A composition and a manufacturing method of a highly flame-retardant and low-smoke extruded polyvinyl chloride pipe are provided. The composition includes a polyvinyl chloride resin material, a flame retardant additive and a carbon forming additive. The polyvinyl chloride resin material is in an amount between 10 PHR (parts per hundred resin) and 90 PHR. The flame retardant additive is in an amount between 0.5 PHR and 2.0 PHR, and is a phosphorus-containing flame retardant modified by a modifier. The carbon forming additive is in an amount between 0.2 PHR and 1.0 PHR. The carbon forming additive is at least one material selected from a group consisting of zinc chloride, zinc stearate, calcium stearate, zinc hydroxystannate, anhydrous zinc stannate, zinc phosphate and zirconium phosphate. A total added amount of the flame retardant additive and the carbon forming additive in the composition is not greater than 3 PHR.

A composition and a manufacturing method of a highly flame-retardant and low-smoke extruded polyvinyl chloride pipe are provided. The composition includes a polyvinyl chloride resin material, a flame retardant additive and a carbon forming additive. The polyvinyl chloride resin material is in an amount between 10 PHR (parts per hundred resin) and 90 PHR. The flame retardant additive is in an amount between 0.5 PHR and 2.0 PHR, and is a phosphorus-containing flame retardant modified by a modifier. The carbon forming additive is in an amount between 0.2 PHR and 1.0 PHR. The carbon forming additive is at least one material selected from a group consisting of zinc chloride, zinc stearate, calcium stearate, zinc hydroxystannate, anhydrous zinc stannate, zinc phosphate and zirconium phosphate. A total added amount of the flame retardant additive and the carbon forming additive in the composition is not greater than 3 PHR.

The present invention is directed to a method and a system for the production of at least one polymeric yarn comprising means for mixing a polymer (1) with a first solvent yielding a mixture; means for homogenizing the mixture; means for rendering the mixture inert (21, 22, 23); means for dipping the mixture into a quenching bath (30), wherein an air gap is maintained before the mixture reaches the quenching bath (30) liquid surface forming at least one polymeric yarn; means for drawing (41) the at least one polymeric yarn at least once; means for washing (5) the at least one polymeric yarn with a second solvent that is more volatile than the first solvent; means for heating the at least one polymeric yarn (6); means for drawing at room temperature (7) the at least one polymeric yarn at least once; and means for heat drawing (8) the at least one polymeric yarn at least once. The instant invention also concerns a system and method of dosing a polymer mixture with a first solvent into an extruder (26), a device (5), a system and a method of solvent extraction from at least one polymeric yarn, and a method and system of mechanical pre-recovery (4) of at least one liquid in at least one polymeric yarn.

The present invention is directed to a method and a system for the production of at least one polymeric yarn comprising means for mixing a polymer (1) with a first solvent yielding a mixture; means for homogenizing the mixture; means for rendering the mixture inert (21, 22, 23); means for dipping the mixture into a quenching bath (30), wherein an air gap is maintained before the mixture reaches the quenching bath (30) liquid surface forming at least one polymeric yarn; means for drawing (41) the at least one polymeric yarn at least once; means for washing (5) the at least one polymeric yarn with a second solvent that is more volatile than the first solvent; means for heating the at least one polymeric yarn (6); means for drawing at room temperature (7) the at least one polymeric yarn at least once; and means for heat drawing (8) the at least one polymeric yarn at least once. The instant invention also concerns a system and method of dosing a polymer mixture with a first solvent into an extruder (26), a device (5), a system and a method of solvent extraction from at least one polymeric yarn, and a method and system of mechanical pre-recovery (4) of at least one liquid in at least one polymeric yarn.

A three-dimensional printing nozzle, a three-dimensional printing nozzle assembly, and a three-dimensional printing apparatus are provided. The three-dimensional printing nozzle includes a nozzle body having an inlet and an outlet, a driving unit disposed in the nozzle body, a first heating unit, and a first heat dissipation unit. A particle forming material is adapted to enter the nozzle body from the inlet. The driving unit is configured for pushing the particle forming material to move from the inlet to the outlet. The first heating unit is disposed in the nozzle body for heating and melting the particle forming material and extrudes a melted forming material out of the nozzle body from the outlet through the driving unit. The first heat dissipation unit is disposed in the nozzle body and located between the first heating unit and the inlet to reduce heat transmitted from the first heating unit to the inlet.

Polyester polymer particle spheroids comprising a polyester polymer including: a carboxylic acid component containing at least 90 mole % of the residues of terephthalic acid, derivates of terephthalic acid, naphthalene-2,6-dicarboxylic acid, and/or derivatives of naphthalene-2,6-dicarboxylic acid, and a hydroxyl component containing from 90 to 96 mole % of the residues of ethylene glycol, based on 100 mole percent of the carboxylic acid component residues and 100 mole percent hydroxyl component residues in the polyester polymer, wherein said particle has an It.V. of at least 0.72 dL/g, and the It.V. at the surface of the particle is from 0.02 dL/g to less than 0.25 dL/g higher than the It.V. at the center of the particle, and wherein the polyester polymer spheroids are not solid state polymerized.

Polyester polymer particle spheroids comprising a polyester polymer including: a carboxylic acid component containing at least 90 mole % of the residues of terephthalic acid, derivates of terephthalic acid, naphthalene-2,6-dicarboxylic acid, and/or derivatives of naphthalene-2,6-dicarboxylic acid, and a hydroxyl component containing from 90 to 96 mole % of the residues of ethylene glycol, based on 100 mole percent of the carboxylic acid component residues and 100 mole percent hydroxyl component residues in the polyester polymer, wherein said particle has an It.V. of at least 0.72 dL/g, and the It.V. at the surface of the particle is from 0.02 dL/g to less than 0.25 dL/g higher than the It.V. at the center of the particle, and wherein the polyester polymer spheroids are not solid state polymerized.

A composite floor comprises a coextrusion layer compression molded using a coextrusion process. The layer comprises a first stone-plastic layer, a stone-plastic foaming layer, and a second stone-plastic layer sequentially arranged from top to bottom. The stone-plastic foaming layer is used as the main material layer, which reduces a whole weight of the floor; and the first stone-plastic layer and the second stone-plastic layer are arranged at two sides of the stone-plastic foaming layer, respectively, so that the composite floor is more stable. It is more environmentally friendly and simple in manufacturing to use the coextrusion process for compression molding by avoiding bonding using glue. Use of the coextrusion process makes various layers bond more compact, with little delamination and warpage due to effect of environmental changes. The composite floor has a low expansion rate and shrinkage rate, excellent in performance and long in service life.

A composite floor comprises a coextrusion layer compression molded using a coextrusion process. The layer comprises a first stone-plastic layer, a stone-plastic foaming layer, and a second stone-plastic layer sequentially arranged from top to bottom. The stone-plastic foaming layer is used as the main material layer, which reduces a whole weight of the floor; and the first stone-plastic layer and the second stone-plastic layer are arranged at two sides of the stone-plastic foaming layer, respectively, so that the composite floor is more stable. It is more environmentally friendly and simple in manufacturing to use the coextrusion process for compression molding by avoiding bonding using glue. Use of the coextrusion process makes various layers bond more compact, with little delamination and warpage due to effect of environmental changes. The composite floor has a low expansion rate and shrinkage rate, excellent in performance and long in service life.

Novel aromatic polyimides are disclosed with sufficient physical properties to be useful in 3D printing.