Provided are a novel filament for a three-dimensional printer, a winding, a method for producing a filament for a three-dimensional printer, and a method for producing a formed article. The filament for a three-dimensional printer includes a continuous reinforcing fiber impregnated with a thermosetting resin composition containing a thermosetting resin, the filament having a characteristic of being solid at 25° C.

A process can be used for preparing silicone (meth)acrylates, according to which at least one acetoxysilicone is reacted with at least one hydroxyfunctional (meth)acrylic acid ester. The corresponding silicone (meth)acrylates are useful, and can be used in curable compositions.

A process can be used for preparing silicone (meth)acrylates, according to which at least one acetoxysilicone is reacted with at least one hydroxyfunctional (meth)acrylic acid ester. The corresponding silicone (meth)acrylates are useful, and can be used in curable compositions.

A powder with a volume-weighted particle size distribution, with a median diameter D50 ranging from 40 to 120 micrometers, including at least one polyaryl ether ketone and at least one filler, in which: said at least one polyaryl ether ketone forms a matrix incorporating, at least partly, said at least one filler, and said filler has a Stokes equivalent spherical diameter distribution with a median diameter d′50 of less than or equal to 5 micrometers. Also a powder manufacturing process and the use thereof in a process for the layer-by-layer construction of objects by electromagnetic radiation-mediated sintering.

A powder with a volume-weighted particle size distribution, with a median diameter D50 ranging from 40 to 120 micrometers, including at least one polyaryl ether ketone and at least one filler, in which: said at least one polyaryl ether ketone forms a matrix incorporating, at least partly, said at least one filler, and said filler has a Stokes equivalent spherical diameter distribution with a median diameter d′50 of less than or equal to 5 micrometers. Also a powder manufacturing process and the use thereof in a process for the layer-by-layer construction of objects by electromagnetic radiation-mediated sintering.

A semicrystalline polyketone powder useful for additive manufacturing may be made by dissolving a polyketone having differential scanning calorimetry (DSC) monomodal melt peak, at a temperature above 50° C. to below the melt temperature of the polyketone, precipitating the dissolved polyketone by cooling, addition of a nonsolvent or combination thereof. The method may be used to form polyketones having a DSC melt peak with an enthalpy greater than the starting polyketone.

A semicrystalline polyketone powder useful for additive manufacturing may be made by dissolving a polyketone having differential scanning calorimetry (DSC) monomodal melt peak, at a temperature above 50° C. to below the melt temperature of the polyketone, precipitating the dissolved polyketone by cooling, addition of a nonsolvent or combination thereof. The method may be used to form polyketones having a DSC melt peak with an enthalpy greater than the starting polyketone.

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin) particles may comprising: mixing a mixture comprising: (a) a CNM-g-polyolefin comprising a polyolefin grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyolefin of the CNM-g-polyolefin, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyolefin of the CNM-g-polyolefin and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyolefin in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form the CNM-g-polyolefin particles; and separating the CNM-g-polyolefin particles from the carrier fluid.

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin) particles may comprising: mixing a mixture comprising: (a) a CNM-g-polyolefin comprising a polyolefin grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyolefin of the CNM-g-polyolefin, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyolefin of the CNM-g-polyolefin and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyolefin in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form the CNM-g-polyolefin particles; and separating the CNM-g-polyolefin particles from the carrier fluid.

A lightweight liquid metal composition and a method for producing a lightweight liquid metal composition. The composition includes: a liquid metal inclusion; a low-density phase including a plurality of particles; and an elastic polymer. The method includes: combining a low-density phase with a liquid metal to produce a multiphase liquid metal (LM), the low-density phase including a material having a density less than a density of the LM; mixing the multiphase LM with an elastomer to produce an emulsion; and curing the emulsion to produce a lightweight LM composition.