In an example of a three-dimensional (3D) printing method, a ceramic build material is applied. A liquid functional material, including an anionically stabilized susceptor material, is applied to at least a portion of the ceramic build material. A sintering aid/fixer fluid, including a cationically stabilized amphoteric alumina particulate material, is applied to the at least the portion of the ceramic build material. The applied anionically stabilized susceptor material and the applied cationically stabilized amphoteric alumina particulate material react to immobilize the anionically stabilized susceptor material, thereby patterning the at least the portion of the ceramic build material.

An additive manufacturing apparatus includes a platform, one or more supports positioned above the platform, an actuator, a first dispenser system configured dispense a plurality of successive layers of powder onto a build area supported by the platform, a first binder material dispenser configured to selectively dispense a first binder material on a voxel-by-voxel basis to an uppermost layer of powder in the build area, and an energy source configured to emit radiation toward the platform so as to solidify the binder material. The first dispenser system includes a first powder dispenser that is attached to and moves with a first support from the one or more supports and is configured to selectively dispense a first powder onto the build area, and a second powder dispenser that is configured to selectively dispense the second powder onto the build area.

Provided is a three-dimensional object formation method for forming a three-dimensional object by at least repeating: forming a powder material layer using a powder material for three-dimensional object formation containing a base material coated with an organic material; and hardening a predetermined region of the powder material layer by delivering a hardening liquid to the powder material layer formed in the formation of a powder material layer, where the hardening liquid contains a cross-linking agent cross-linkable with the organic material.

Provided is a three-dimensional object formation method for forming a three-dimensional object by at least repeating: forming a powder material layer using a powder material for three-dimensional object formation containing a base material coated with an organic material; and hardening a predetermined region of the powder material layer by delivering a hardening liquid to the powder material layer formed in the formation of a powder material layer, where the hardening liquid contains a cross-linking agent cross-linkable with the organic material.

Provided is a three-dimensional shaped article with relatively high strength and relatively high accuracy. A sintering and shaping method includes: a shaping layer forming process of forming a shaping layer by using a sintering and shaping material in which inorganic particles are included; a process of applying a liquid binding agent, in which a thermoplastic resin and inorganic particles are included, to a desired region of the shaping layer; a process of curing the liquid binding agent, which is applied, to form a shaping cross-sectional layer (shaping portion); a process of removing a region (non-shaping portion) of the shaping layer to which the liquid binding agent is not applied; and a process of heating the shaping cross-sectional layer that is laminated for a sintering treatment.

In a three-dimensional printing method example, build material granules are applied. Each of the build material granules includes uncoated, primary ceramic particles agglomerated together by a binder that is soluble in a primary solvent of a fusing agent. The fusing agent is selectively applied on at least a portion of the build material granules. The binder dissolves and a green body including a slurry of the uncoated, ceramic particles is created.

An additive manufacturing apparatus includes a platform, one or more supports positioned above the platform, an actuator, a first powder dispenser that is attached to and moves with a first support from the one or more supports and is configured to selectively dispense a first powder onto the build area, a first binder material dispenser configured to selectively dispense a first binder material on a voxel-by-voxel basis to an uppermost layer of powder in the build area to form a volume of the layer having powder and binder material and corresponding to a cross-sectional portion of a part being built, a third dispensing system configured to deliver a densification material to the layer of powder or the combined layer of powder and binder material, and an energy source configured to emit radiation toward the platform so as to solidify the binder material.

A method for the manufacture of a three-dimensional object using a refractory matrix material is provided. The method includes the additive manufacture of a green body from a powder-based refractory matrix material followed by densification via chemical vapor infiltration (CVI). The refractory matrix material can be a refractory ceramic (e.g., silicon carbide, zirconium carbide, or graphite) or a refractory metal (e.g., molybdenum or tungsten). In one embodiment, the matrix material is deposited according to a binder-jet printing process to produce a green body having a complex geometry. The CVI process increases its density, provides a hermetic seal, and yields an object with mechanical integrity. The residual binder content dissociates and is removed from the green body prior to the start of the CVI process as temperatures increase in the CVI reactor. The CVI process selective deposits a fully dense coating on all internal and external surfaces of the finished object.

Provided is a three-dimensional structure manufacturing apparatus which manufactures a three-dimensional structure by repeatedly forming layers by using three-dimensional formation compositions containing three-dimensional formation powders, the apparatus including: a formation unit in which the three-dimensional structure is formed; and a layer formation unit which forms the layers configured with the three-dimensional formation compositions on the formation unit, in which a distance between the formation unit and the layer formation unit is adjusted according to the number of times the layer is formed.

An additive manufacturing apparatus includes a platform, one or more supports positioned above the platform, an actuator, a first powder dispenser that is attached to and moves with a first support from the one or more supports and is configured to selectively dispense a first powder onto the build area, a first binder material dispenser configured to selectively dispense a first binder material on a voxel-by-voxel basis to an uppermost layer of powder in the build area to form a volume of the layer having powder and binder material and corresponding to a cross-sectional portion of a part being built, a third dispensing system configured to deliver a densification material to the layer of powder or the combined layer of powder and binder material, and an energy source configured to emit radiation toward the platform so as to solidify the binder material.