The present invention provides for concentrated aqueous silk fibroin solutions and an all-aqueous mode for preparation of concentrated aqueous fibroin solutions that avoids the use of organic solvents, direct additives, or harsh chemicals. The invention further provides for the use of these solutions in production of materials, e.g., fibers, films, foams, meshes, scaffolds and hydrogels.

The invention relates to a multilayer structure comprising at least one layer of supramolecular material and one layer of rigid material, to a method for producing such a structure by casting a composition comprising a precursor of the supramolecular material, and to the uses of the structures produced, especially for applications where a dampening of impacts, vibrations and/or sound waves is desired, for example for producing locomotion vehicles such as automotive, rail, nautical, aeronautical or aerospace vehicles, or for the construction industry.

The invention relates to a co-extruded film comprising a sealing layer of low density polyethylene and a skin layer, wherein the skin layer comprises a copolyamide which comprises: At least 75 wt % monomeric units derived from caprolactam; Between 5 to 25 wt % monomeric units derived from a diamine and terephthalic acid; wherein the weight percentage is with respect to the total weight of copolyamide in the skin layer. The invention also relates to a process for preparing such a film, as well as applications of the film.

A polymer sheet includes a polyurethane core. The polyurethane core has a first major surface and a second major surface opposite the first major surface. The polymer sheet can have at least one functional layer overlying a major surface. The polymer sheet has a thickness t.sub.PS. The polyurethane core has a thickness t.sub.PC. In embodiments t.sub.PC can be at least 0.3 t.sub.PS. The polyurethane core can have at least one of the following property: (i) a Scratch Resistance Rating, as further described herein, of not greater than about 10 wt %, (ii) an elongation at break of at least 200%, (iii) a tensile strength at break of at least 0.3 MPa, (iv) a loss of tensile strength of not greater than about 30% when exposed to UV light according to standard SAE J1960 (Rev. August 2003).
The polymer sheet can be used for gaskets or bonding tapes.

A polymer sheet includes a polyurethane core. The polyurethane core has a first major surface and a second major surface opposite the first major surface. The polymer sheet can have at least one functional layer overlying a major surface. The polymer sheet has a thickness t.sub.ps. The polyurethane core has a thickness t.sub.pc. In embodiments t.sub.pc can be at least 0.3 t.sub.ps. The polyurethane core can have at least one of the following property: (i) a Scratch Resistance Rating, as further described herein, of not greater than about 10 wt %, (ii) an elongation at break of at least 200%, (iii) a tensile strength at break of at least 0.3 MPa, (iv) a loss of tensile strength of not greater than about 30% when exposed to UV light according to standard SAE J1960 (Rev. August 2003). The polymer sheet can be used for gaskets or bonding tapes.

A water-soluble film (WSF) system comprises at least one active material embedded/entrapped in the film so as to provide precise and desired release of the at least one active material therefrom. The at least one active material includes detergents, enzymes, softeners, perfumes, pesticides, fungicides, active ingredients, dyes, pigments, hazardous chemicals, active agents for cleaning laundry, dishes, floorings, walls, furniture, fluffs, pulp, and combinations thereof. Online and offline processes can be used for the manufacture of multi-layered WSFs with or without liners. The WSFs can be formed in desired shapes to selectively entrap interacting/non-interacting materials and combinations thereof. The process also provides options for the use of a wide range of raw materials, liners such as paper, film, foil, fabric, etc.

A polymer sheet includes a polyurethane core. The polyurethane core has a first major surface and a second major surface opposite the first major surface. The polymer sheet can have at least one functional layer overlying a major surface. The polymer sheet has a thickness t.sub.PS. The polyurethane core has a thickness t.sub.PC. In embodiments t.sub.PC can be at least 0.3 t.sub.PS. The polyurethane core can have at least one of the following property: (i) a Scratch Resistance Rating, as further described herein, of not greater than about 10 wt %, (ii) an elongation at break of at least 200%, (iii) a tensile strength at break of at least 0.3 MPa, (iv) a loss of tensile strength of not greater than about 30% when exposed to UV light according to standard SAE J1960 (Rev. August 2003).

The polymer sheet can be used for gaskets or bonding tapes.

The present invention provides for concentrated aqueous silk fibroin solutions and an all-aqueous mode for preparation of concentrated aqueous fibroin solutions that avoids the use of organic solvents, direct additives, or harsh chemicals. The invention further provides for the use of these solutions in production of materials, e.g., fibers, films, foams, meshes, scaffolds and hydrogels.

A polymer sheet includes a polyurethane core. The polyurethane core has a first major surface and a second major surface opposite the first major surface. The polymer sheet can have at least one functional layer overlying a major surface. The polymer sheet has a thickness t.sub.PS. The polyurethane core has a thickness t.sub.PC. In embodiments t.sub.PC can be at least 0.3 t.sub.PS. The polyurethane core can have at least one of the following property: (i) a Scratch Resistance Rating, as further described herein, of not greater than about 10 wt %, (ii) an elongation at break of at least 200%, (iii) a tensile strength at break of at least 0.3 MPa, (iv) a loss of tensile strength of not greater than about 30% when exposed to UV light according to standard SAE J1960 (Rev. August 2003).
The polymer sheet can be used for gaskets or bonding tapes.

A film comprising a) at least one base layer comprising a thermoplastic polymeric matrix material; and b) a skin layer comprising a thermoplastic polymeric matrix material and from 5 wt % to 80 wt % of polymeric particles having an average particle diameter from 0.5 m to 15 m, a refractive index from 1.46 to 1.7, and at least 60 mole % of acrylic monomer units wherein the film is stretched by a factor of 2 to 8 uniaxially or biaxially; and wherein after stretching, the skin layer has a thickness that is between 50% and 200% of the diameter of the polymeric particles, and a method of making the film, are disclosed.