The present disclosure provides a light curing non-transparent material for 3D printing and a preparation method thereof, a 3D printed product and a 3D printer. The light curing non-transparent material for 3D printing provided by the present disclosure can be used to print non-transparent 3D printed products without adding white pigments such as white pigments powder, and therefore has the characteristic of high stability, and also ensures fluency of the 3D printing process, good quality of the 3D printed products, as well as good performances of the 3D printer that containing light curing non-transparent material for 3D printing.

Disclosed is a composition including at least one polymer, wherein the polymer is in the form of a powder, and wherein the polymer includes at least one thermoplastic polymer. The thermoplastic polymer is selected from at least one polyaryletherketone and/or a copolymer and/or a block-copolymer and/or a polymer blend thereof, wherein the composition has a melt volume rate (MVR) of at least 5 cm.sup.3/10 min and a process of manufacturing and a use thereof. Also disclosed are a process for the manufacture of a construction element and the construction element thereof.

Disclosed is a composition including at least one polymer, wherein the polymer is in the form of a powder, and wherein the polymer includes at least one thermoplastic polymer. The thermoplastic polymer is selected from at least one polyaryletherketone and/or a copolymer and/or a block-copolymer and/or a polymer blend thereof, wherein the composition has a melt volume rate (MVR) of at least 5 cm.sup.3/10 min and a process of manufacturing and a use thereof. Also disclosed are a process for the manufacture of a construction element and the construction element thereof.

A resin powder for three-dimensional laminated modeling contains an aggregate of resin particles. A volume average particle size MV of the resin particles is in the range of 1 to 200 μm. A value of a ratio (MV/MN) of the volume average particle size MV and a number average particle size MN of the resin particles is 2.5 or more. A static bulk density is 0.30 g/cm3 or more. The resin particles contain a crystalline thermoplastic resin.

A resin powder for three-dimensional laminated modeling contains an aggregate of resin particles. A volume average particle size MV of the resin particles is in the range of 1 to 200 μm. A value of a ratio (MV/MN) of the volume average particle size MV and a number average particle size MN of the resin particles is 2.5 or more. A static bulk density is 0.30 g/cm3 or more. The resin particles contain a crystalline thermoplastic resin.

Disclosed are Self-Gelling materials and structures or materials or structures having one or more self-gelling components that overcome existing gel limitations due to hydrogel localization for medical applications by providing, for example, 1) microstructurally, or physically, anchored characteristics to help localize the gel, and the overall printed, or otherwise formed structure, giving structural form to the gel that allows the gel to be localized within the body, and even sutured in place, and mitigates gel migration and extends its residence time; 2) to provide an underlying 3D printed structure to help contain and support the gel after implantation; and more. Self-Gelling 3D printed structures may be further processed via milling to yield deconstructed scaffold micro-granules, with the composition and nano-/micro- structure of the original larger structure. Deconstructed scaffold micro-granules may be hydrated to form a micro-granule embedded gel network that can be injected, giving form to injectable gels.

A method is provided for treating the surface of a molded part produced with a plastic having ester, ketone and/or ether bonds. The plastic is selected from the group including a polymer, copolymer, polymer blend and combinations of the same. The method includes a pretreatment step for cationically modifying the surface of the molded part. The cationic modification is carried out with a reactant dissolved in a solvent and having one or more amine, imine and/or amide groups.

A method is provided for treating the surface of a molded part produced with a plastic having ester, ketone and/or ether bonds. The plastic is selected from the group including a polymer, copolymer, polymer blend and combinations of the same. The method includes a pretreatment step for cationically modifying the surface of the molded part. The cationic modification is carried out with a reactant dissolved in a solvent and having one or more amine, imine and/or amide groups.

A composition of matter comprises at least 10 wt % epoxy functionalized two-dimensional shaped particles, carbon nanotubes in the range of 0.1 to 5 wt %, epoxy resin and a curing agent. A method of manufacturing a composition of matter includes mixing epoxy resin, carbon nanotubes and a solvent to produce a material, drying the material, and mixing the material with a curing agent to product the composition of matter. A method of printing a composition of matter includes producing the composition of matter by combining epoxy functionalized graphene, carbon nanotubes, epoxy base resin, and a curing agent, extrusion printing the composition of matter into a desired pattern, and curing the pattern.

A composition of matter comprises at least 10 wt % epoxy functionalized two-dimensional shaped particles, carbon nanotubes in the range of 0.1 to 5 wt %, epoxy resin and a curing agent. A method of manufacturing a composition of matter includes mixing epoxy resin, carbon nanotubes and a solvent to produce a material, drying the material, and mixing the material with a curing agent to product the composition of matter. A method of printing a composition of matter includes producing the composition of matter by combining epoxy functionalized graphene, carbon nanotubes, epoxy base resin, and a curing agent, extrusion printing the composition of matter into a desired pattern, and curing the pattern.