer of the powder at second locations. The sintering aid solution comprises a sintering aid in a solvent. In various embodiments, the sintering aid enables an increased brown strength as compared to parts containing unbound powder. The method enables binders that provide high green strength to be used at the edges of the part, while also balancing a shortened debind time with an increased brown strength. Embodiments in which binder solution is deposited according to a predetermined pattern at second locations are also described.

Disclosed are methods for building colloidal solids by precipitation from a liquid bridge using a needle through which a colloidal particle suspension is dispensed onto a substrate in a temperature-controlled environment. The substrate can rest on a motion-controlled stage, and freeform shapes can be built by coordinating the motion of the stage with the rate of dispense of colloidal particle suspension. Aspects include a scaling law that governs the rate of assembly and a direct-write colloidal assembly process that combines self-assembly with direct-write 3D printing, and can be used to build exemplary freestanding structures using a diverse materials, such as polystyrene, silica and gold particles. Additionally, disclosed are methods for predicting and eliminating cracking by a geometric relationship between particle size and structure dimensions, enabling the production of macroscale, crack-free colloidal crystals.