A process for the production of ethylene-based polymers from waste plastics feedstocks includes the steps in this order of: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; providing a hydrocarbon stream B; supplying a feed C including a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace having cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit to obtain a product stream E containing ethylene; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an ethylene-based polymer; wherein in step (d): the coil outlet temperature is ?800 and ?870? C.; and the weight ratio of steam to feed C is >0.3 and <0.8.

Waste treatment and recycling of a carbon fiber-reinforced plastic and a glass fiber-reinforced plastic are difficult owing to their excellent characteristics. The present invention has been completed on the basis of the finding that a reinforcing material can be recovered with high efficiency by bringing heated titanium oxide granules into contact with a reinforced plastic.

Pre-shredded, solid plastic and/or rubber waste is fed in to a melting unit (4), of two sequentially linked melting equipments (41,42), where the first melting equipment (41) is constructed with an extruder axis (39) with a thread interruption (44), which shall cause solidity of the melted feedstock and formation of a compaction and a plug, thereby forcing the gases and steams to escape from the feedstock and to prevent back-flow of gases, via an interconnecting pipeline (28) a second melting equipment (42) is mounted, from where the heated high pressure melted feedstock flows into the thermocatalityc reactor (7), where thermal decomposition of the hydrocarbon polymers in the feedstock takes place, then is followed by the collection and storage of the liquid product oil and gaseous end products.

High surface area 3D mesoporous carbon nanocomposites can be derived from Zn dust and PET bottle mixed waste with a high surface area. Simultaneous transformation of Zn metal into ZnO nanoparticles and PET bottle waste to porous carbon materials can be achieved by thermal treatment at preferably 600 to 800? C., and reaction times of from 15 to 60 minutes, after optionally de-aerating the reaction mixtures with N.sub.2 gas. The waste-based carbon materials can have surface areas of 650 to 725 m.sup.2/g, e.g., 684.5 m.sup.2/g and pore size distributions of 12 to 18 nm. The carbon materials may have 3D porous dense layers with a gradient pore structure, which may have enhanced photocatalytic performance for degrading, e.g., organic dyes, such as methylene blue and malachite green. Sustainable methods make ZnO-mesoporous carbon materials from waste for applications including photocatalysis, upcycling mixed waste materials.

A method and apparatus for obtaining carbon fiber from carbon fiber waste (e.g., pre-preg and CFP waste). The method and apparatus selects, or is controlled to select, between using an oxygen free pyrolytic process to volatilize the epoxy resin or other matrix in which the fibers are held to liberate the fibers therefrom and, depending upon the type of pre-preg waste, using a reactor environment where the reactor atmosphere has about 1% to about 2% oxygen by volume. The reactor has a counterflow such that the carbon fibers are moved in one direction and the off gasses are moved in the opposite direction. A combination of steam at the reactor outlet and vacuum pressure at the reactor inlet create the counter flow.

Aspects of the present disclosure relate to methods, systems, and apparatus for efficiently reducing carbon footprints in refining systems and petrochemical processing systems. In one aspect, a plastic powder feedstock is blended into a feedstock of a processing system to re-use plastic and reduce carbon footprints. In one implementation, a method of blending plastics into a processing system includes pulverizing a plastic supply to a plastic stock having a granule size that is within a range of 7 nanometers to 10 nanometers. The method includes separating the plastic stock to remove a portion having a granule size that is outside of the range of 7 nanometers to 10 nanometers and generate a plastic feedstock. The method includes blending the plastic feedstock into a feedstock of the processing system to generate a blended feedstock, and processing the blended feedstock.

Provided is a pyrolysis method of waste plastics including the steps of inputting waste plastics to a batch reactor and performing heating to produce a waste plastic melt at a first temperature; heating the waste plastic melt to remove chlorine from the melt at a second temperature; and heating the waste plastic melt from which chlorine has been removed to produce a pyrolysate at a third temperature. The batch reactor is sequentially heated in a direction from a raw material inlet to a reaction product outlet so that the temperature is raised from the first temperature to the third temperature.

The invention relates to a pyrolysis plant and a process for recovering (recycling) carbon fibers from carbon fiber-containing plastics, in particular from carbon fiber-reinforced plastics (CFPs or CFP materials), preferably from carbon fiber-containing and/or carbon fiber-reinforced composites (composite materials).

A processing method according to the present embodiment is a processing method of a fiber containing resin in which fibers are contained in a matrix resin. The processing method includes: a step of thermal decomposition of the matrix resin in the fiber containing resin; and a step of stirring a resulting fibers bundle in solvent after the thermal decomposition. At the time of the thermal decomposition, the matrix resin may be carbonized in a dry distillation-carbonization furnace, for example.

This invention details a method and device for recycling polymeric, composite, and industrial rubber waste. It involves a bath of liquid-metal coolant, made by melting metals like lead, bismuth, zinc, aluminum, and copper. This coolant is heated to 50-150? C. above its melting point. A layer of melted salts of alkaline and alkaline-earth metals is formed on the coolant's surface, topped by a purifying layer of melted active alkaline or alkaline-earth metals. Waste is pre-loaded into perforated-wall containers with horizontal partitions and submerged in the coolant bath, then removed after processing. The device includes guide rails, an internal space with a hearth, side walls, roof, inlet and outlet sluices, and a reaction chamber. This process improves desulphurization and dichlorination of pyrolysis products, yielding a solid carbon-containing residue.