The invention relates to a method for the treatment of cellulosic material. The method is comprising the steps of impregnation of the cellulosic material and treatment of the impregnated cellulosic material by a fumigation step or an evaporation step. Impregnation is performed with a metal ion M and at least one ion precursor Z yielding an impregnated cellulosic material. The at least one ion precursor Z provides an anion A or an anion A and a cation Y comprised within at least one metal salt solution I or with a metal salt solution II comprising a metal ion M. The fumigation or evaporation step is yielding a cellulosic composite material comprising a compound M(NH4)A, MYA or M(OH)x, wherein M is a metal.

This invention relates to a process for modifying wood. The process comprises treating the wood with an impregnating solution comprising an alkali metal (or alkaline earth metal) silicate, under conditions sufficient to impregnate the wood with one or more of the components of the impregnating solution. The process can comprise an optional second impregnation with a second impregnating solution. The process also comprises adding gaseous carbon dioxide to the treated wood, in the absence or presence of water, under pressure ranging from about 2 to about 12 bars, thereby lowering the pH of the treated wood to about 11 or below, to stabilize and/or fix the components of the impregnating solution in the wood. The process is green, non-toxic, and the resulting modified wood or wood product can be used across all primary construction and infrastructure applications.

A method for reinforcing and enhancing bamboo/wood materials employs a sulfuric acid hydrolysis method to prepare a nanocellulose dispersion solution; then with the nanocellulose dispersion solution having a certain concentration as a precursor, nano zinc oxide is in-situ produced on the surface of the nanocellulose; and the cellulose dispersion solution is improved by compounding. The obtained treatment solution is impregnated into the pores of bamboo/wood materials in a specific manner to play the role of filling, binding and consolidating the bamboo/wood tissues, so that the treated bamboo/wood materials have enhanced hardness, strength and dimension stability, and significantly-improved mildew- and corrosion-resistance. The method is suitable for the reinforcing and enhancing treatment of wood materials with relatively-loose texture, such as fast-growing wood and wood from a planted forest, and is also suitable for the reinforcement and restoration of slightly-rotten wood materials.

The present invention is directed to a method for manufacturing a drylaid mat suitable for thermoforming. The present invention is directed to a dry forming process, wherein cellulosic or lignocellulosic fibers have been impregnated, but not cross linked, with a cross linking agent prior to forming in a dry forming method. The invention is also directed to dry-laid mats manufactured according to the method as well as to thermoformed products manufactured from such dry-laid mats.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper ammine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.

In one inventive concept, a product for modifying a cellulose-lignin material with siloxane includes a mixture having a siloxane species, a metal catalyst, and a nonpolar solvent. The mixture is operative to modify a cellulose-lignin material with siloxane upon wetting of the cellulose-lignin material with the mixture and subsequent drying of the cellulose-lignin material. In another inventive concept, a product includes a siloxane-modified cellulose-lignin material having a cellulose-lignin network and a network of siloxane in cross-linking bridges in the cellulose-lignin network.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising an aqueous alkaline copper-containing solution comprising copper tetraammine carbonate; and exposing the cellulosic material provided thereby to carbon dioxide to provide treated cellulosic material.

The invention concerns a process for treating lignocellulosic material, preferably wood, comprising the following successive steps: (1) extracting lignin by a fluid in supercritical or subcritical phase to extract 40 to 85% by weight % of the lignin of the initial material; (2) filling by a filling compound, preferably in the presence of a fluid in supercritical or subcritical phase; and (3) finishing, so as to obtain a composite material formed by a three-dimensional network of filling compound that is transformed and incorporated in a network of cellulose and lignin.

A treatment process and wood products thereof including a product formulation of a single phase solution combining a wood preservative (durable component) with a Flame Retardant component (FR) to produce a durable Flame Retardant (dFR) treated wood product. The durable component comprises a range of copper based and non-copper based wood preservatives, while the FR component comprises alkali metal silicates and alkali metal aluminate compounds. The dFR working solution undergoes chemical impregnation (treatment) followed by a heat (fixation) process step that locks the chemical into the wood making it non-leachable. The dFR treated wood products are tested for their enhanced fire performance properties. When heated, wood undergoes thermal degradation and combustion producing gases, vapors, tars and chars. Using a cone calorimeter burn test method, dFR treated wood products show a significant reduction in heat release rate, mass loss rate and smoke generated values compared to untreated radiate pine.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper amine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.