Methods of forming metal multipod nanostructures. The methods may include providing a mixture that includes a metal acetylacetonate, a reducing agent, and a carboxylic acid. The mixture may be contacted with microwaves to form the metal multipod nanostructures. The methods may offer control over the structure and/or morphology of the metal multipod nano structures.

This invention concerns a versatile and simple one-pot method to prepare nanomaterials, and in particular nanoparticles, grafted with an ultra-thin layer of calixarenes by placing at 5 least one oxidized metal with at least one calix[n]arene diazonium salt in the presence of a reducing agent in a solvent, and heating the traction mixture to obtain a metal-based nanomaterial coated with calix[n]arenes. The invention further concerns the coupling of organic molecules or biomolecules to the calixarene-grafted nanomaterials in order to further functionalize the surface of the particles. The metal-based nanomaterial coated with 10 calix[n]arenes can for example be used in immunoassays.

The present invention relates to a process for purifying metal nanowires, comprising at least the following steps: (i) providing a suspension of metal nano-objects in a hydroalcoholic solvent medium having a viscosity at 25° C. strictly less than 10 mPa.Math.s, the metal nano-objects including fine nanowires and additional nanoparticles different from the fine nanowires; (ii) adding, to the metal nano-object suspension, metalloid or metal oxide nanoparticles having a diameter less than or equal to 50% of the average diameter of the nanowires; (iii) allowing the suspension of metal nano-objects with the added metalloid or metal oxide nanoparticles to settle under conditions conducive to the precipitation of the fine metal nanowires; and (iv) recovering the settled solids made from the fine metal nanowires.

The present invention relates to a process for purifying metal nanowires, comprising at least the following steps: (i) providing a suspension of metal nano-objects in a hydroalcoholic solvent medium having a viscosity at 25° C. strictly less than 10 mPa.Math.s, the metal nano-objects including fine nanowires and additional nanoparticles different from the fine nanowires; (ii) adding, to the metal nano-object suspension, metalloid or metal oxide nanoparticles having a diameter less than or equal to 50% of the average diameter of the nanowires; (iii) allowing the suspension of metal nano-objects with the added metalloid or metal oxide nanoparticles to settle under conditions conducive to the precipitation of the fine metal nanowires; and (iv) recovering the settled solids made from the fine metal nanowires.

Disclosed is a method for producing transition metal oxide fine particles having a size smaller than several micrometers (μm), and more preferably, having a size of several hundred nanometers (nm). To this end, the method for producing transition metal oxide fine particles of the present invention comprises dissolving a transition metal oxide in a strongly basic aqueous solution, and titrating same with a strongly acidic aqueous solution, thereby precipitating transition metal oxide fine particles.

The supported catalyst synthesis device according to the present disclosure includes a first source for a liquid containing a reducing agent; a second source for a liquid containing elements to constitute single-metal fine particles or solid solution fine particles to be supported; a third source for a liquid containing support particles; a reaction unit that joins flows of these liquids; a liquid feed route connecting between the first source and the reaction unit; a liquid feed route connecting between the second source and the reaction unit; a liquid feed route connecting between the third source and the reaction unit; and a collection unit, connected to the reaction unit via a pipe, to collect a produced reaction product, and further includes a pressure adjustment mechanism connected to the collection unit.

Fluorescent bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) of silver-gold (Ag@Au-NC) and silver-platinum (Ag@Pt-NC) are prepared by reducing silver nitrate (AgNO.sub.3) on gold nanoparticles (AuNPs) and platinum nanoparticles (PtNPs) using sodium borohydride (NaBH.sub.4) at alkaline pH=11, in the presence of a lysozyme that acts as a template, and in the presence of a capping and stabilizing agent. The biocompatible bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) have promising multifunctional applications (cell imaging, bio-sensing, therapeutics) observed by both in vitro as well as in vivo experiments. The fluorescent bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) of silver-gold (Ag@Au-NC) and silver-platinum (Ag@Pt-NC) may be useful as an alternative nanomedicine in cancer theranostics applications.

Fluorescent bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) of silver-gold (Ag@Au-NC) and silver-platinum (Ag@Pt-NC) are prepared by reducing silver nitrate (AgNO.sub.3) on gold nanoparticles (AuNPs) and platinum nanoparticles (PtNPs) using sodium borohydride (NaBH.sub.4) at alkaline pH=11, in the presence of a lysozyme that acts as a template, and in the presence of a capping and stabilizing agent. The biocompatible bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) have promising multifunctional applications (cell imaging, bio-sensing, therapeutics) observed by both in vitro as well as in vivo experiments. The fluorescent bimetallic nanocomposites (M.sub.1@M.sub.2-NCs) of silver-gold (Ag@Au-NC) and silver-platinum (Ag@Pt-NC) may be useful as an alternative nanomedicine in cancer theranostics applications.

Processes are provided for producing a titanium alloy material, such as Ti—Al alloys. In one embodiment, the process includes: heating an input mixture to a preheat temperature with the input mixture including aluminum, optionally, AlCl.sub.3, and, optionally ally, one or more alloying element halide; introducing TiCl.sub.4 to the input mixture at the first reaction temperature such that substantially all of the Ti.sup.4+ in the TiCl.sub.4 is reduced to Ti.sup.3+; thereafter, heating to a second reaction temperature such that substantially all of the Ti.sup.3+ is reduced to Ti.sup.2+ to form an intermediate mixture (e.g., a Ti.sup.2+ salt); and introducing the intermediate mixture into a reaction chamber at a disproportionation temperature reaction to form the titanium alloy material from the Ti.sup.2+ via a disproportionation reaction.

Processes are provided for producing a titanium alloy material, such as Ti—Al alloys. In one embodiment, the process includes: heating an input mixture to a preheat temperature with the input mixture including aluminum, optionally, AlCl.sub.3, and, optionally ally, one or more alloying element halide; introducing TiCl.sub.4 to the input mixture at the first reaction temperature such that substantially all of the Ti.sup.4+ in the TiCl.sub.4 is reduced to Ti.sup.3+; thereafter, heating to a second reaction temperature such that substantially all of the Ti.sup.3+ is reduced to Ti.sup.2+ to form an intermediate mixture (e.g., a Ti.sup.2+ salt); and introducing the intermediate mixture into a reaction chamber at a disproportionation temperature reaction to form the titanium alloy material from the Ti.sup.2+ via a disproportionation reaction.