The use of a composition including a mixture of at least one non-reactive thermoplastic polymer of Tg >40° C., especially >100° C., in particular >120° C., and at least one reactive thermoplastic prepolymer, with a fibrous material, for the preparation of a fibrous material impregnated with the composition, the composition having an initial melt viscosity during the impregnation, as measured in plate-plate rheology under 1 Hz and 2% strain, at a temperature of 300° C., of less than the viscosity of the same composition devoid of reactive prepolymer, measured under the same conditions, and/or a ductility, after in situ polymerization of the reactive thermoplastic prepolymer in the composition during the impregnation and after the impregnation, that is at least equivalent to the ductility of the same composition devoid of non-reactive thermoplastic polymer, and of which said reactive thermoplastic prepolymer is polymerized to the same number-average molecular mass (Mn).

Methods of making a composite article are provided herein. The method can include an unwinding step including unwinding a fiber substrate material from a creel at an unwinding velocity and an impregnation step including applying an uncured resin composition to the fiber substrate material to form a resin-fiber material. The method further includes a winding step comprising applying the resin-fiber material onto a shaped surface at a winding velocity and a solidifying step comprising applying heat to the resin-fiber material to initiate an exothermic reaction comprising polymerization, cross-linking, or both of the uncured resin composition. Temperature of the resin-fiber material can be monitored during operation of the method and a polymerization front velocity set point (v.sub.pfs) and an operating polymerization front velocity (v.sub.pfo) can be determined. Parameters can be adjusted to maintain a v.sub.pfo that is substantially the same as the v.sub.pfs. Systems for performing said methods are also provided.

A system for manufacturing a thermoplastic prepreg includes a double belt mechanism that is configured to compress a fiber mat, web, or mesh that is passed through the double belt mechanism, a resin applicator that is configured to apply monomers or oligomers to the fiber mat, web, or mesh, and a curing oven that is configured to effect polymerization of the monomers or oligomers and thereby form the thermoplastic polymer as the fiber mat, web, or mesh is moved through the curing oven. The double belt mechanism compresses the fiber mat, web, or mesh and the applied monomers or oligomers as the fiber mat, web, or mesh is passed through the curing oven so that the monomers or oligomers fully saturate the fiber mat, web, or mesh. Upon polymerization of the monomers or oligomers, the fiber mat, web, or mesh is fully impregnated with the thermoplastic polymer.

The purpose of the present invention is to provide a fiber-reinforced resin material having minimal directionality of strength as well as excellent productivity, a method and device for manufacturing a fiber-reinforced resin material whereby a molded article is obtained, and a device for inspecting a fiber bundle group. A method for manufacturing a sheet-shaped fiber-reinforced resin material in which a paste (P1) is impregnated between cut fiber bundles (CF), the method for manufacturing a fiber-reinforced resin material including a coating step applying a coating of a paste (P1) on a first sheet (S11) conveyed in a predetermined direction, a cutting step for cutting a long fiber bundle (CF) using a cutter (113A), a scattering step for dispersing the cut fiber bundles (CF) and scattering the cut fiber bundles (CF) on the paste (P1), and an impregnation step for pressing a fiber bundle group (F1) and the paste (P1) on the first sheet (S11) and impregnating the paste (P1) between the fiber bundles (CF).

A system for manufacturing a thermoplastic prepreg product includes a belt or conveyor, a prepreg applicator that positions a thermoplastic prepreg atop the belt or conveyor, a foam applicator that applies a foam mixture atop the thermoplastic prepreg, a heating mechanism that heats the thermoplastic prepreg and the foam mixture to cause the foam mixture to react atop the thermoplastic prepreg, and a laminator that is configured to press the thermoplastic prepreg and foam mixture to control a thickness of the resulting thermoplastic prepreg product. The thermoplastic prepreg includes a fabric, mat, or web of fibers and a thermoplastic material that is impregnated within the fabric, mat, or web of fibers. The thermoplastic material is formed from in situ polymerization of monomers and oligomers. The foam mixture includes an isocyanate, a polyol blend, and a blowing agent.

The present disclosure provides an impregnation device for a fiber prepreg, which includes a film layer separation assembly, a hot pressing element, and a thermal barrier element. The hot pressing element is disposed beneath the film layer separation assembly. The thermal barrier element is disposed between the film layer separation assembly and the hot pressing element. The present disclosure also provides an impregnation method for a fiber prepreg.

Provided is a fiber-reinforced resin material molding in which fluctuations of the dispersion state of the fiber bundle in the molding is small, the generation of a resin pool is suppressed, and fluctuations in physical properties such as tensile strength and modulus of elasticity are suppressed; a method for manufacturing the same, and a method for manufacturing a fiber-reinforced resin material. Provided is a fiber-reinforced resin material molding comprising: a fiber bundle comprising a plurality of reinforcing fibers; and a matrix resin, wherein a coefficient of variation in fiber content of the reinforcing fibers per unit zone of 0.1 mm square on a cut face along a thickness direction is 40% or less.

A resin supply unit of a manufacturing apparatus supplies a resin to a roller surface of an impregnated roller which is capable of rotating at a constant speed. A transport mechanism brings the fiber bundle into contact with the resin on the roller surface and thereby forms a tow prepreg while the fiber bundle is being transported. A fineness acquisition unit acquires as a fineness acquisition value a fineness, which is defined by a mass per unit length of the fiber bundle during conveyance thereof before being brought into contact with the resin. A resin supply amount control unit controls the resin supply amount based on the fineness acquisition value, in a manner so that a resin content of the tow prepreg becomes a target resin content.

Ballistic resistant composite materials having high positive buoyancy in water are provided. More particularly, provided are foam-free, buoyant composite materials fabricated using dry processing techniques. The materials comprise fibrous plies that are partially coated with a particulate binder that is thermopressed to transform a portion of the binder into raised, discontinuous patches bonded to fiber/tape surfaces, while another portion of the particulate binder remains on the fibers/tapes as unmelted particles. The presence of the unmelted binder particles maintains empty spaces within the composite to materials which increases the positive buoyancy of the composites in water.

Ballistic resistant composite materials having high positive buoyancy in water are provided. More particularly, provided are foam-free, buoyant composite materials fabricated using dry processing techniques. The materials comprise fibrous plies that are partially coated with a particulate binder that is thermopressed to transform a portion of the binder into raised, discontinuous patches bonded to fiber/tape surfaces, while another portion of the particulate binder remains on the fibers/tapes as unmelted particles. The presence of the unmelted binder particles maintains empty spaces within the composite to materials which increases the positive buoyancy of the composites in water.