Chemical recycling facilities for processing mixed plastic waste are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy generation/energy production facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

A method of recovering filler material from a polymer material comprises (a) heating the polymer material to a first temperature; (b) heating the polymer material to a second temperature higher than the first temperature resulting in a pyrolyzed material; (c) elutriating the pyrolyzed material to obtain a separated mixture; and (d) filtering the separated mixture to obtain the filler material.

Aspects of the present disclosure relate to methods, systems, and apparatus for efficiently reducing carbon footprints in refining systems and petrochemical processing systems. In one aspect, a plastic powder feedstock is blended into a feedstock of a processing system to re-use plastic and reduce carbon footprints. In one implementation, a method of blending plastics into a processing system includes pulverizing a plastic supply to a plastic stock having a granule size that is within a range of 7 nanometers to 10 nanometers. The method includes separating the plastic stock to remove a portion having a granule size that is outside of the range of 7 nanometers to 10 nanometers and generate a plastic feedstock. The method includes blending the plastic feedstock into a feedstock of the processing system to generate a blended feedstock, and processing the blended feedstock.

Process and apparatus for recovering a product stream from a waste plastic feedstock and reducing the endpoint of the product stream is provided. A polymer oil is produced as a product stream by pyrolyzing the waste plastic feedstock in a pyrolysis reactor to produce a pyrolysis reactor effluent and passing the reactor effluent stream to a contact condensing column. In the contact condensing column, the pyrolysis reactor effluent stream is separated into a vapor product stream and a liquid product stream. The vapor product stream is recovered from the condensing column and the liquid product stream is passed back to the pyrolysis reactor for further reduction.

A woven article for a carbon fiber reinforced plastic according to the present invention is a woven article of a spun yarn containing: about 10 wt % to about 60 wt % of a carbon fiber staple in which the content of carbon components is equal to or greater than about 97 wt %; and about 40 wt % to about 90 wt % of a thermoplastic resin fiber, wherein the carbon fiber staple is obtained by carbonizing carbon fiber reinforced plastic scrap at a temperature of about 900 to about 1400° C. The woven article for a carbon fiber reinforced plastic includes a carbon fiber staple manufactured from scrap generated during manufacture of the carbon fiber reinforced plastic, and allows economic recycling of the carbon fiber reinforced plastic scrap without a reduction in mechanical properties. When molded, productivity is high due to a short cycle time, there is almost no orientation, and an excellent flexural modulus is exhibited.

A waste management system for plastic or other material floating on the surface and in the subsurface of a body of water. A shredding device will reduce the size of the particles of waste. Ocean water is removed by a drying device. The dried waste material is frozen to a temperature at or below minus fifty degrees Fahrenheit, using liquid nitrogen or other suitable means. The frozen waste material is then pulverized and ground into a powder. The powder may then be sprayed into a gas-filled chamber and heated. Temperature, pressure and humidity are maintained within the chamber for more than one minute. Microwave or other radiation and catalysts may be used to enhance the process of extraction. The processed material is then removed from the chamber. Carbon may be recycled or used as fuel by the ship. Water may be used by the ship or returned to the ocean.

A graphene material prepared using waste tires and a preparation method thereof. Waste tires are crushed to 30-200 meshes to obtain tire powders. The tire powders are mixed with KOH or an aqueous solution of KOH to obtain a homogeneous mixture. The mixture is dried at 50-90° C. for 12-48 hours, heated and calcinated in a tube furnace under a protective gas for 1-48 hour to obtain a black lump. The black lump is washed with distilled water, dilute hydrochloric acid or dilute sulfuric acid for at least 3 times, and then washed with deionized water for at least 3 times to obtain a black powder. The black powder is dried to obtain the graphene material. The graphene material has a three-dimensional structure composed of oligolayer graphene intertwined and connected with each other, has a high crystallinity, is not easily agglomerated, and thus can maintain nano-effect of the graphene material.

The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and <0.8.

High surface area 3D mesoporous carbon nanocomposites can be derived from Zn dust and PET bottle mixed waste with a high surface area. Simultaneous transformation of Zn metal into ZnO nanoparticles and PET bottle waste to porous carbon materials can be achieved by thermal treatment at preferably 600 to 800° C., and reaction times of from 15 to 60 minutes, after optionally de-aerating the reaction mixtures with N.sub.2 gas. The waste-based carbon materials can have surface areas of 650 to 725 m.sup.2/g, e.g., 684.5 m.sup.2/g and pore size distributions of 12 to 18 nm. The carbon materials may have 3D porous dense layers with a gradient pore structure, which may have enhanced photocatalytic performance for degrading, e.g., organic dyes, such as methylene blue and malachite green. Sustainable methods make ZnO-mesoporous carbon materials from waste for applications including photocatalysis, upcycling mixed waste materials.

The present disclosure relates to a plastic pyrolysis/emulsification system for pyrolyzing waste plastic in a high-temperature/high-vacuum environment, the plastic pyrolysis/emulsification system being characterized by comprising: an introduction portion having a hopper for introducing plastic; a heating furnace having a burner mounted thereon so as to establish a high-temperature environment therein and having a combustion gas outlet; a melting furnace penetrating the heating furnace such that one end of the melting furnace is connected to the introduction portion, and both ends thereof are exposed to the outside, a transferring/compressing means being mounted in the melting furnace along the longitudinal direction so as to transfer and compress the plastic in one direction, thereby transferring, compressing, and melting the plastic, and the melting furnace having a vapor outlet for discharging water vapor resulting from compression and melting of the plastic; a first transfer portion connected to the other end of the melting furnace so as to transfer the melt of the plastic; a vacuum pyrolysis furnace penetrating the heating furnace such that one end of the vacuum pyrolysis furnace is connected to the first transfer portion, and both ends thereof are exposed to the outside, a transfer means being mounted in the vacuum pyrolysis furnace along the longitudinal direction so as to transfer the melt in one direction, thereby transferring and pyrolyzing the melt, and the vacuum pyrolysis furnace having an oil vapor outlet for discharging oil vapor resulting from transfer and pyrolysis of the melt; a second transfer portion connected to the other end of the vacuum pyrolysis furnace so as to transfer the pyrolysis remnant of the melt; a discharge portion connected to the second transfer portion so as to discharge the pyrolysis remnant; a first condenser connected to the vapor outlet so as to condense the water vapor; a second condenser connected to the other end of the vacuum pyrolysis furnace so as to transfer the pyrolysis remnant of the melt; a discharge portion connected to the second transfer portion so as to discharge the pyrolysis remnant; a first condenser connected to the vapor outlet so as to condense is the water vapor; a second condenser connected to the oil vapor outlet so as to condense the oil vapor; multiple third condensers connected to the second condenser via first, second, and third valves, respectively; a vacuum pump connected to the multiple third condensers via fourth, fifth, and sixth valves, respectively; and a fourth condenser connected to the vacuum pump.