Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles and a polymer material comprising at least one thermoplastic polymer and at least one photocurable polymer precursor. The at least one photocurable polymer precursor may undergo a reaction in the presence of electromagnetic radiation, optionally undergoing a reaction with the piezoelectric particles, in the course of forming the printed part. The piezoelectric particles may be mixed with the polymer material and remain substantially non-agglomerated when combined with the polymer material. The compositions may define a form factor such as a composite filament, a composite pellet, or an extrudable composite paste, which may be utilized in forming printed parts by extrusion and layer-by-layer deposition, followed by curing.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a polymer matrix comprising a first polymer material and a second polymer material that are immiscible with each other, and a plurality of piezoelectric particles substantially localized in one of the first polymer material or the second polymer material. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer matrix. The compositions may define a form factor such as a composite filament, a composite pellet, or an extrudable composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions that are extrudable and comprise a plurality of piezoelectric particles and a plurality of carbon nanomaterials dispersed in at least a portion of a polymer material. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer material. The polymer material may comprise at least one thermoplastic polymer, optionally further containing at least one polymer precursor. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

A hollow-cylindrical device (1) having first and second openings (2, 3) for continuous production of a dental composite block. A curable composite material (4) and a temperature control unit (5) are provided. The composite material (4) is introduced into the device (1) through the first opening. The composite material (4) is cured by energy from the temperature control unit (5). An energy input occurs across a defined length of the substantially hollow-cylindrical device (1) and/or for a defined period of time. The composite material (4) is subsequently guided through the first opening (2) of the device (1). The composite material (4) is discharged from the second opening (3). In a first region along a portion of the length of the device, the device is either provided with an insulation or the flow-through device has a heat conductivity of 0.05 to 12 W/(m×K).

A graphene reinforced polyethylene terephthalate composition is provided for forming graphene-PET containers. The graphene reinforced polyethylene terephthalate composition includes a continuous matrix comprising polyethylene terephthalate and a dispersed reinforcement phase comprising graphene nanoplatelets. The graphene nanoplatelets range in diameter between 5 μm and 10 μm with surface areas ranging from about 15 m.sup.2/g to about 150 m.sup.2/g. In some embodiments, the graphene reinforced polyethylene terephthalate comprises a concentration of graphene nanoplatelets being substantially 3% weight fraction of the graphene reinforced polyethylene terephthalate. The graphene reinforced polyethylene terephthalate is configured to be injection molded into a graphene-PET preform suitable for forming a container. The graphene-PET preform is configured to be reheated above its glass transition temperature and blown into a mold so as to shape the graphene-PET preform into the container.

The present invention addresses the problem of providing a three-dimensional modeled article having high dimensional precision, high strength, and high ductility, and a resin composition for a three-dimensional modeled article, the resin composition being used to fabricate the three-dimensional modeled article, and of providing a method for manufacturing a three-dimensional modeled article. To address this problem, a resin composition for a three-dimensional modeled article according to the present invention contains resin particles having a continuous phase including a thermoplastic resin, and a dispersed phase including a thermoplastic elastomer, dispersed in the continuous phase, the amount of the thermoplastic elastomer therein being 1-12 parts by mass with respect to a total of 100 parts by mass of the thermoplastic resin and the thermoplastic elastomer.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a polymer matrix comprising a first polymer material and a second polymer material that are immiscible with each other, and a plurality of piezoelectric particles located in at least a portion of the polymer matrix. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer matrix. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

A thermosetting composite material and its method for 3D printing by extrusion, the thermosetting composite material including a furan polymer forming a thermosetting matrix, a solvent, and a material formed from particles chosen from among micrometric particles, nanometric particles, even a mixture of micrometric particles and nanometric particles, these particles being with the basis of a compound comprising more than 40% by mass of carbon. The thermosetting composite material and its 3D printing method enabling to obtain an object having dimensional tolerances of between 2.5 and 5% with respect to the numerical model, and a resistance to high temperatures going up to 300° C. The thermosetting composite material and its 3D printing method representing a biosourced and cheaper alternative with respect to synthetic thermoplastic polymers and their usual printing method.

A method for preparing a vapor sensitive sacrificial support material. The method may include decomposing a polycondensed PEO polymer with heat in the presence of a graphene-like material to release PEO polymer radicals from the polycondensed PEO polymer, such that at least a portion of the PEO polymer radicals become trapped on at least a portion of a surface of the graphene-like material to form a coated graphene-like material, which may be defined as a structural reinforcement material. The method may further include forming the vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may include a polyethylene oxide polymer backbone. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may further include one or more nanoscopic particulate processing aids. The structural reinforcement material may be uniformly dispersed in the vapor sensitive water-soluble thermoplastic polymer composite.

An additive manufacturing ink includes MXene nanoparticles including a titanium carbide represented by Ti.sub.3C.sub.2T.sub.x, where x is an integer and each T is a functional group or an atom (e.g., O, F, OH, or Cl). Additive manufacturing includes depositing a first amount of an ink including MXene nanoparticles in a region of a microchannel defined by a substrate, allowing the first amount of the ink to flow in the microchannel by capillary action to form a first layer of the ink in the microchannel, depositing a second amount of the ink in the region of the microchannel, and allowing the second amount of the ink to flow in the microchannel by capillary action to form a second layer of the ink atop the first layer of ink. A pressure sensor includes a substrate defining a microchannel, and a multiplicity of MXene film layers deposited in the microchannel.