A die assembly (5) including: (i) a die plate (10) having an inlet surface (15) and an opposing discharge surface (35); (ii) an inlet (30) on the inlet surface (15) and a first axis of symmetry (A) extending through the inlet (30) and perpendicular to the inlet surface (15); (iii) a discharge port (45) on the discharge surface (35) and a second axis of symmetry (B) extending through the discharge port (45) and perpendicular to the discharge surface (35). The first and second axes are apart from, and parallel to, one another. The die assembly (5) includes (iv) an extrudate passage (42) fluidly connecting the inlet (30) and the discharge port (45). A third axis of symmetry (C) extends through the extrudate passage (42). The die assembly (5) includes (v) a nozzle (100) mounted in the die plate (10), the nozzle (100) having an injection tip (110) in the extrudate passage (42) at the discharge port (45); and (vi) the third axis of symmetry (C) intersects the first axis of symmetry (A) to form an acute angle.

A method of extruding a melt of a linear low-density polyethylene (LLDPE) without surface melt fracture, the method comprises heating a melt of the LLDPE to a temperature from 190.0 to 260.0 degrees Celsius; and extruding through a die the heated melt at a shear rate of from 1,100 to 7,000 per second and at a shear stress of greater than 0.40 megapascal, thereby forming a polyethylene extrudate without surface melt fracture.

A molded article of a composite resin containing fibers includes a base resin 1 and a fibrous filler 2 having fibrillated ends in a fiber length direction. An expression Ho × 0.4 ≤ H ≤ Ho is satisfied where H is a maximum height for an unbroken first plate-like test piece having a thickness of 1 to 2 mm after the test piece is kept at -10° C. for three hours and then is hit by a dropped weight of 250 g; and Ho is as same maximum height for the unbroken second plate-like test piece only made of the base resin with a thickness of 1 to 2 mm as for the first plate-like test piece. An expression So × 0.4 ≤ s ≤ So is satisfied where S is a Charpy impact strength (JIS K 7111) of the molded article, and So is a Charpy impact strength of the molded article only made of the base resin.

The present invention describes a process to convert non-biodegradable polymeric raw materials or pellets/granules into biodegradable raw materials/pellets/granules by applying enzyme-based coating, in water or suitable solvent or combination thereof, on their surfaces, before construction of the components from them.

A high-strength high-modulus graphene/nylon-6 fiber and a preparation method thereof are provided. The fiber is obtained through processing modified graphene and caprolactam with in situ polymerization and high-speed melt spinning. A graphene/nylon-6 composite is provided, which is obtained through compositing the modified graphene, the caprolactam and an additive. Based on the composite, a graphene/nylon-6 fabric with a permanent far-infrared healthcare function and a graphene/nylon-6 fabric with an ultraviolet protective property are provided, whose far-infrared property and ultraviolet protective property will not be attenuated due to an increase of fabric washing times, having a great market potential.

The present invention describes a process of manufacturing biodegradable PET chips, comprising the steps of providing a purified terephthalic acid (PTA) in a predetermined quantity in a slurry tank; providing virgin monoethylene glycol (MEG) in a predetermined quantity in the slurry tank; transferring the combination of the slurry tank to an esterification reactor for esterification of the combination in the reactor at above 250° C. temperature which releases monomers; transferring the monomers from the esterification reactor to a polymerisation reactor; providing poly-catalysts such as, but not limited, to Ti-based catalyst, sb2O3 or any other suitable catalysts or combination thereof into the polymerisation reactor; and polymerization of the monomers in the polymerisation reactor at above 280° C. temperature, wherein an enzyme based composition is provided either at PTA/MEG stage or poly-catalyst stage or at other stages or combination thereof.

Disclosed is a device for cooling particulate materials or particles, in particular granulates of polymeric materials, having an outer container with an, in particular frustoconical, outer shell surface and an inner container, which is arranged at least in sections in the interior of the outer container, with an, in particular frustoconical, inner shell surface, wherein an intermediate space is formed between the outer shell surface and the inner shell surface, wherein an inlet equipment for introducing a gas flow as well as the particles into the intermediate space is provided in an inlet-side initial region of the device, and wherein an outlet opening for the particles is provided in an outlet-side end region of the device opposite the inlet equipment, wherein the inlet equipment is so arranged and/or designed that the gas flow as well as the particles can be introduced substantially tangentially into the intermediate space.

The present invention is directed to a propylene polymer composition comprising (a) at least 90 wt. %, based on the weight of the total propylene homopolymer composition, of a propylene homopolymer having (i) a pentad isotacticity (mmmm) of equal or more than 98.0 mol.-%, determined by quantitative .sup.13C NMR spectroscopy, (ii) a relative amount of <2,1> erythro regio-defects of not more than 0.2 mol.-%, determined by quantitative .sup.13C NMR spectroscopy, as described herein, and (b) a nucleating agent (B) selective for the beta-modification of isotactic polypropylene in an amount of from 0.001 to 1.0 wt. %, based on the weight of the total propylene homopolymer composition, wherein said propylene homopolymer composition has a melt flow rate MFR.sub.2 (230° C., 2.16 kg) according to ISO 1133 of 0.1 to 10 g/10 min., a beta-phase content of not less than 80%, measured by wide angle x-ray scattering (WAXS). Further disclosed is a moulded propylene homopolymer product obtainable by compression moulding or extrusion of the propylene homopolymer composition.

Granulate based on high-temperature thermoplastics with a bulk density in the range of 100 to 650 kg/m.sup.3 in accordance with DIN ISO 697:1984 and less than 1% by weight content of volatile organic compounds, and also method for their production and use for the production of membranes or coatings, or for the toughness-modification of reactive resins.

There are provided a resin pellet having high transportability in a solid state in a feeder and a method of producing the same. A resin pellet has a recess, and when a height of the resin pellet in a case in which the resin pellet is disposed on a horizontal plane in such a manner that the recess faces the horizontal plane is defined as T1, and a maximum diameter of the resin pellet as viewed from a direction perpendicular to the horizontal plane is defined as L, an aspect ratio defined by L/T1 is 1.2 to 1.8.